GB/T 5750.6-2023Standard examination methods for drinking water—Part 6: Metal and metalloid indices (English PDF)
生活饮用水标准检验方法 第6部分:金属和类金属指标
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Issued by
SAMR; SAC
Level / Type
National · Recommended
Issue date
March 17, 2023
Implementation date
October 1, 2023
Scope
GB/T 5750.6-2023 is the English-translated version of 生活饮用水标准检验方法 第6部分:金属和类金属指标.
GB/T 5750.6-2023 is Part 6 of GB/T 5750 and holds the Chinese national examination methods for the metal and metalloid indices of drinking water.
It gives determination methods for aluminium, iron, manganese, copper, zinc, arsenic, selenium, mercury, cadmium, hexavalent chromium, lead, silver, molybdenum, cobalt, nickel, barium, titanium, vanadium, antimony, beryllium, thallium, sodium, tin, tetraethyl lead, ethylmercuric chloride, boron and asbestos, each clause setting out the minimum detection concentration, the interferences, the principle, the reagents and the procedure.
Its foreword records ten test methods added, one changed and thirteen deleted against the 2006 edition. Clause 1 applies it to drinking water and source water. It replaces GB/T 5750.6-2006, was issued on 17 March 2023 and has applied since 1 October 2023.
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Document preview — GB/T 5750.6-2023
National Standard of the People's Republic of China
- ICS
- 13.060
- Classification
- C 51
- Replacing
- GB/T 5750.6-2006
Issued by: State Administration for Market Regulation; Standardization Administration of the PRC
Contents
- Preface
- Introduction
- 1 Scope
- 2 Normative references
- 3 Terms and Definitions
- 4 Aluminum
- 5 Iron
- 6 Manganese
- 7 Bronze
- 8 Zinc
- 9 Arsenic
- 10 Selenium
- 11 Mercury
- 12 Cadmium
- 13 Chromium (hexavalent)
- 14 Lead
- 15 Silver
- 16 Molybdenum
- 17 Cobalt
- 18 Nickel
- 19 Barium
- 20 Titanium
- 21 Vanadium
- 22 Antimony
- 23 Beryllium
- 24 Thallium
- 25 Sodium
- 26 Tin
- 27 Tetraethyl lead
- 28 Ethyl mercury chloride
- 29 Boron
- 30 Asbestos
Foreword
This document is in accordance with the provisions of GB/T 1.1-2020 "Guidelines for standardization work Part 1: Structure and drafting rules for standardization documents" Drafting.
This document is part 6 of GB/T 5750 "Standard test methods for drinking water". GB/T 5750 has been published in the following parts.
--- Part 1: General;
--- Part 2: Collection and preservation of water samples;
--- Part 3: Water quality analysis quality control;
--- Part 4: Sensory properties and physical indicators;
--- Part 5: Inorganic non-metallic indicators;
--- Part 6: Metal and metalloid indicators;
--- Part 7: Comprehensive indicators of organic matter;
--- Part 8: Organic matter indicators;
--- Part 9: Pesticide indicators;
--- Part 10: Disinfection by-product indicators;
--- Part 11: Disinfectant indicators;
--- Part 12: Microbiological indicators;
--- Part 13: Radioactivity indicators.
This document replaces GB/T 5750.6-2006 "Standard test methods for metal indicators of drinking water" and is consistent with GB/T 5750.6-2006 Compared with the previous version, in addition to structural adjustments and editorial changes, the main technical changes are as follows.
a) Added "Terms and Definitions" (see Chapter 3);
b) 10 test methods were added (see 9.5, 9.6, 10.5, 13.2, 28.1, 28.2, 28.3, 29.1, 30.1, 30.2);
c) One test method was changed (see 4.5, 1.5 of the 2006 edition);
d) 13 test methods were deleted (see 4.2.2, 4.2.3, 4.2.4, 5.2, 5.4, 6.4, 7.4, 7.5, 9.3, 11.3, 11.4, 17.1, 20.3).
Introduction
GB/T 5750 "Standard Test Methods for Drinking Water" is a recommended national standard for drinking water testing technology.
The supporting work of the "Sanitary Standard for Drinking Water" is an important technical support for GB 5749, and is an important technical support for the implementation of GB 5749 and the development of the sanitation of drinking water. Safety evaluation provides testing methods.
GB/T 5750 consists of 13 parts.
--- Part 1: General. The purpose is to provide the basic principles and requirements for water quality inspection.
--- Part 2: Collection and preservation of water samples. The purpose is to provide a basis for water sample collection, preservation, management, transportation and sampling quality control. These principles, measures and requirements.
--- Part 3: Water quality analysis quality control. The purpose is to provide quality control requirements and methods for water quality inspection and testing laboratories.
--- Part 4: Sensory properties and physical indicators. The purpose is to provide corresponding test methods for sensory properties and physical indicators.
--- Part 5: Inorganic non-metallic indicators. The purpose is to provide corresponding test methods for inorganic non-metallic indicators.
--- Part 6: Metal and metalloid indicators. The purpose is to provide corresponding test methods for metal and metalloid indicators.
--- Part 7: Comprehensive indicators of organic matter. The purpose is to provide corresponding test methods for comprehensive indicators of organic matter.
--- Part 8: Organic matter indicators. The purpose is to provide corresponding test methods for organic matter indicators.
--- Part 9: Pesticide indicators. The purpose is to provide corresponding test methods for pesticide indicators.
--- Part 10: Disinfection by-product indicators. The purpose is to provide the corresponding test methods for disinfection by-product indicators.
--- Part 11: Disinfectant indicators. The purpose is to provide the corresponding test methods for disinfectant indicators.
--- Part 12: Microbiological indicators. The purpose is to provide corresponding test methods for microbiological indicators.
--- Part 13: Radioactive indicators. The purpose is to provide the corresponding test methods for radioactive indicators.
1 Scope
This document describes the content of aluminum, iron, manganese, copper, zinc, arsenic, selenium, mercury, cadmium, chromium (hexavalent), lead, silver, molybdenum, cobalt, nickel, barium, titanium, vanadium, Determination methods for antimony, beryllium, thallium, sodium, tin, tetraethyl lead, ethyl mercuric chloride, boron, asbestos and determination methods for aluminum, iron, manganese, copper, zinc, arsenic, selenium, mercury, Cadmium, chromium (hexavalent), lead, silver, molybdenum, cobalt, nickel, barium, titanium, vanadium, antimony, beryllium, thallium, sodium, tin, tetraethyl lead, ethylmercuric chloride (purge and trap gas chromatography- Atomic fluorescence spectrometry), boron and asbestos determination methods.
This document is applicable to the determination of metal and metalloid indicators in drinking water and source water.
2 Normative references
The contents of the following documents constitute the essential clauses of this document through normative references in this document.
For referenced documents without a date, only the version corresponding to that date applies to this document; for referenced documents without a date, the latest version (including all amendments) applies to this document.
GB/T 5750.1 Standard test methods for drinking water Part 1: General
GB/T 5750.3-2023 Standard test methods for drinking water Part 3: Quality control of water quality analysis
GB/T 5750.5-2023 Standard test methods for drinking water Part 5: Inorganic non-metallic indicators
GB/T 6682 Specifications and test methods for water used in analytical laboratories
3 Terms and definitions
The terms and definitions defined in GB/T 5750.1 and GB/T 5750.3-2023 apply to this document.
4 Aluminum
4.1 Chrome Azure S spectrophotometry
4.1.1 Minimum detection concentration
The minimum detection mass of this method is 0.20µg. If 25mL of water sample is taken, the minimum detection mass concentration is 0.008mg/L.
Copper, manganese and iron in water interfere with the determination. 1mL ascorbic acid (100g/L) can eliminate the interference of 25µg copper and 30µg manganese. 2mL thiol Acetic acid (10 g/L) can eliminate the interference of 25 µg of iron.
4.1.2 Principle
In the pH range of 6.7 to 7.0, aluminum reacted with octylphenyl ether (OP) and cetylpyridinium bromide (CPB).
Chrome azure S reacts to form blue-green quaternary micelles, which are quantified by colorimetry.
4.1.3 Reagents
4.1.3.1 Chrome azuro blue S solution (1 g/L). weigh 0.1 g of Chrome azuro blue S (C23H13O9SCl2Na3) and dissolve it in 100 mL of ethanol solution (1 1)
......
This preview omits tables, figures, formulas and parts of the technical clauses. The complete document — 104 pages — is available in the English PDF.
Referenced standards
Normative references
- GB/T 5750.1Standard examination methods for drinking water - Part 1: General principles
- GB/T 5750.3-2023Standard examination methods for drinking water—Part 3: Water analysis quality control
- GB/T 5750.5-2023Standard examination methods for drinking water—Part 5: Inorganic nonmetallic indices
- GB/T 6682Water for analytical laboratory use - Specification and test methods
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- RB/T 138-2023Technical specifications for the certification of selenium-enriched product
- GB 5749-2022Standards for drinking water quality
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Editions of GB/T 5750.6
| Edition | Title | Revision | Status |
|---|---|---|---|
| GB/T 5750.6-2023 | Standard examination methods for drinking water—Part 6: Metal and metalloid indices | current edition | Current |
| GB/T 5750.6-2006 | Standard examination methods for drinking water—Part 6: Metal and metalloid indices | previous edition | Superseded |
This page sells the current edition, GB/T 5750.6-2023. Earlier editions are listed for reference only.
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Related Standards
GB/T 5750.1-2023 — Standard examination methods for drinking water - Part 1: General principles
GB/T 5750.10-2006 — Standard examination methods for drinking Water -- Disinfection by-products parameters
GB/T 5750.10-2023 — Standard examination methods for drinking water—Part 10: Disinfection by-products indices
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