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GB/T 678-2023Chemical reagent - Ethanol (English PDF)

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Issued by

SAMR; SAC

Level / Type

National · Recommended

Issue date

August 6, 2023

Implementation date

March 1, 2024

Scope

GB/T 678-2023 (Chemical reagent - Ethanol) is available as an English-translated PDF.

GB/T 678-2023 — This document specifies the characters, technical requirements, test methods, inspection rules, packaging and marking of the chemical reagent ethanol (anhydrous ethanol). This document is applicable to the inspection of the chemical reagent ethanol (anhydrous ethanol). NOTE. the rational formula of the chemical reagent ethanol (anhydrous ethanol) is CH3CH2OH, the relative molecular mass is 46.07 (in accordance with the 2022 international relative atomic mass), and the CAS No. is 64-17-5.

Document preview — GB/T 678-2023

National Standard of the People's Republic of China

Issued by: SAMR; SAC

Contents

  • Foreword...3
  • 1 Scope...5
  • 2 Normative References...5
  • 3 Terms and Definitions...6
  • 4 Characters...6
  • 5 Technical Requirements...6
  • 6 Test Methods...7
  • 7 Inspection Rules...13
  • 8 Packaging and Marking...13

Foreword

This document was drafted in accordance with the rules provided in GB/T 1.1-2020 Directives

for Standardization - Part 1.Rules for the Structure and Drafting of Standardizing Documents.

This document serves as a replacement of GB/T 678-2002 Chemical Reagent - Ethanol. In

comparison with GB/T 678-2002, apart from structural adjustments and editorial modifications,

the main technical changes are as follows.

---The liquid-phase chromatography purity grade, technical requirements and

determination methods are added (see Chapter 5 and Chapter 6);

---The technical requirements for ethanol are modified, and the technical requirement for

top-grade purity is adjusted from " 99.8%" to " 99.9%" (see Chapter 5; Chapter 4 of

Version 2002);

---The unit of acidity and alkalinity is adjusted from "mmol/100 g" to "mmol/g" (see

Chapter 5; Chapter 4 of Version 2002);

---The technical requirements for moisture are modified, and the technical requirement for

top-grade purity is adjusted from " 0.2%" to " 0.1%" (see Chapter 5; Chapter 4 of

Version 2002);

---The technical requirements for methanol are modified, and the technical requirement

for top-grade purity is adjusted from " 0.02%" to " 0.005%" (see Chapter 5; Chapter

4 of Version 2002);

---The technical requirements and determination methods for n-propanol are added (see

Chapter 5 and 6.11);

---The determination methods for ethanol, methanol and isopropanol are modified (see 6.2,

6.10 and 6.11; 5.1, 5.8 and 5.9 of Version 2002);

---The determination method for density using a vibrating-type liquid density meter is

added (see 6.4);

---The packaging and marking are modified (see Chapter 8; Chapter 7 of Version 2002).

This document was drafted with reference to ISO 6353-2.1983 Reagents for Chemical Analysis

- Part 2.Specifications - First Series. The degree of consistency is non-equivalent.

Please be noted that certain content of this document may involve patents. The institution

issuing this document does not undertake the responsibility of identifying these patents.

This document was proposed by China Petroleum and Chemical Industry Federation (CPCIF).

This document shall be under the jurisdiction of Chemical Reagent Subcommittee of National

Technical Committee 63 on Chemistry of Standardization Administration of China (SAC/TC

63/SC 3).

The drafting organizations of this document. Jiangsu Qiangsheng Chemical Co., Ltd.; Beijing

Chemical Reagent Research Institute Co., Ltd.; Anhui Fulltime Specialized Solvent & Reagent

Co., Ltd.; Taicang Xintai Alcohol Co., Ltd.; Changshu Binjiang Chemical Co., Ltd.; Zhejiang

Environmental Testing Technology Co., Ltd.

1 Scope

This document specifies the characters, technical requirements, test methods, inspection rules,

packaging and marking of the chemical reagent ethanol (anhydrous ethanol).

This document is applicable to the inspection of the chemical reagent ethanol (anhydrous

ethanol).

NOTE. the rational formula of the chemical reagent ethanol (anhydrous ethanol) is CH3CH2OH,

the relative molecular mass is 46.07 (in accordance with the 2022 international relative

atomic mass), and the CAS No. is 64-17-5.

2 Normative References

The contents of the following documents constitute indispensable clauses of this document

through the normative references in the text. In terms of references with a specified date, only

versions with a specified date are applicable to this document. In terms of references without a

specified date, the latest version (including all the modifications) is applicable to this document.

GB/T 601 Chemical Reagent - Preparations of Standard Volumetric Solutions

GB/T 602 Chemical Reagent - Preparations of Standard Solutions for Impurity

GB/T 603 Chemical Reagent - Preparations of Reagent Solutions for Use in Test Methods

GB/T 605 Chemical Reagent - General Method for the Measurement of Color

GB/T 606 Chemical Reagent - General Method for the Determination of Water - Karl Fischer

Method

GB/T 611-2021 Chemical Reagent - General Method for the Determination of Density

GB/T 6682 Water for Analytical Laboratory Use - Specification and Test Methods

GB/T 9721-2006 Chemical Reagent - General Rules for the Molecular Absorption

Spectrophotometry

3 Terms and Definitions

This document does not have terms and definitions that need to be defined.

4 Characters

Ethanol (anhydrous ethanol) is a colorless and transparent liquid that is easily volatile. It can

be mixed with water, chloroform and ether, etc., and can easily absorb water.

5 Technical Requirements

The chemical requirements for ethanol (anhydrous ethanol) are shown in Table 1.

6 Test Methods

6.1 General Rules

Unless it is otherwise specified in this Chapter, the standard titration solutions, standard

solutions, preparations and products used are prepared in accordance with the stipulations of

GB/T 601, GB/T 602 and GB/T 603.The water used for the tests shall comply with Grade-3

water specifications in GB/T 6682.The samples are weighed to an accuracy of 0.01 g or

measured-taken to an accuracy of 0.1 mL. All solutions expressed in percentage (%) are mass

fraction (w).

6.2 Ethanol

6.2.1 Reagents, materials and instruments

Shall comply with the stipulations of Chapter 5 and Chapter 6 in GB/T 9722-2006.

6.2.3 Quantitative method

In accordance with the stipulations of 9.2 in GB/T 9722-2006, conduct the determination.

Take the arithmetic mean of two parallel determination results as the determination result. The

absolute difference between two parallel determination results shall be not greater than 0.1%.

6.3 Chroma

In accordance with the stipulations of GB/T 605, conduct the determination.

6.4 Density

In accordance with the stipulations of 4.2 or 4.4 in GB/T 611-2021, conduct the determination.

6.8 Alkalinity

In accordance with the stipulations of 5.1 in GB/T 9736-2008, conduct the determination.

6.9 Moisture

Weigh-take 4 g (about 5 mL) of sample and use 10 mL of methanol as the solvent. In accordance

with the stipulations of GB/T 606, conduct the determination.

6.10 Methanol

6.10.1 Reagents, materials and instruments
6.10.2 Determination conditions

See 6.2.2.

6.10.3 Determination method

Take 1 L of methanol external standard solution (6.10.1.3) and 1 L of sample, and

respectively inject the sample.

6.10.4 Calculation

The mass fraction (w2) of methanol shall be calculated in accordance with Formula (2).

6.17 Absorbance

6.17.1 Reagents and instruments

The water used for the test shall comply with Grade-2 water specifications in GB/T 6682.

UV-visible spectrophotometer shall comply with the stipulations of Chapter 6 in GB/T 9721-

2006.

6.17.2 Determination conditions
6.17.3 Determination method

In accordance with the stipulations of 7.2.1 in GB/T 9721-2006, at the wavelengths specified

in 6.17.2, respectively determine the absorbance.

7 Inspection Rules

In accordance with the stipulations of HG/T 3921, conduct sampling and acceptance inspection.

8 Packaging and Marking

In accordance with the stipulations of GB 15346, conduct packaging, storage and transportation,

and make markings, including.

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This preview omits tables, figures, formulas and parts of the technical clauses. The complete document — all pages — is available in the English PDF.

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