Superseded

GB/T 4842-2006Argon (English PDF)

氩

Preview PDF

This is a limited preview

Buy now to download the full PDF (18 pages)

Need quotation for your management?

Get a formal quotation for GB/T 4842-2006 in 30 minutes.

Issued by

General Administration of Quality Supervision, Inspection and Quarantine

Level / Type

National · Recommended

Issue date

September 1, 2006

Implementation date

February 1, 2007

Scope

GB/T 4842-2006 is the English-translated version of 氩.

GB/T 4842-2006 — This Standard specifies the requirements, test methods, packaging, labeling, storage, and security of pure argon and high purity argon.

This Standard applies to the gaseous and liquid pure argon, and high purity argon extracted from the air and ammonia exhaust by cryogenic method; and pure argon and high purity argon obtained by purification method.

They are mainly used in metal smelting and welding, semiconductor manufacturing, electric light, preparation of standard samples, scientific research and other industries.

Molecular formula. Ar. Relative molecular mass. 39.948 (according to 2001 international relative atomic mass).

Found what you need?

Document preview — GB/T 4842-2006

National Standard of the People's Republic of China

ICS
71.100.20
Classification
G 86

Issued by: General Administration of Quality Supervision, Inspection and Quarantine

Contents

  • Foreword...3
  • 1 Scope...6
  • 2 Normative references...6
  • 3 Requirements...7
  • 4 Test methods...8
  • 5 Labeling, packaging, storage, and security...11
  • 6 Others...12
  • Appendix A...14
  • Appendix B...18

Foreword

This Standard replaces GB/T 4842-1995 "Pure argon" and GB/T 10624-1995

"High purity argon".

The main differences between this Standard AND GB/T 4842-1995, GB/T

10624-1995 are as follows.

- MERGE two standards into one;

- MODIFY the scope of high purity argon (Chapter 1 of this Standard, and

Chapter 1 of GB/T 10624-1995);

- ADD pallet-loaded, cluster-bottled, and tanker-loaded argon products. And

SPECIFY the inspection methods (4.1.3 of this Standard);

- MODIFY the normative references (Chapter 2 of this Standard, Chapter 2

of GB/T 4842-1995, and Chapter 2 of GB/T 10624-1995);

- MODIFY the contents of technical indicators. DELETE superior-class and

A-class products of high purity argon. DIVIDE pure argon's total carbon

content into methane, carbon monoxide, and carbon dioxide; high purity

argon's total carbon content is methane + carbon monoxide + carbon

dioxide, and it can be determined separately. ADJUST hydrogen, oxygen,

nitrogen, and water content. INCLUDE water content in purity calculation

(3.4.2 of this Standard, 3.4.1 of GB/T 4842-1995, and 3.4.1 of GB/T

10624-1995);

- MODIFY the sampling methods of pure argon (4.1.2 of this Standard,

Chapter 5 of GB/T 10624-1995);

- ADD new analysis method. ADD zirconia gas chromatography method to

determine hydrogen, oxygen, methane, and carbon monoxide in argon

gases. ADD ion migration gas chromatography method, argon ionization

gas chromatography method, and argon discharge ionization gas

chromatography method to determine hydrogen, oxygen, nitrogen,

methane, carbon monoxide, and carbon dioxide components in argon

gases. ADD other methods for the determination of water. When there

occurs a variety of analysis methods, add specified arbitration method (4.3

of this Standard);

- DELETE the method of adopting ion migration gas chromatography

method to determine nitrogen in argon gases, in previous standard (4.2 of

GB/T 10624-1995);

- ADD safety specifications (5.6 of this Standard);

- ADD the Normative Appendix A. And INCLUDE the methods of adopting

ion migration gas chromatography method, argon ionization gas

chromatography method, and argon discharge ionization gas

chromatography method to determine hydrogen, oxygen, nitrogen,

methane, carbon monoxide, and carbon dioxide components in argon

gases INTO this Appendix (Appendix A of this Standard).

Appendix A and Appendix B of this Standard are normative.

This Standard was proposed by China Petroleum and Chemical Industry

Association.

This Standard shall be centralized by the National Standardization Technical

Committee of Gases.

Main drafting organizations of this Standard. The Oxygen Co., Ltd. of Wuhan

Iron and Steel Group. Kena Science and Technology Development Co., Ltd. of

Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Beijing

Sys Ruitai Sciences and Technology Co., Ltd. and Southwest Research

Institute of Chemical Industry.

Main drafters of this Standard. Chen Wenyu, Wang Guiyue, Zhang Bingxin,

and Zhou Pengyun.

The previous versions replaced by this Standard are. GB 4842-1984, GB

4843-1984, GB 10624-1989, GB 10625-1989, GB/T 4842-1995, GB/T

10624-1995.

Argon

1 Scope

This Standard specifies the requirements, test methods, packaging, labeling,

storage, and security of pure argon and high purity argon.

This Standard applies to the gaseous and liquid pure argon, and high purity

argon extracted from the air and ammonia exhaust by cryogenic method; and

pure argon and high purity argon obtained by purification method. They are

mainly used in metal smelting and welding, semiconductor manufacturing,

electric light, preparation of standard samples, scientific research and other

industries.

Molecular formula. Ar.

Relative molecular mass. 39.948 (according to 2001 international relative

atomic mass).

2 Normative references

The provisions in following documents become the provisions of this Standard

through reference in this Standard. For dated references, the subsequent

amendments (excluding corrections) or revisions do not apply to this Standard,

however, parties who reach an agreement based on this Standard are

encouraged to study if the latest versions of these documents are applicable.

For undated references, the latest edition of the referenced document applies.

GB 190-1990 Labels for packages of dangerous goods

GB/T 3723 Sampling of chemical products for industrial use - Safety in

sampling

GB 5099 Seamless steel gas cylinders (GB 5099-1994, neq ISO 4705.

1993)

GB/T 5832.1 Determination of moisture in gases - Part 1.Electrolytic method

GB/T 5832.2 Determination of moisture in gases - Part 2.Dew point method

determination results, take the ion migration gas chromatography method as

arbitration method.

4.3.5 It is allowed to determine the trace methane, carbon monoxide and

carbon dioxide in pure argon and high purity argon according to the methods

specified in GB/T 8984.1 or other equivalent methods. It is allowed to

determine the total content of trace methane, carbon monoxide, and carbon

dioxide in high purity argon according to the methods specified in GB/T 8984.2.

When there exists dispute to the above determination results, take the

methods specified in GB/T 8984.1 as arbitration method.

4.4 Determination of water content

EXECUTE it according to GB/T 5832.1 or GB/T 5832.2.

It is allowed to use other equivalent methods to determine the water content in

argon. When there exists dispute to the determination results, take the

methods specified in GB/T 5832.2 as arbitration method.

5 Labeling, packaging, storage, and security

5.1 Argon gas cylinders shall comply with the specifications of GB 5099.And

the color and labeling of gas cylinders shall comply with the specifications of

GB 7144.When being transported, gas cylinders shall be accompanied by the

labels specified in Chapter 3 of GB 190-1990.

5.2 Filling, storage and transportation

5.2.1 Bottled gaseous argon shall comply with the relevant specifications of

GB 14194 and "Gas Cylinder Safety Supervision Regulations".

5.2.2 Liquid argon shall comply with the relevant specifications of JB/T 5905,

JB/T 6897, JB/T 6898, and "Pressure Vessel Safety Supervision Regulations".

5.2.3 Pipe-transported gaseous argon shall comply with "Pressure Pipe Safety

Management and Supervision Regulations".

5.3 The finished product pressure of bottled argon at 20 °C is not less than

13.5 MPa. The precision of pressure gauges used for measurement is not less

In the formula.

V - Volume of gaseous argon converted from liquid argon. The unit is cubic

meter (m3);

m - Mass of liquid argon. The unit is kilogram (kg);

1.662 - Argon density. The unit is kilogram per cubic meter (kg/m3).

6.2 Calculation of gaseous argon volume

Calculation of gaseous argon volume refers to Appendix B.

Appendix A

(Normative)

Determination of hydrogen, oxygen, nitrogen, methane, carbon

monoxide, and carbon dioxide in argon

A.1 Instruments

USE the gas chromatography that is equipped with ion migration detector,

argon ionization detector or argon discharge ionization detector to determine

hydrogen, oxygen, nitrogen, methane, carbon monoxide, and carbon dioxide in

argon.

A.2 Principle

A.2.1 Principles of ion migration gas chromatography method

USE the argon gases of which the purity (volume fraction) is not less than

99.999 9% as carrier gases. The carrier gases will produce a steady

base-current in the detector that contains tritium source. When

diatomic-molecule (such as hydrogen, oxygen, nitrogen, etc.) components or

multi-atoms (such as carbon monoxide, carbon dioxide, etc.) components in

the sample gases enter into the detectors, the free electrons in the detectors

have a non-elastic collision with the molecules of these components. The

electrons lose energy. And these molecules are converted into the

corresponding ions. When the electrons' migration-speed along the direction of

anode increasing, the ions' migration-speed along the direction of cathode will

increase, too. APPLY a wave voltage between the 2 electrodes of the detector.

Within 1 period of the voltage, the electrons just pass through the detector. The

more electrons trapped by anode, the more electrons trapped by cathode, then

the more base-current produced by trapping electrodes. Within a certain

content range, impurity content in sample gases is...

......

......
This preview omits tables, figures, formulas and parts of the technical clauses. The complete document — 18 pages — is available in the English PDF.

Referenced standards

Cited by

How to Download GB/T 4842-2006

  1. 1

    Add to cart

    Click "Download PDF" on this page and choose "Buy this standard". You can add more standards before checkout.

  2. 2

    Checkout

    Enter your email and billing details. Payment is processed securely by Stripe (cards or bank transfer). Prefer bank details? Request a quotation (min. order $300).

  3. 3

    Instant delivery (0–9 sec)

    Delivery is automatic: within seconds of payment you'll receive an email with a secure download link. The link stays valid for 72 hours.

  4. 4

    Invoice included

    A tax invoice is attached to the confirmation email. Need a custom invoice? Contact us.

Related Standards

English PDF
18 pages
Instant delivery (0–9 sec)
Invoice included
View Cart

Secure payment via Stripe

Payments accepted

VisaMastercardAmerican ExpressApple PayGoogle PayStripe

GB/T 4842-2006

$55.00