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GB 5085.6-2007Identification standards for hazardous wastes Identification for toxic substance content (English PDF)

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Issued by

General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China, Standardization Administration of the People's Republic of China

Level / Type

National · Mandatory

Issue date

April 25, 2007

Implementation date

October 1, 2007

Scope

GB 5085.6-2007 (Identification standards for hazardous wastes Identification for toxic substance content) is available as an English-translated PDF.

GB 5085.6-2007 — This standard specifies the criteria to identify hazardous wastes containing toxic, carcinogenic, mutagenic and reproductive toxic substances. Identification of the content of toxic substances This standard applies to any production, life and other activities generated solid waste.

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Document preview — GB 5085.6-2007

National Standard of the People's Republic of China

ICS
13.030.50
Classification
Z 70

Issued by: General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China, Standardization Administration of the People's Republic of China

Contents

  • 5 experimental method ..3
  • 6 Standards ..3

Foreword

To implement the "People's Republic of China Environmental Protection Law" and "People's Republic of China Solid Waste Pollution Prevention Law"

Environmental pollution prevention caused by hazardous waste, strengthen the management of hazardous waste, protect the environment, protect human health, the development of

This standard.

This standard is part of the national hazardous waste identification standard. National hazardous waste identification standard solid waste

Hazardous characteristics Technical indicators hazardous characteristics standard technical specifications of solid waste are hazardous waste, required by law

Hazardous waste management. National Hazardous Waste Identification standard consists of the following seven criteria consists of.

1, hazardous waste identification standard General

2 Identification standard for hazardous wastes Identification corrosion

3, hazardous waste identification standard acute toxicity screening

4 Identification of hazardous waste leaching toxic identification standard

5 Identification standard for hazardous wastes Identification Flammability

6, hazardous waste identification standard differential reactivity

7, hazardous waste identification standard differential toxic substance content

This standard is the new part.

According to relevant laws and regulations, the standard shall be enforceable.

This standard was proposed by the State Environmental Protection Administration of Science, Technology.

This standard was drafted. Chinese Research Academy of Environmental Sciences, Institute of solid waste pollution control technology, environmental standards research

The,

This standard SEPA March 27, 2007 for approval.

This standard since October 1, 2007 implementation.

This standard is interpreted by the State Environmental Protection Administration.

Identification standard for hazardous wastes Identification content of toxic substances

1 Scope

This standard specifies the criteria to identify hazardous wastes containing toxic, carcinogenic, mutagenic and reproductive toxic substances.

Identification of the content of toxic substances This standard applies to any production, life and other activities generated solid waste.

2 Normative references

The following documents contain provisions which, through GB 5085 of this standard reference and become the standard terms. Undated

Reference documents, the latest versions apply to this standard.

HJ/T 298 Identification of Hazardous Waste Technical Specifications

3 Terms and Definitions

The following terms and definitions apply to this standard.

3.1

Acutely toxic substance toxic substance

It has a very strong toxicity of hazardous chemicals, including synthetic chemicals and natural toxins, and mixtures thereof.

3.2

Toxic substance toxic substance

After ingestion, inhalation or skin may cause death or serious material damage to health after exposure.

3.3

Carcinogenic carcinogenic substance

Substance can cause cancer or increase the cancer incidence.

3.4

Mutagenic substance mutagenic substance

It can cause mutations in human germ cells and can be inherited substance.

3.5

Reproductive toxic substances reproductive toxic substance

Have a detrimental effect on adult male or female sexual function and fertility and offspring development substances.

3.6

POPs persistent organic pollutants

Toxic, biodegradable and bio-accumulation and other characteristics, by air, water and migratory species migrate long distances and Shen

Accumulated during the deposition to terrestrial ecosystems and aquatic ecosystems accumulated organic chemicals.

Identification standard 4

One of the following conditions are solid waste is hazardous waste.

Appendix A contains 4.1 total content of one or more toxic substance >=0.1% of this standard;

4.2 This standard contains a total content of Appendix B of one or more toxic substances >=3%;

4.3 This standard contains a total content of Appendix C of one or more carcinogenic substances >=0.1%;

4.4 This standard contains a total content of Appendix D of one or more mutagenic substances >=0.1%;

4.5 This standard contains a total content of Appendix E of one or more substances toxic for reproduction of >=0.5%;

4.6 This standard contains Appendices A to E of two or more different toxic substances, if the following equation, in accordance with

Hazardous Waste Management.

1)] [(>= sum

Tera

Tera

Muta

Muta

Carc

Carc

Where.

PT - content of toxic substances in solid waste;

PT - content of toxic substances in solid waste;

PCarc - content of the solid waste carcinogenic substances;

Content PMuta-- solid waste mutagenic substances;

PTera - reproductive toxicity content of the solid waste material;

LT, LT, LCarc, LMuta, LTera-- are standard values for various toxic substances prescribed in 4.1 to 4.5.

4.7 F containing any one of the persistent organic pollutants (except polychlorinated dibenzo-p-dioxins appendix to this standard, polychlorinated

Benzofuran outside) content of >=50 mg/kg;

4.8 content containing polychlorinated dibenzo-p-dioxins and polychlorinated dibenzofurans >=15 µg TEQ/kg.

5 Experimental Method

5.1 sampling sites and sampling methods according to HJ/298 performed.

5.2 Samples of inorganic elements and their compounds (except hexavalent chromium, inorganic fluorides, cyanides outside) pre-treatment methods, see

GB 5085.3 Appendix S; sample pretreatment method hexavalent chromium and its compounds with reference to GB 5085.3 Appendix T.

5.3 Sample pretreatment methods of organic reference GB 5085.3 Appendix U, Appendix V, W and the appendix of this standard Appendix G.

5.4 Determination of various toxic substances, in addition to implementation of the provisions of the standard analytical methods, the method specified in Appendix Zanan execution;

After the national environmental protection standards to be applied to measuring specific release of toxic substances, according to the standard implementation of the provisions.

6 Standards

This standard by the people's governments above the county level environmental protection administrative department responsible for overseeing implementation.

Appendix A List of highly toxic substances

Chinese name English name alias No. Chemical name CAS Number Analysis

1 thiophenol thiophenol; benzenethiol Thiophenol; Benzenethiol 108-98-5 GB 5085.3 Appendix K

Acetone cyanohydrin 2 hydroxy-2-methyl-propionitrile; 2-

Hydroxy-isobutyronitrile

Acetone cyanohydrin;

2-Hydroxy-2-methylpropionitrile;

2-Hydroxuisobutyronitrile

75-86-5 GB 5085.3 Appendix O

2- 3 acrolein acrolein; lose fat aldehyde Acrolein; 2-Propenal 107-02-8 GB 5085.3 Appendix O

4 acrylate, 2-acrylic acid Acrylic acid; 2-Propenoic acid 79-10-7 GB 5085.3 Appendix I

5 carbofuran Wei Kaba furan; 2,3-dihydro-2,2

Dimethyl-7-benzofuranyl

-N- Methylcarbamate

Furadan; Carbofuran;

2,2-Dimethyl-2,3-dihydro-7-benzofuran

yl N-methylcarbamate

1563-66-2

GB 5085.3 attached

Record K,

Appendix H of this standard

6 high mercury iodide, mercury iodide; diiodide mercury Mercuric iodide; Mercury diiodide 7774-29-0 GB 5085.3 Appendix B

7 thallium iodide, thallium iodide; a thallium iodide Thallium iodide; Thallous iodide

7790-30-9

GB 5085.3 attached

Record A, B, C,

8 dinitro-o-cresol methyl-4,6-dinitrophenol Dinitro-ortho-cresol;

2-Methyl-4,6-dinitrophenol 534-52-1

GB 5085.3 attached

Record K

9 selenite selenium dioxide Selenium dioxide; Selenious acid 7783-00-8 GB 5085.3 Appendix B, C, E

10 phorate O, O - diethyl -S- (ethylthio

Methyl) phosphorodithioate; three

Nine hundred eleven

Phorate; O, O-Diethyl

S- (ethylthio) methyl phosphorodithioate 298-02-2 GB 5085.3 Appendix I, K, L

11 phosphamidon chloro-2-diethylcarbamoyl

Methylethenyl dimethylphosphorane

Esters; large pest control

Phosphamidon;

2-Chloro-2-diethylcarbamoyl-1-methylv

inyl dimethylphosphate

13171-21-6 GB 5085.3 Appendix I, K

12 mercuricthiocyanate two mercuricthiocyanate Mercuric thiocyanate; Mercury

dithiocyanate 592-85-8

GB 5085.3 attached

Appendix B

13 mercuric chloride mercury chloride (II); mercuric chloride Mercuric chloride; Mercury (II) chloride;

Mercury dichloride 7487-94-7

GB 5085.3 attached

Appendix B

14 selenium chloride monochloride selenium Selenium chloride; Selenium

monochloride; 10025-68-0

GB 5085.3 attached

Record B, C, E

15 thallium chloride, thallium chloride Thallous chloride; Thallium chloride

7791-12-0

GB 5085.3 attached

Record A, B, C,

Methomyl 16 1- (methylthio) ethylene ammonia

Methylcarbamate; Off

Buggy; off voioe

Methomyl;

1- (Methylthio) ethylideneamino

methylcarbamate

16752-77-5

GB 5085.3 attached

Record L,

Appendix H of this standard

17 two cyanide barium cyanide Ba Barium cyanide; Barium dicyanide 542-62-1 GB 5085.3 Appendix G

18 calcium cyanide - Calcium cyanide; Calcyanide 592-01-8 GB 5085.3 Appendix G

19 two mercury cyanide cyanide mercury Mercuric cyanide; Mercury dicyanide 592-04-1 GB 5085.3 Appendix G

20 potassium cyanide hydrocyanic acid potassium salt; kaempferol potassium Potassium cyanide; Hydrocyanic acid,

Potassium salt 151-50-8

GB 5085.3 attached

Record G

21 hydrocyanic acid sodium salt; kaempferol; Mountain

Sodium Chennai

Sodium cyanide;

Hydrocyanic acid, sodium salt 143-33-9

GB 5085.3 attached

Record G

22 two zinc cyanide zinc cyanide Zinc cyanide; Zinc dicyanide 557-21-1 GB 5085.3 Appendix G

Chinese name English name alias No. Chemical name CAS Number Analysis

23 cyanide cuprous cyanide copper (I) Cuprous cyanide; Copper (I) cyanide 544-92-3 GB 5085.3 Appendix G

24 copper cyanide, sodium cyanide, sodium copper; copper salt Sodium cuprocyanide; Copper sodium

cyanide 14264-31-4

GB 5085.3 attached

Record G

25 silver cyanide silver cyanide (1) Silver cyanide; Silver (1) cyanide 506-64-9 GB 5085.3 Appendix G

26 triiodide Arsenic iodide Arsenic Arsenic triiodide; Arsenous iodide 7784-45-4 GB 5085.3 Appendix C, E

27 arsenic trichloride chloride arsenite Arsenic trichloride; Arsenous chloride 7784-34-1 GB 5085.3 Appendix C, E

28 arsenite (elemental arsenic

Objective analysis to the compound

Basis)

Original sodium arsenate; arsenic acid trisodium salt Sodium arsenate; Arsenic acid, trisodium

salt 7631-89-2 GB 5085.3 Appendix C, E

29 tetraethyl lead - Lead tetraethyl; Plumbane, tetraethyl-

78-00-2

GB 5085.3 attached

Record A, B, C,

30 thallium metal thallium Thallium; Thallium metal

7440-28-0

GB 5085.3 attached

Record A, B, C,

31 carbon chlorine spirit octachlorohepta hexahydro methylene isobenzofuran

Furan; carbon chlorine Trane

Isobenzan;

Octachloro-hexahydro-methanoisobenzo

furan

297-78-9 GB 5085.3 Appendix K

32 nickel carbonyl nickel tetracarbonyl Nickel carbonyl; Nickel tetracarbonyl

13463-39-3

GB 5085.3 attached

Record A, B, C,

33 Aldicarb methyl-2- (methylthio

Yl) -O - ((methylamino) methyl group)

Oxime; aldicarb; tears

Mieke

Aldicarb; Propanal,

2-methyl-2- (methylthio) -,

O - ((methylamino) carbonyl) oxime 116-06-C Appendix H of this standard

34 CdSe - Cadmium selenide

1C06-24-7

GB 5085.C attached

Record A, B, C,

35 mercurous nitrate mercuric nitrate (monohydrate) Mercurous nitrate;

Mercurous nitrate (monohydrate) 7782-86-7

GB 5085.3 attached

Appendix B

Thallium bromide 36 - Thallous bromide

7789-40-4

GB 5085.3 attached

Record A, B, C,

37 tellurite sodium (as elemental tellurium

In order to analyze the goal, that of

Compound meter)

Three oxygen telluric acid disodium Sodium tellurite; Disodium

trioxotellurate 10102-20-2 GB 5085.3 Appendix B

Arsenite 38 Asia (elemental arsenic

In order to analyze the goal, that of

Compound meter)

Sodium arsenite; partial arsenite

Sodium arsenite; Arsenenous acid,

sodium salt; Sodium metaarsenite 7784-46-5 GB 5085.3 Appendix C, E

39 Nicotine Nicotine; 1-methyl-2- (3-pyrazol

Piperidyl) pyrrolidine

Pyridine; Nicotine;

1-Methyl-2- (3-pyridyl) pyrrolidine 54-11-5

GB 5085.3 attached

Record K

Appendix B List of Toxic Substances

No. Chinese name

Alias English name Chemical name CAS Number Analysis

1 aminotriazole amitrole Aminotriazole; Amitrole 61-82-5 Appendix I of this standard

2 palladium sponge (like) palladium Palladium; Palladium sponge 7440-05-3 GB 5085.3 Appendix B

3 paraquat 1,1-dimethyl-4,4 - bipyridine

Dichloride; paraquat

Paraquat; 4,4'-Bipyridinium,

1,1'-dimethyl-, dichloride 1910-42-5 this standard appendix A0

4 chlorothalonil 2,4,5,6-tetrachloro-1,3-isophthalonitrile Chlorothalonil;

1,3-Benzenedicarbonitrile,

2,4,5,6-tetrachloro-

1897-45-6 GB 5085.3 Appendix H, K

5 fenthion O, O- dimethyl methylthio -O-4-

Intergenerational tolyl phosphorothioate

Ester; one hundred rule Tu; Fan parathion

Fenthion;

O, O-Dimethyl O-4-methylthio-m-tolyl

phosphorothioate

55-38-9 GB 5085.3 Appendix I, K

6 aniline amino benzene Aniline; Aminobenzene; Benzeneamine 62-53-3 Appendix K of this standard

7 1,4-phenylenediamine p-phenylene diamine;

1,4-diaminobenzene

1,4-Phenylenediamine;

p- Phenylenediamine;

1,4-Diaminobenzene

106-50-3 GB 5085.3 Appendix K

8 1,3-hydroquinone, resorcinol; resorcinol 1,3-Benzenediol; m-Benzenediol;

Resorcin 108-46-3

GB 5085.3 attached

Record K

9 1,4-hydroquinone hydroquinone; hydroquinone 1,4-Benzenediol; p-Benzenediol;

Hydroquinone; 123-31-9

GB 5085.3 attached

Record K

10 phenylhydrazine hydrazine benzene Phenylhydrazine; Hydrazobenzene 100-63-0 GB 5085.3 Appendix K

11 Benomyl benzene to special Benomyl; Benlate 17804-35-2 GB 5085.3 Appendix L

12 benzoquinone benzoquinone;

1,4-cyclohexadiene-dione

Quinone; p-Quinone;

1,4-Cyclohexadienedione 106-51-4

GB 5085.3 attached

Record K

13 Styrene divinylbenzene Styrene; Vinyl benzene 100-42-5 GB 5085.3 Appendix O, P

14 epichlorohydrin 1-chloro-2,3-propylene oxide; ethylene

Chloropropane

Epichlorohydrin;

1-Chloro-2,3-epoxypropane 106-89-8

GB 5085.3 attached

Record O, P

15 Acetone 2-propanone Acetone; 2-Propanone 67-64-1 GB 5085.3 Appendix O

16 platinum sponge (like) platinum; platinum Platinum; Platinum sponge 7440-06-4 GB 5085.3 Appendix B

17 Glyphosate N- (phosphorus) glycine; town

Glyphosate

Glyphosate;

N- (Phosphonomethyl) glycine 1071-83-6 The Standard Appendix L

18 Diflubenzuron 1- (4-chlorophenyl) -3- (2,6-difluoro

Benzoyl) urea; V urea kill,

Insecticidal urea, di-fluorouracil

Diflubenzuron;

1- (4-Chlorophenyl) -3- (2,6-difluorobenz

oyl) urea

35367-38-5 The Standard Appendix M

19 2,4 (content > 75%) of 2,4-dichlorophenoxyacetic acid 2,4-D (content > 75%);

2,4-Dichlorophenoxyacetic acid 94-75-7

GB 5085.3 attached

Record L,

The Standard Appendix N

Trichlorfon 20 Dimethyl (2,2,2-trichloro-1-hydroxyethyl

Yl-ethyl) phosphonate

Trichlorfon;

Dimethyl (2,2,2-trichloro-1-hydroxyethy

l) phosphonate

52-68-6 GB 5085.3 Appendix I, L

21 diquat diquat; 1,1'-ethylidene -

2,2'-dibromo pyridine salt

Diquat; Diquat dibromide; 1,1'-Ethylene

2,2'-bipyridylium dibromide 85-00-7 Appendix J of this standard

Diuron 22 N- (3,4- dichloro-phenyl) -N ', N'-

Dimethylurea

Diuron;

N- (3,4-Dichlorophenyl) -N ', N'-dimethyl

urea 330-54-1

GB 5085.3 attached

Record L,

This standard appendix

23 dichlorvos O, O - dimethyl - O - (2,2-

Dichlorophenyl) vinyl phosphate

Dichlorvos;

O, O-Dimethyl-O- (2,2-dichloro) vinyl

phosphate

62-73-7 GB 5085.3 Appendix I, K, L

No. Chinese name

Alias English name Chemical name CAS Number Analysis

241- butanol butanol 1-Butanol; n-Butanol 71-36-3 GB 5085.3 Appendix O

252- butanol, sec-butanol 2-Butanol; sec-Butanol 78-92-2 GB 5085.3 Appendix O

Iso-propanol, butanol, 2-methyl Isobutanol; 2-Methyl propanol 78-83-1 GB 5085.3 Appendix O

1,1-dimethyl ethanol, tert-butanol tert-Butyl alcohol; 1,1-Dimethylethanol 75-65-0 GB 5085.3 Appendix O

27 propachlor -N- isopropyl-2-chloro-acetanilide Propachlor;

2-Chloro-N-isopropylacetanilide 1918-16-7

GB 5085.3 attached

L record

28 Carbendazim Cotton Xiaoweiling Carbendazim; Carbendazol 4697-36-3 GB 5085.3 Appendix L

Over 29, barium sulfide, barium sulfide; sulfur mixture of barium Barium polysulfide; Barium sulfide

50864-67-0

GB 5085.3 attached

Record A, B, C,

30 1,1-diphenyl hydrazine N, N- diphenyl linked amine 1,1-Diphenylhydrazine;

N, N-Diphenylhydrazine 530-50-7

GB 5085.3 attached

Record K

31 N, N- dimethylaniline (dimethylamino) benzene, N, N-Dimethylaniline;

(Dimethylamino) benzene 121-69-7

GB 5085.3 attached

Record K

32 dimethylphenol xylenol Dimethyl phenol; Xylenol 1300-71-6 GB 5085.3 Appendix K

33 dimethylformamide N, N- Dimethylformamide dimethyl formamide;

N, N-Dimethylformamide 68-12-2

GB 5085.3 attached

Record K

34 o-dichlorobenzene, 1,2-dichlorobenzene 1,2-Dichlorobenzene;

o-Dichlorobenzene 95-50-1

GB 5085.3 attached

Record K, O, P,

35 1,3-dichlorobenzene-dichlorobenzene 1,3-Dichlorobenzene;

m-Dichlorobenzene 541-73-1

GB 5085.3 attached

Record K, O, P,

36 1,4-dichlorobenzene dichlorobenzene 1,4-Dichlorobenzene;

p-Dichlorobenzene 106-46-7

GB 5085.3 attached

Record K, O, P,

37 2,4-dichloro-aniline 2,4-DCA 2,4-Dichloroaniline;

2,4-Dichlorobenzenamine 554-00-7 of the Standard Appendix K

38 2,5-dichloro-aniline to dichloroaniline 2,5-Dichloroaniline; p-Dichloroaniline 95-82-9 Appendix K of this standard

39 2,6-dichloro-aniline - 2,6-Dichloroaniline;

Benzenamine, 2,6-dichloro- 608-31-1 of the Standard Appendix K

40 aniline 1-amino-3,4-dichloro-3,4-dichlorobenzene 3,4-Dichloroaniline;

1-Amino-3,4-dichlorobenzene 95-76-1 Appendix K of this standard

41 3,5-dichloro-aniline 3,5-DCA 3,5-Dichloroaniline;

Benzenamine, 3,5-dichloro- 626-43-7 of the Standard Appendix K

42 1,3-D, 1,2

Dichloropropane and mixtures

Didi Mixture; chloropropyl Mixture 1,3-Dichloropropene,

1,2-dichloropropane and mixtures 542-75-6

78-87-5

GB 5085.3 attached

Record O, P

43 2,4-dichloro-1-2,4-dichlorotoluene toluene 2,4-Dichlorotoluene;

Benzene, 2,4-dichloro-1-methyl- 95-73-8

GB 5085.3 attached

Record K, O, P,

44 2,5-Dichloro-1,4-dichloro-2-methylbenzene toluene 2,5-Dichlorotoluene;

Benzene, 1,4-dichloro-2-methyl- 19398-61-9

GB 5085.3 attached

Record K, O, P,

45 3,4-dichloro-1,2-dichloro-4-toluene toluene 3,4-Dichlorotoluene;

Benzene, 1,2-dichloro-4-methyl- 95-75-0

GB 5085.3 attached

Record K, O, P,

46 dichloromethane methylene chlorine Dichloromethane; Methylene chloride 75-09-2 GB 5085.3 Appendix O, P

47 Diazinon Diazinon; Diazinon Diazinon; Diazide 333-41-5 GB 5085.3 Appendix I

No. Chinese name

Alias English name Chemical name CAS Number Analysis

48 1,2-nitrobenzene o-nitrophenyl 1,2-Dinitrobenzene;

o- Dinitrobenzene 528-29-0

GB 5085.3 attached

Record K

49 1,3 two nitrobenzene dinitrobenzene 1,3-Dinitrobenzene; m-Dinitrobenzene 99-65-0 GB 5085.3 Appendix J, K

50 1,4-dinitrobenzene for dinitrobenzene 1,4- Dinitrobenzene; p- Dinitrobenzene 100-25-4 GB 5085.3 Appendix K

Room 51 2,4-dinitroaniline dinitroaniline 2,4-Dinitroaniline; m-Dinitroaniline

97-02-9

GB 5085.3 attached

Record K,

The Standard Appendix K

52 dinitroaniline 2,6-dinitroaniline 2,6-Dinitroaniline; Dinitrobenzenamine

606-22-4

GB 5085.3 attached

Record K,

The Standard Appendix K

53 1,2-dibromoethane ethylene dibromide 1,2-Dibromoethane; Ethylene dibromide 106-93-4 GB 5085.3 Appendix O, P

54 dust Vanadium Vanadium Vanadium; Vanadium dust

7440-62-2

GB 5085.3 attached

Record A, B, C,

55 aluminum fluoride, aluminum trifluoride Aluminium fluoride; Aluminium

trifluoride 7784-18-1

GB 5085.3 attached

Record F

56 a sodium fluoride Sodium fluoride; Sodium monofluoride 7681-49-4 GB 5085.3 Appendix F

57 lead fluoride two lead fluoride Lead fluoride; Lead difluoride 7783-46-2 GB 5085.3 Appendix F

58 zinc fluoride difluoride zinc Zinc fluoride; Zinc diflu...

END: Draft Version (GB 5085.6-2007)

......
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