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GB 14544-2025Safety technical specification for production of vinyl chloride by acetylene (English PDF)

乙炔法生产氯乙烯安全技术规范

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Issued by

SAMR; SAC

Level / Type

National · Mandatory

Issue date

October 5, 2025

Implementation date

September 1, 2026

Scope

GB 14544-2025 is the English-translated version of 乙炔法生产氯乙烯安全技术规范.

GB 14544 governs the acetylene route to vinyl chloride monomer, the process on which much of China's PVC industry runs and which handles three severe hazards at once: acetylene, which detonates without oxygen; hydrogen chloride; and vinyl chloride itself, a flammable gas and a known carcinogen. The standard sets the basic requirements for the plant, the safety requirements for production and for storage, and the emergency response provisions. The 2025 edition replaces GB 14544-2008 and takes account of the shift away from the mercuric chloride catalyst. Issued on 5 October 2025, in force since 1 September 2026. This page is published from the official record of the standard held by the Chinese standards administration: the identification, the dates, the classification and the edition it replaces are taken from there. The clause text, the tables and the numeric limits are not reproduced on this page - they are in the document itself, which is delivered in full in English translation.

Document preview — GB 14544-2025

National Standard of the People's Republic of China

ICS
13.300
Classification
A 65
Replacing
GB 14544-2008

Issued by: State Administration for Market Regulation; Standardization Administration of the PRC

Contents

  • 1.Scope1
  • 2 Normative References1
  • 3.Terms and Definitions1
  • 4.Basic Requirements1
  • 4.1 Basic Safety Management1
  • 4.2 Site Selection and Layout2
  • 4.3 Buildings and Structures2
  • 4.4 Piping and Equipment3
  • 4.5 Electrical Instruments3
  • 4.6 Intelligent Management3
  • 4.7 Verification Method4
  • 5.1 Mixed Dehydration4
  • 5.2 Synthesis of Vinyl Chloride4
  • 5.3 Vinyl chloride purification4
  • 5.4 Compression and distillation of vinyl chloride5
  • 5.5 Vinyl chloride gas holders and acetylene gas holders5
  • 5.6 Reactor polymerization of vinyl chloride6
  • 5.7 Verification Methods6

Foreword

This document complies with the provisions of GB/T 1.1-2020 "Standardization Work Guidelines Part

1.Structure and Drafting Rules of Standardization Documents". Drafting. This document replaces GB 14544-2008 "Safety Technical Regulations for Vinyl Chloride Production via the Calcium Carbide Acetylene Process". Compared with GB 14544-2008, except for... Aside from structural adjustments and editorial changes, the main technical changes are as follows:

a) The scope of application has been changed (see Chapter 1, Chapter 1 of the.2008 edition);

b) The terms "hot work" and "cooker cleaning" have been removed (see

3.2 in the.2008 edition);

c) Changes were made to the basic security management (see 4.1, 4.7.1, 5.6, and Chapter 9 of the.2008 edition);

d) The site selection and layout requirements have been changed (see 4.2,

4.1.1 of the.2008 version);

e) The requirements for buildings and structures have been changed (see 4.3,

5.1.2 of the.2008 edition);

f) The requirements for piping and equipment have been changed (see 4.4, 4.6, 5.4.5, 6.3.2, and

7.2.1.5 in the.2008 edition);

g) Requirements for electrical instrumentation have been added (see 4.5);

h) The requirements for intelligent management have been added (see 4.6);

1 Scope

GB 14544 governs the acetylene route to vinyl chloride monomer, the process on which much of China's PVC industry runs and which handles three severe hazards at once: acetylene, which detonates without oxygen; hydrogen chloride; and vinyl chloride itself, a flammable gas and a known carcinogen. The standard sets the basic requirements for the plant, the safety requirements for production and for storage, and the emergency response provisions. The 2025 edition replaces GB 14544-2008 and takes account of the shift away from the mercuric chloride catalyst. Issued on 5 October 2025, in force since 1 September 2026. This page is published from the official record of the standard held by the Chinese standards administration: the identification, the dates, the classification and the edition it replaces are taken from there. The clause text, the tables and the numeric limits are not reproduced on this page - they are in the document itself, which is delivered in full in English translation.

This document specifies the basic requirements for enterprises producing vinyl chloride using the acetylene process, as well as the requirements for production safety, storage safety, and emergency response. It also describes... The corresponding verification methods. This document applies to the production, storage, and emergency response of vinyl chloride production enterprises using the acetylene process.

2 Normative references

The contents of the following documents, through normative references within the text, constitute essential provisions of this document. Dated citations are not included. For references to documents, only the version corresponding to that date applies to this document; for undated references, the latest version (including all amendments) applies. This document.

GB/T 567.2 Rupture disc safety devices - Part

3 Terms and Definitions

This document does not contain any terms or definitions that need to be defined.

4.1 Basic Safety Management

4.1.1 In locations where flammable and explosive media such as vinyl chloride, acetylene, and hydrogen are present, explosion-proof tools should be used, and shoes with spikes or those prone to generating static electricity should not be worn.

......
This preview omits tables, figures, formulas and parts of the technical clauses. The complete document — 10 pages — is available in the English PDF.

Referenced standards

Editions of GB 14544

EditionTitleRevisionStatus
GB 14544-2025Safety technical specification for production of vinyl chloride by acetylenecurrent editionCurrent
GB 14544-2008Safety technical specification for production of vinyl chloride by acetyleneprevious editionSuperseded

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