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GB/T 25963-2022Determination of aromatic hydrocarbon types in middle distillates containing fatty acid methyl esters - High performance liquid chromatography method with refractive index detection (English PDF)

含脂肪酸甲酯中间馏分芳烃含量的测定 示差折光检测器高效液相色谱法

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Issued by

SAMR; SAC

Level / Type

National · Recommended

Issue date

October 12, 2022

Implementation date

October 12, 2022

Scope

GB/T 25963-2022 is the English-translated version of 含脂肪酸甲酯中间馏分芳烃含量的测定 示差折光检测器高效液相色谱法.

GB/T 25963-2022 is the Chinese standard "Determination of aromatic hydrocarbon types in middle distillates containing fatty acid methyl esters - High performance liquid chromatography method with refractive index detection".

Its scope clause reads: This document describes a test method for the determination of aromatics content in middle distillates by high performance liquid chromatography with a refractive index detector.

This document is applicable to the determination of diesel fuel containing fatty acid methyl ester (FAME) not more than 30% by volume, fatty acid methyl ester (FAME) containing Monocyclic aromatic hydrocarbons, bicyclic aromatic hydrocarbons and tricyclic aromatic hydrocarbons in high-wax diesel oil with an integral fraction of not more than 7% and petroleum fractions with a distillation range of 150°C~400°C content.

The content of polycyclic aromatic hydrocarbons was obtained by summing the contents of bicyclic aromatic hydrocarbons and tricyclic aromatic hydrocarbons, and the total aromatic hydrocarbon content was determined by the sum of monocyclic aromatic hydrocarbons, bicyclic aromatic hydrocarbons and tricyclic aromatic hydrocarbons.

The content of cyclic aromatic hydrocarbons is obtained by summation. This document contains two steps.

Step A and Step B. Step A is suitable for determining the volume fraction of fatty acid methyl esters (FAME) not greater than The content of monocyclic aromatic hydrocarbons, bicyclic aromatic hydrocarbons and tricyclic aromatic hydrocarbons in 30% diesel oil and petroleum fractions with a distillation range of 150 °C ~ 400 °C, of which monocyclic aromatic hydrocarbons Hydrocarbon content (mass fraction) is 6%~30%, bicyclic aromatic hydrocarbon content (mass fraction) is 1%~10%, tricyclic aromatic hydrocarbon content (mass fraction) 0%~2%, polycyclic aromatic hydrocarbon content (mass fraction) 1%~12%, total aromatic hydrocarbon content (mass fraction) 7%~42%.

Step B is suitable It is used to determine the content of aromatics in high-wax diesel oil with a volume fraction of fatty acid methyl esters (FAME) not greater than 7%.

The total aromatics content (mass fraction) is 0.2%~2%. NOTE. Typically, aromatic hydrocarbon types are defined based on their elution properties on a particular LC column compared to model compounds.

Monocyclic aromatic hydrocarbons, bicyclic The content of aromatics and tricyclic aromatics was quantified using the working curve of the external standard. In this document, one for each of monocyclic aromatic hydrocarbons, bicyclic aromatic hydrocarbons and tricyclic aromatic hydrocarbons is used.

Aromatic compounds alone act as external standards, and these compounds may (may not be) representative of the aromatics present in the sample. Other methods for each aromatic Definition and quantification of hydrocarbon types may differ from this method.

For example, the refractive index of tetrahydronaphthalene is higher than that of o-xylene, and the refractive index of n-hexylbenzene is lower than that of o-xylene.

The differences in the contents of benzene, tetrahydronaphthalene and n-hexylbenzene in the samples may cause the quantitative results of monocyclic aromatic hydrocarbons in this method to be inconsistent with the actual situation. Its clauses include terms and definitions.

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Document preview — GB/T 25963-2022

National Standard of the People's Republic of China

ICS
75.160.20
Classification
E 31
Replacing
GB/T 25963-2010

Issued by: State Administration for Market Regulation; Standardization Administration of the PRC

Contents

  • Foreword
  • 1 Scope
  • 2 Normative references
  • 3 Terms and Definitions

1 Scope

This document describes a test method for the determination of aromatics content in middle distillates by high performance liquid chromatography with a refractive index detector.

This document is applicable to the determination of diesel fuel containing fatty acid methyl ester (FAME) not more than 30% by volume, fatty acid methyl ester (FAME) containing

Monocyclic aromatic hydrocarbons, bicyclic aromatic hydrocarbons and tricyclic aromatic hydrocarbons in high-wax diesel oil with an integral fraction of not more than 7% and petroleum fractions with a distillation range of 150°C~400°C content. The content of polycyclic aromatic hydrocarbons was obtained by summing the contents of bicyclic aromatic hydrocarbons and tricyclic aromatic hydrocarbons, and the total aromatic hydrocarbon content was determined by the sum of monocyclic aromatic hydrocarbons, bicyclic aromatic hydrocarbons and tricyclic aromatic hydrocarbons.

The content of cyclic aromatic hydrocarbons is obtained by summation.

This document contains two steps. Step A and Step B. Step A is suitable for determining the volume fraction of fatty acid methyl esters (FAME) not greater than

The content of monocyclic aromatic hydrocarbons, bicyclic aromatic hydrocarbons and tricyclic aromatic hydrocarbons in 30% diesel oil and petroleum fractions with a distillation range of 150 °C ~ 400 °C, of which monocyclic aromatic hydrocarbons

Hydrocarbon content (mass fraction) is 6%~30%, bicyclic aromatic hydrocarbon content (mass fraction) is 1%~10%, tricyclic aromatic hydrocarbon content (mass fraction)

0%~2%, polycyclic aromatic hydrocarbon content (mass fraction) 1%~12%, total aromatic hydrocarbon content (mass fraction) 7%~42%. Step B is suitable

It is used to determine the content of aromatics in high-wax diesel oil with a volume fraction of fatty acid methyl esters (FAME) not greater than 7%. The total aromatics content (mass fraction) is

0.2%~2%.

NOTE. Typically, aromatic hydrocarbon types are defined based on their elution properties on a particular LC column compared to model compounds. Monocyclic aromatic hydrocarbons, bicyclic

The content of aromatics and tricyclic aromatics was quantified using the working curve of the external standard. In this document, one for each of monocyclic aromatic hydrocarbons, bicyclic aromatic hydrocarbons and tricyclic aromatic hydrocarbons is used.

Aromatic compounds alone act as external standards, and these compounds may (may not be) representative of the aromatics present in the sample. Other methods for each aromatic

Definition and quantification of hydrocarbon types may differ from this method. For example, the refractive index of tetrahydronaphthalene is higher than that of o-xylene, and the refractive index of n-hexylbenzene is lower than that of o-xylene.

The differences in the contents of benzene, tetrahydronaphthalene and n-hexylbenzene in the samples may cause the quantitative results of monocyclic aromatic hydrocarbons in this method to be inconsistent with the actual situation.

2 Normative references

The contents of the following documents constitute essential provisions of this document through normative references in the text. Among them, dated citations documents, only the version corresponding to that date applies to this document; for undated references, the latest edition (including all amendments) applies to this document.

GB/T 4756 Petroleum liquid manual sampling method

GB/T 12806-2011 Laboratory glass instrument single-line volumetric flask

GB 25199 B5 diesel

GB/T 27867 Petroleum liquid pipeline automatic sampling method

NB/SH/T 0843 Evaluation Statistical Techniques for Analytical Testing Systems in the Petrochemical Industry

3 Terms and Definitions

The following terms and definitions apply to this document.

......
This preview omits tables, figures, formulas and parts of the technical clauses. The complete document — 15 pages — is available in the English PDF.

Referenced standards

Similar standards

Editions of GB/T 25963

EditionTitleRevisionStatus
GB/T 25963-2022Determination of aromatic hydrocarbon types in middle distillates containing fatty acid methyl esters - High performance liquid chromatography method with refractive index detectioncurrent editionCurrent
GB/T 25963-2010Determination of aromatic hydrocarbon types in middle distillates containing fatty acid methyl esters - High performance liquid chromatography method with refractive index detectionprevious editionSuperseded

This page sells the current edition, GB/T 25963-2022. Earlier editions are listed for reference only.

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