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GB/T 6285-2016Determination of trace oxygen in gases—Electrochemical method (English PDF)

气体中微量氧的测定 电化学法

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Issued by

SAMR; SAC

Level / Type

National · Recommended

Issue date

December 13, 2016

Implementation date

July 1, 2017

Scope

GB/T 6285-2016 is the English-translated version of 气体中微量氧的测定 电化学法.

GB/T 6285-2016 is the Chinese standard "Determination of trace oxygen in gases—Electrochemical method".

Its scope clause reads: This standard specifies the use of electrochemical method for the determination of trace oxygen in the gas, including fuel cell method, Hertz battery method, zirconia concentration Battery, ion flow, the original battery method, the instrument, calibration, test procedures, the results of processing and test reports made a request.

This standard applies to gases that do not react chemically with the chemical cell and do not interfere with the measurement. Measurement range. 0.01 × 10-6 (volume points Number) to 1000 × 10-6 (volume fraction). Its clauses include normative reference documents; principle.

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Document preview — GB/T 6285-2016

National Standard of the People's Republic of China

ICS
71.040.40
Classification
G 86
Replacing
GB/T 6285-2003

Issued by: State Administration for Market Regulation; Standardization Administration of the PRC

Contents

  • 1 Scope
  • 2 normative reference documents
  • 3 principle
  • 3.1 Overview
  • 3.2 fuel cell method
  • 3.3 Hz battery method

1 Scope

This standard specifies the use of electrochemical method for the determination of trace oxygen in the gas, including fuel cell method, Hertz battery method, zirconia concentration

Battery, ion flow, the original battery method, the instrument, calibration, test procedures, the results of processing and test reports made a request.

This standard applies to gases that do not react chemically with the chemical cell and do not interfere with the measurement. Measurement range. 0.01 × 10-6 (volume points

Number) to 1000 × 10-6 (volume fraction).

2 normative reference documents

The following documents are indispensable for the application of this document. For dated references, only the dated edition applies to this article

Pieces. For undated references, the latest edition (including all modifications) applies to this document.

General rules for sampling safety of industrial chemical products GB/T 3723

GB/T 5274 Preparation of gas mixtures for gas analysis calibration

GB/T 5275.11 Gas analysis - Dynamic volume method for the preparation of calibrated gas mixtures - Part 11. Electrochemical generation method

GB/T 33360 Gas analysis - Guidelines for gas purification for trace analysis

3 principle

3.1 Overview

The use of chemical batteries as a measure of oxygen in the gas sensor.

The gas to be measured in the appropriate form into the chemical battery, according to the oxygen in the chemical oxygen in the chemical characteristics of the battery, by measuring and oxygen

Content of a chemical function to determine the relationship between the potential of the chemical battery, or current, or conductivity and other physical quantities, to achieve the gas in the measured gas analysis

Determination.

3.2 fuel cell method

The battery used in the fuel cell method is a closed chemical charge consisting of an inert metal electrode (cathode), a lead electrode (anode) and an electrolyte

Pool. Oxygen in the gas diffuses into the cell through the polymer film, is reduced in the cathodic oxygen, and is oxidized at the anode lead. The battery reacts to electricity

The output signal of the flow sensor is proportional to the oxygen content in the gas.

The electrolyte of this type of equipment is acidic and alkaline two kinds of alkaline electrolyte is not suitable for the determination of trace oxygen in acidic gases, acidic

The solution is not suitable for the determination of trace oxygen in alkaline gases.

3.3 Hz battery method

The Hertz battery method uses a chemical cell consisting of a carbon alloy (cathode), a platinum wire (anode), and an electrolyte. Apply to the battery

Plus a DC voltage to provide electron transfer energy. The current generated by the battery reaction is the size of the sensor output signal and the oxygen content in the gas

Proportional.

This type of instrument is suitable for the determination of trace oxygen in inert and inactive gases, including hydrogen, nitrogen, carbon monoxide, freon, carbon

Compounds and so on.

......
This preview omits tables, figures, formulas and parts of the technical clauses. The complete document — 15 pages — is available in the English PDF.

Referenced standards

Similar standards

Editions of GB/T 6285

EditionTitleRevisionStatus
GB/T 6285-2016Determination of trace oxygen in gases—Electrochemical methodcurrent editionCurrent
GB/T 6285-2003Determination of trace oxygen in gases—Electrochemical methodprevious editionSuperseded

This page sells the current edition, GB/T 6285-2016. Earlier editions are listed for reference only.

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