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GB/T 36700.8-2018Chemicals—Guidance on hazard classification to the aquatic environment—Part 8:Guidance on transformation/dissolution of metals and metal compounds in aqueous media (English PDF)

化学品 水生环境危害分类指导 第8部分:金属和金属化合物在水介质中的转化/溶解指导

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Issued by

SAMR; SAC

Level / Type

National · Recommended

Issue date

September 17, 2018

Implementation date

January 1, 2019

Scope

GB/T 36700.8-2018 is the English-translated version of 化学品 水生环境危害分类指导 第8部分:金属和金属化合物在水介质中的转化/溶解指导.

GB/T 36700.8-2018 is Part 8 of the Chinese national guidance on classifying chemicals for hazards to the aquatic environment. It explains how to run transformation/dissolution tests that measure how fast and how far metals and sparingly soluble metal compounds release metal ions into standard aqueous media.

It covers the principle, test substance information, equipment and reagents, test preparation and conditions, procedures, treatment of results and the test report.

A screening test uses a single load of 100 mg/L for 24 h, while the full test uses loads of 1, 10 and 100 mg/L over 7 days and 1 mg/L over 28 days. The results are compared with toxicity data for classification under GB/T 36700.7, and organometallic compounds are excluded. It was issued on 17 September 2018 and has applied since 1 January 2019.

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Document preview — GB/T 36700.8-2018

National Standard of the People's Republic of China

ICS
13.300
Classification
A 80

Issued by: State Administration for Market Regulation; Standardization Administration of the PRC

Contents

  • Foreword
  • Introduction
  • 1 Scope
  • 2 Normative references
  • 3 Principle

Foreword

GB/T 36700 "Chemical Aquatic Environmental Hazard Classification Guidance" is divided into the following eight parts.

--- Part 1. Introduction;

--- Part 2. Unified classification method;

---Part 3. Aquatic toxicity;

--- Part 4. Degradation;

--- Part 5. Bioconcentration;

--- Part 6. Quantitative structure activity relationship (QSAR);

--- Part 7. Classification of metals and metal compounds;

--- Part 8. Guidance for the conversion/dissolution of metals and metal compounds in aqueous media.

This part is the eighth part of GB/T 36700.

This part is drafted in accordance with the rules given in GB/T 1.1-2009.

Introduction

This part of GB/T 36700 provides guidance on how to perform conversion/dissolution tests, which are intended for standard laboratory conditions.

Determination of the rate at which metals and sparingly soluble metal compounds form ions and metal solubles in aqueous media that represent the natural environmental conditions of nature degree. The results of the assay can be used to assess acute and chronic aquatic toxicity. Compare metal ions produced by conversion or dissolution in a standard aqueous medium Degree, as well as standard ecotoxicity data (acute and chronic toxicity values) obtained from metal salt solutions, for metals and sparingly soluble metal compounds Classification of acute and chronic aquatic toxicity. For the method of using the obtained results to classify aquatic environmental hazards, see GB/T 36700.7.

1 Scope

This part of GB/T 36700 specifies the basic principle for determining the conversion/dissolution test method for metals and metal compounds in aqueous media.

Test substance information, equipment and reagents, test preparation, test conditions, test procedures, and treatment and test reports of test results.

This section applies to the guidance for the classification of chemical aquatic environmental hazards involving the conversion/dissolution of metals and metal compounds in aqueous media. This section does not apply to organometallic compounds.

2 Normative references

The following documents are indispensable for the application of this document. For dated references, only dated versions apply to this document. For undated references, the latest edition (including all amendments) applies to this document.

GB/T 16125 Large cockroach acute toxicity test method

ASTME 729-96 Standard Guide for Very Toxic Toxicity Tests on Fish, Large Invertebrates, and Amphibians (Standard Guideforconductingacutetoxicitytestsontestmaterialswithfishes,macroinvertebrates,andam- Phiibians)

3 Principle

3.1 Overview

Stir a different amount of the test substance in a pH buffer and sample and analyze at a specified time interval to determine the metal in the solution Ion concentration. There are two types of tests, screening tests and complete tests. Screening tests are performed at a single concentration and are Compounds that are difficult to distinguish between their ecotoxic potential and dissolved state due to decomposition or rapid conversion are screened out. complete The purpose of the test is to determine the level of dissolution or conversion of the metal and metal compound in a different aqueous solution after a certain period of time.

3.2 Screening test

For sparingly soluble metal compounds, determine the maximum solubility of the metal by determining the solubility limit, or according to the conversion/dissolution screening test. set. A slightly soluble metal compound having the smallest typical particle size was commercially available and added to water at a single test load of 100 mg/L. After 24h Stirring was continued to determine the concentration of metal ions.

3.3 Complete test

3.3.1 Add bulk and/or powder test substances to water at three different test loads of 1mg/L, 10mg/L and 100mg/L, The short-term conversion/dissolution test endpoint was determined by measuring the metal ion concentration after the 7-day conversion/dissolution test; by measuring 1 mg/L single The metal ion concentration after the 28-day conversion/dissolution test of the test load determines the end point of the long-term conversion/dissolution test. If dissolved metal is expected The substance will not be released in a large amount, and the test load can be selected only for 100 mg/L. Test using a stirring method that does not cause particulate matter to wear.

3.3.2 pH has a significant effect on conversion/dissolution, so both screening and complete tests should be performed at maximum metal ion concentration.

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This preview omits tables, figures, formulas and parts of the technical clauses. The complete document — 15 pages — is available in the English PDF.

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