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GB/T 23229-2023Methods for analysis of waterborne wood preservatives (English PDF)

水载型木材防腐剂的分析方法

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Issued by

SAMR; SAC

Level / Type

National · Recommended

Issue date

November 27, 2023

Implementation date

November 27, 2023

Scope

GB/T 23229-2023 is the English-translated version of 水载型木材防腐剂的分析方法.

GB/T 23229-2023 is the Chinese national standard that collects the analytical methods for waterborne wood preservatives and for wood treated with them.

It covers the determination of copper, chromium and arsenic in CCA products, of boron in boron-containing products, of DDAC and BAC in ACQ preservatives and, by high performance liquid chromatography, in ACQ-treated wood, of quaternary ammonium salts in treated wood by two-phase titration, and of cyproconazole, tebuconazole, propiconazole, hexaconazole, triadimenol, DCOI, OIT, CMIT, MIT and IPBC.

Two further clauses measure the penetration of copper-containing preservatives such as ACQ, CuAz and CCA and of boron-containing ones, and a last clause sets the component content and treatment quality indicators.

It cites GB/T 14019, GB/T 27651-2023, GB/T 27654-2023, GB/T 40196 and SB/T 10404. It replaces GB/T 23229-2009, was issued on 27 November 2023 and has applied since 27 November 2023.

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Document preview — GB/T 23229-2023

National Standard of the People's Republic of China

ICS
79.020
Classification
B 60
Replacing
GB/T 23229-2009

Issued by: State Administration for Market Regulation; Standardization Administration of the PRC

Contents

  • Preface
  • 1 Scope
  • 2 Normative references
  • 3 Terms and Definitions
  • 4 Determination of copper, chromium and arsenic content in preservatives containing copper, chromium and arsenic and in preservative wood
  • 5 Determination of boron content in boron-containing preservatives and preservative wood
  • 6 Determination method of DDAC and BAC in ACQ preservative
  • 7 Determination of DDAC or BAC in ACQ preservative wood---High performance liquid chromatography
  • 8 Analysis method of quaternary ammonium salts in anticorrosive wood---Two-phase titration method
  • 9 Analysis method of cyproconazole
  • 10 Analytical methods for tebuconazole, propiconazole, hexaconazole, triazole alcohol, etc
  • 11 DCOI, OIT analysis methods
  • 12 CMIT, MIT analysis methods
  • 13 IPBC Analysis Method
  • 14 Determination of penetration of copper-containing anticorrosive wood such as ACQ, CuAz, CCA
  • 15 Determination of penetration of boron-containing anticorrosive wood
  • 16 Determination of preservative component content indicators and preservative wood treatment quality indicators

Foreword

This document complies with the provisions of GB/T 1.1-2020 "Standardization Work Guidelines Part 1: Structure and Drafting Rules of Standardization Documents" Drafting.

This document replaces GB/T 23229-2009 "Analysis Method for Waterborne Wood Preservatives". Compared with GB/T 23229-2009, in addition to structural adjustments and editorial changes, the main technical changes are as follows:

a) Atomic absorption spectrometry for the determination of chromium and arsenic content in preservatives containing chromium and arsenic and in preservative wood has been added (see 4.2);

b) Changed the analysis method for the determination of boron content in boron-containing preservatives and preservative wood (see 5.2, 2009 version of 5.2);

c) Added the analysis method of quaternary ammonium salts in preservative wood---two-phase titration method (see Chapter 8);

d) Added analytical methods for cyproconazole, hexaconazole, triazole, prothioconazole, difenoconazole, tetrafluroconazole, etc. (see Chapter 9, Chapter 10);

e) The analytical methods of tebuconazole and propiconazole have been changed (see Chapter 10, Chapter 8 and 9 of the 2009 edition);

f) Added 4,5-dichloro-N-n-octyl-4-isothiazolin-3-one (DCOI), N-octyl-4-isothiazolin-3-one (OIT), 5- Chloro-2-methyl Analysis methods for methyl 4-isothiazolin-3-one (CMIT), 2-methyl 4-isothiazolin-3-one (MIT), etc. (see Chapter 11 and Chapter 12);

g) Added the analytical method for iodopropynylbutylcarbamate (IPBC) (see Chapter 13).

1 Scope

This document describes the waterborne preservatives copper chromium arsenic (CCA), copper quaternary ammonium (ACQ), copper azole (CuAz), triazole, iodopropynylbutylammonium Copper, chromium, arsenic and didecyldimethylammonium chloride are the active ingredients in preservative wood (IPBC), isothiazolinone, boride and antiseptic wood. (DDAC), dodecylbenzyldimethylammonium chloride (BAC), cyproconazole, tebuconazole, propiconazole, hexaconazole, triazole, prothioconazole, benzene Containing etherfenoconazole, tetrafluroconazole, bis-(N-cyclohexyl)diazene dioxide (HDO), IPBC, DCOI, OIT, CMIT, MIT and boron Quantitative measurement method and method for determining the penetration of anticorrosive wood.

This document is applicable to the determination of active ingredients in water-borne preservatives and preservative wood.

2 Normative reference documents

The contents of the following documents constitute essential provisions of this document through normative references in the text. Among them, the dated quotations For undated referenced documents, only the version corresponding to that date applies to this document; for undated referenced documents, the latest version (including all amendments) applies to this document.

GB/T 14019 Wood anticorrosion terminology

GB/T 27651-2023 Classification and requirements for the use of anticorrosive wood

GB/T 27654-2023 Wood preservatives

GB/T 40196 Method for determination of CCA and ACQ in preservative wood and wood preservatives using X-ray fluorescence spectrometer

SB/T 10404 Determination of main components of water-borne preservatives and flame retardants

3 Terms and definitions

The terms and definitions defined in GB/T 14019 apply to this document.

4 Determination of copper, chromium and arsenic content in preservatives containing copper, chromium and arsenic and in preservative wood

4.1 Determination of copper content in copper-containing preservatives and preservative wood by atomic absorption spectrometry

4.1.1 Instruments

4.1.1.1 Atomic absorption spectrometer.

4.1.1.2 Analytical balance (accuracy 0.1mg).

4.1.1.3 Electric drill or plant tissue grinder.

4.1.1.4 250mL Erlenmeyer flask.

4.1.1.5 200mL and 500mL volumetric flasks.

4.1.2 Reagents

4.1.2.1 98% concentrated sulfuric acid, analytical grade.

4.1.2.2 30% hydrogen peroxide, analytical grade.

......
This preview omits tables, figures, formulas and parts of the technical clauses. The complete document — 15 pages — is available in the English PDF.

Referenced standards

Similar standards

Editions of GB/T 23229

EditionTitleRevisionStatus
GB/T 23229-2023Methods for analysis of waterborne wood preservativescurrent editionCurrent
GB/T 23229-2009Methods for analysis of waterborne wood preservativesprevious editionSuperseded

This page sells the current edition, GB/T 23229-2023. Earlier editions are listed for reference only.

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