GB/T 26396-2011Safety technical specification for soaps and detergents (English PDF)
洗涤用品安全技术规范
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Issued by
AQSIQ; SAC
Level / Type
National · Recommended
Issue date
May 12, 2011
Implementation date
November 1, 2011
Scope
GB/T 26396-2011 is the English-translated version of 洗涤用品安全技术规范.
China's national safety technical specification for soaps and detergents. The document covers the whole family of washing products made and sold in China and divides them by who and what they touch: detergents for food, food utensils and equipment; personal cleaning products such as soap, bath products and hand wash; and everything else, from laundry powder and liquid to kitchen, glass, floor and furniture cleaners, fabric softeners, bleaches and animal cleaning products. Two questions run through it. The first is what the product does to the person using it, which is why skin corrosion and sensitisation testing, preservative control and heavy metal limits are specified. The second is what it does after it goes down the drain: surfactants are the largest single load a household puts into wastewater, and the standard fixes the biodegradability that a surfactant must reach. It does not cover dry-cleaning products based on organic solvents nor certain industrial detergents made for special purposes.
Document preview — GB/T 26396-2011
National Standard of the People's Republic of China
- ICS
- 71.100.40
- Classification
- Y 43
Issued by: General Administration of Quality Supervision, Inspection and Quarantine; Standardization Administration of the PRC
Contents
- 1 Scope
- 2 Normative references
- 3 Terms and definitions
- 4 Product classification
- 5 Requirements
- 5.1 Basic requirements
- 5.2 Requirements for raw materials
- 5.2.1 General
- 5.2.2 Surfactants
- 5.2.2.1 Biodegradability
- 5.2.2.2 Harmful substances
- 5.2.3 Preservatives
- 6 Test methods
- 7 Inspection rules
Foreword
GB/T 26396-2011 was issued on 12 May 2011 by the General Administration of Quality Supervision, Inspection and Quarantine and the Standardization Administration of the People's Republic of China, and has been in force since 1 November 2011.
The document is a recommended national standard: the /T in the designation marks it as recommended rather than compulsory.
1 Scope
China's national safety technical specification for soaps and detergents. The document covers the whole family of washing products made and sold in China and divides them by who and what they touch: detergents for food, food utensils and equipment; personal cleaning products such as soap, bath products and hand wash; and everything else, from laundry powder and liquid to kitchen, glass, floor and furniture cleaners, fabric softeners, bleaches and animal cleaning products. Two questions run through it. The first is what the product does to the person using it, which is why skin corrosion and sensitisation testing, preservative control and heavy metal limits are specified. The second is what it does after it goes down the drain: surfactants are the largest single load a household puts into wastewater, and the standard fixes the biodegradability that a surfactant must reach. It does not cover dry-cleaning products based on organic solvents nor certain industrial detergents made for special purposes.
This standard specifies the terms and definitions, the product classification, the requirements, the test methods and the inspection rules for soaps and detergents.
This standard applies to soaps and detergents produced, sold and used within the territory of the People's Republic of China, including detergents for food, food utensils and equipment, detergents for personal cleaning, and detergents for other purposes.
This standard does not apply to dry-cleaning products whose principal component is an organic solvent, nor to certain industrial detergents manufactured for special purposes.
2 Normative references
The following documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies.
GB 9985 Detergent for hand dishwashing
GB 14930.1 Hygienic standard for detergents used for food utensils and equipment
GB/T 15818 Test method for biodegradability of surfactants
GB/T 21801 Chemicals - Ready biodegradability - Respirometric method
GB/T 21802 Chemicals - Ready biodegradability - Modified MITI test (I)
GB/T 21827 Chemicals - Skin sensitization test - Local lymph node assay
GB/T 21831 Chemicals - Ready biodegradability - Closed bottle test
GB/T 21856 Chemicals - Ready biodegradability - Carbon dioxide evolution test
GB/T 22731 Fragrances for daily use
QB/T 1505 Food flavours
QB/T 2951 Inspection rules for soaps and detergents
QB/T 2952 Marking and packaging requirements for soaps and detergents
SN/T 2245 Chemicals - In vitro skin corrosion - Human skin model test
SN/T 2246 Chemicals - In vitro skin corrosion - Transcutaneous electrical resistance test
Hygienic Standard for Cosmetics (2007 edition), Wei Jian Du Fa [2007] No. 1
3 Terms and definitions
For the purposes of this document, the following terms and definitions apply.
3.1 soaps and detergents - preparations containing soap and/or surfactant for the purpose of washing and cleaning. Note: soaps and detergents may be in any form (liquid, powder, paste, bar, block, flake and so on) and are placed on the market for household, public institutional or industrial use.
3.2 primary biodegradation - the change in the structure of a compound brought about by the action of micro-organisms, resulting in the loss of some of its properties.
3.3 ultimate biodegradation - the degradation of a compound or organic substance by micro-organisms in the presence of oxygen into carbon dioxide, water and mineral salts of the elements, together with its assimilation into part of the micro-organisms.
4 Product classification
Products are divided into three classes according to the object of use.
Class A: detergents for food, food utensils and equipment, including dishwashing detergents and fruit and vegetable detergents.
Class B: detergents for personal cleaning, including toilet soap, bath products and hand wash.
Class C: detergents for other articles, including laundry powder, laundry liquid, laundry soap, laundry soap powder, laundry paste, sanitary ware cleaners, kitchen cleaners, glass cleaners, floor cleaners, furniture cleaners, laundry detergents for commercial laundries, fabric softeners, bleaches and animal cleaning products.
5.1 Basic requirements
Under normal and reasonably foreseeable conditions of use, soaps and detergents shall not endanger human health or the safety of animals and plants, and the effect on the environment of the product and of its discharge after use shall be within an acceptable range.
The quality of soaps and detergents shall meet the requirements of the corresponding product standards and specifications.
5.2.1 General
The use of raw materials in soaps and detergents, including packaging materials, shall comply with the relevant national laws, regulations and standards.
5.2.2.1 Biodegradability
The surfactants used in soaps and detergents shall be chemicals confirmed to be degradable and, at the present level of scientific and technical knowledge, harmless in themselves and in their degradation products to animals, plants and the environment. The specific requirements are: a) the primary biodegradability of the surfactant shall be not lower than 90 %; b) where the primary biodegradability of the surfactant is lower than 90 % but not lower than 80 %, its ultimate biodegradability shall be not lower than 60 %.
Note: alkylphenol polyoxyethylene ethers and tetrapropylene benzene sulfonate are known to be surfactant varieties that should not be used in soaps and detergents.
5.2.2.2 Harmful substances
Harmful substances remaining in the finished product as a result of factors that cannot technically be avoided in the manufacture of the surfactant, such as the process and the raw materials, shall be at an acceptable safe level. The manufacturer of soaps and detergents shall ensure that, under normal application and at the present level of scientific and technical knowledge, the harmful substances brought into the product by the surfactant are below the concentration at which they would harm human health, the environment, or animals and plants.
5.2.3 Preservatives
The preservatives used in Class A products shall comply with the relevant provisions of GB 9985.
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This preview omits tables, figures, formulas and parts of the technical clauses. The complete document — 7 pages — is available in the English PDF.
Referenced standards
Normative references
- GB/T 15818 Test method for biodegradability of surfactantsTest method for the biodegradability of surfactants
- GB/T 21827 Chemicals - Skin sensitization test - Local lymph node assayChemicals - Test method of skin sensitization - Local lymph node assay
- GB/T 22731 Fragrances for daily useFragrance compound
GB 9985 Detergent for hand dishwashing · GB 14930.1 Hygienic standard for detergents used for food utensils and equipment · GB/T 21801 Chemicals - Ready biodegradability - Respirometric method · GB/T 21802 Chemicals - Ready biodegradability - Modified MITI test (I) · GB/T 21831 Chemicals - Ready biodegradability - Closed bottle test · GB/T 21856 Chemicals - Ready biodegradability - Carbon dioxide evolution test · QB/T 1505 Food flavours · QB/T 2951 Inspection rules for soaps and detergents · QB/T 2952 Marking and packaging requirements for soaps and detergents · SN/T 2245 Chemicals - In vitro skin corrosion - Human skin model test · SN/T 2246 Chemicals - In vitro skin corrosion - Transcutaneous electrical resistance test · Hygienic Standard for Cosmetics (2007 edition), Wei Jian Du Fa [2007] No. 1
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