GB/T 7991-2003Test method of viterous and porcelain enamels - Part 1: Determination of resistance to alkaline liquids (English PDF)

Foreword

This document is in accordance with the provisions of GB/T 1.1-2020 "Guidelines for Standardization Work Part 1: Structure and Drafting Rules of Standardization Documents" drafted:

This document is part 1 of GB/T 7991 "Test methods for glass-lined layers": GB/T 7991 has released the following parts:

--- Part 1: Determination of corrosion resistance to alkaline solutions;

--- Part 3: Determination of resistance to sudden changes in temperature;

--- Part 4: Determination of mechanical shock resistance;

--- Part 5: Thickness measurement by electromagnetic method;

--- Part 6: High voltage test;

--- Part 7: Determination of the mean coefficient of linear thermal expansion;

--- Part 9: Determination of tensile strength;

--- Part 10: Determination of lead and cadmium dissolution:

This document replaces GB/T 7988-2013 "Determination of Corrosion Resistance of Glass-Lined Glazes to Alkaline Solution", and is in conformity with GB/T 7988-2013 in addition to structural adjustments and editorial changes, the main technical changes are as follows:

a) Changed the technical requirements for test water (see 5.2, 4:2 of GB/T 7988-2013);

b) Added the technical requirement of "rubber layer thickness should not be less than 2mm" for the sample protective cover (see 6.1:4);

c) Changed the technical requirements for constant temperature water baths (see 6.2, 5:2 of GB/T 7988-2013);

d) Deleted "If there are cracks, cracked porcelain, or edge corroded specimens in the two specimens, this phenomenon should be described in the test report:

And the sample should be replaced and re-tested" (see 8.1 of GB/T 7988-2013);

e) The "Calculation formula for the daily corrosion rate of the sample" is deleted (see 8.2 of GB/T 7988-2013);

f) Added "1mol/L hot sodium hydroxide solution corrosion test" (see Chapter 11):

This document is modified to adopt ISO 28706-4:2016 "Determination of chemical resistance of enamels and enamels - Part 4: Testing with cylindrical containers Determination of Corrosion Resistance to Alkaline Liquids":

A chapter "Terms and Definitions" has been added to this document:

Compared with ISO 28706-4:2016, this document has more structural adjustments: Comparison list of structure number changes between two files See Appendix A for the table:

The technical differences between this document and ISO 28706-4:2016 and their reasons are as follows:

--- Delete the normative reference document ISO 48 (see 6.1:4);

--- Replaced ISO 3696 with the normative reference document GB/T 6682, and the degree of consistency between the two documents was modified to accommodate my country's technical conditions to improve operability (see 5.2);

--- Added normative reference document GB/T 678 (see 5.5);

--- Added normative reference document GB/T 629 (see 5.6);

--- Replaced EN10088-1 with the normative reference document GB/T 20878: There is no consistent correspondence between the two documents:

Adapt to my country's technical conditions and improve operability (see 6.1:6);

--- Replaced ISO 1042 with the normative reference document GB/T 12806, the degree of consistency between the two documents is non-equivalent, to suit the According to the technical conditions of our country, improve the operability (see 6.9);

--- Replaced ISO 28764 with the normative reference document HG/T 3105, there is no consistent correspondence between the two documents, in order to suit the According to the technical conditions of our country, improve the operability (see 7.1);

--- Increase the rejection of unqualified samples: Provisions for the removal of quality defects present on the test specimen (see 8.1, 8:2), for the purpose of Improve the accuracy of the test results, try to avoid the quality defect of the sample during the test process after being corroded by the alkali solution to the test results:

effect;

--- Added "the process of taking the sample out of the desiccator to the end of weighing the sample, the time is not more than 2min" (see 8.9), in order to avoid the weight gain of the sample by absorbing moisture in the air as much as possible, and improve the accuracy of weighing;

--- Change the heating time of the test device without the test solution in the constant temperature water bath from 10min to 15min (see 8.6), the purpose is to ensure that the temperature of the test device is consistent with the temperature of the water in the constant temperature water bath, and to improve the accuracy of the test results:

The following editorial changes have been made to this document:

--- In order to harmonize with existing standards, the name of the standard was changed to "Test Methods for Glass-Lined Layers - Part 1: Corrosion Resistance to Alkaline Solutions" Determination of ";

--- Changed the description sequence of protective sleeve, flange plate, plug, and six-wing nut in 6:1 test device;

--- Changed the subscript of the mass symbol m before and after the weighed sample in the formula:

Please note that some content of this document may be patented: The issuing agency of this document assumes no responsibility for identifying patents:

Introduction

GB/T 7991 aims to accurately measure the performance data of the glass-lined layer, and is intended to consist of 10 parts:

--- Part 1: Determination of corrosion resistance to alkaline solutions;

--- Part 2: Determination of resistance to boiling acid and its vapor corrosion properties;

--- Part 3: Determination of resistance to sudden changes in temperature;

--- Part 4: Determination of mechanical shock resistance;

--- Part 5: Thickness measurement by electromagnetic method;

--- Part 6: High voltage test;

--- Part 7: Determination of the mean coefficient of linear thermal expansion;

--- Part 8: Determination of scratch resistance;

--- Part 9: Determination of tensile strength;

--- Part 10: Determination of lead and cadmium dissolution:

These ten performance parameters are very important to glass-lined equipment, and are directly related to the quality and service life of glass-lined equipment:

This document improves the technical level of the test method and the accuracy of the test results, and can more accurately measure the alkali corrosion resistance of the glass-lined layer to optimize the formulation of glass-lined glaze, evaluate the rationality and advancement of the firing process of glass-lined equipment, and improve the quality of glass-lined equipment and service life are very important: In addition, this document is modified using ISO 28706-4:2016 "Enamel and enamel resistance to chemical corrosion" Determination of Properties Part 4: Determination of Corrosion Resistance to Alkaline Liquids by Cylindrical Containers, in line with international standards, and thus in accordance with this document when the results of the test are compared with the test results of international standards, the test results are comparable, which can better promote trade, exchanges and Technical cooperation:

Glass-lined layer test method Part 1: Determination of corrosion resistance to alkaline solutions

1 Scope

This document describes the test principle for the determination of the corrosion resistance of the glass-lined layer of the glass-lined flat plate specimen, and specifies the reagents, test Device, sample, test procedure, result calculation and test report:

This document is applicable to the determination of the corrosion resistance of glass-lined layers to alkaline solutions:

2 Normative references

The contents of the following documents constitute essential provisions of this document through normative references in the text: Among them, dated citations documents, only the version corresponding to that date applies to this document; for undated references, the latest edition (including all amendments) applies to this document:

GB/T 629 Chemical Reagent Sodium Hydroxide GB/T 678 Chemical Reagent Ethanol (Dehydrated Ethanol) GB/T 6682 Analysis Laboratory Water Specifications and Test Methods (GB/T 6682-2008, ISO 3696:1987, MOD) GB/T 12806 Laboratory glass instrument single-line volumetric flask (GB/T 12806-2011, ISO 1042:1998, NEQ) GB/T 20878 Stainless steel and heat-resistant steel grades and chemical composition Preparation of HG/T 3105 Steel Plate Glass-Lined Specimen

3 Terms and Definitions

There are no terms and definitions that need to be defined in this document:

4 Principles

After corroding the glass-lined surface with a certain concentration, a certain temperature and a certain amount of alkaline solution for a certain period of time, the mass loss of the sample was measured, and the Calculate mass loss and corrosion rate per unit area:

5 Reagents

5.1 Basic requirements Unless otherwise specified, the test process should use certified analytical reagents:

5.2 Test water

The distilled water used in the test shall be distilled water with the third-grade purity specified in GB/T 6682 or water of the same purity:

5.3 Acetic acid solution the concentration of acetic acid solution is 50mL/L, which is used to clean the test device and sample: