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GB/T 1033.2-2010Plastics -- Methods for determining the density of non-cellular plastics -- Part 2: Density gradient column method (English PDF)

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Issued by

General Administration of Quality Supervision, Inspection and Quarantine of PRC

Level / Type

National · Recommended

Issue date

September 26, 2010

Implementation date

August 1, 2011

Scope

GB/T 1033.2-2010 (Plastics -- Methods for determining the density of non-cellular plastics -- Part 2: Density gradient column method) is available as an English-translated PDF.

GB/T 1033.2-2010 - This part of GB/T 1033 specifies the method for determining the density of non-cellular plastics using a density gradient column. This standard applies to molded or extruded non-porous non-cellular plastic solid particles.

NOTE: Density is usually used to examine the changes in the physical structure or composition of plastic materials, and is also used to evaluate the homogeneity of samples or specimens.

The density of plastic materials is usually also closely related to the preparation method of the specimen. In this case, the detailed method of specimen preparation shall be included in the relevant specifications of the material.

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Document preview — GB/T 1033.2-2010

National Standard of the People's Republic of China

ICS
83.080.01
Classification
G 31

Issued by: General Administration of Quality Supervision, Inspection and Quarantine of PRC

Contents

  • Foreword...3
  • 1 Scope...5
  • 2 Normative references...5
  • 3 Terms and definitions...6
  • 4 Conditioning...6
  • 5 Methods...7
  • 6 Precision...10
  • 7 Test report...12
  • Appendix A (Informative) Preparation of density gradient columns...13
  • Appendix B (Informative) Liquid systems for density determination...18

Foreword

GB/T 1033 Plastics - Methods for determining the density of non-cellular plastics is

divided into the following three parts:

-- Part 1: Immersion method, liquid pyknometer method and titration method;

-- Part 2: Density gradient column method;

-- Part 3: Gas pyknometer method.

This part is Part 2 of GB/T 1033.

This part was redrafted and modified in relation to ISO 1183-2:2004 Plastics - Methods

for determining the density of non-cellular plastics - Part 2: Density gradient column

method (English version).

The technical differences between this part and ISO 1183-2:2004 and their reasons are

as follows:

-- The International Standards listed in the chapter "Normative references" are

respectively replaced by the Chinese national standards that correspond to these

documents. GB/T 6379.2-2004 Accuracy (trueness and precision) of

measurement methods and results - Part 2: Basic method for the determination

of repeatability and reproducibility of a standard measurement method (ISO

5725-2:1994, IDT) is added to the reference documents;

-- The definition of "density gradient column" is added;

-- The float size requirement in ISO 1183-2:2004 is changed from "diameter not

more than 5 mm" to "diameter not more than 8 mm";

-- The requirements for accuracy of the calculation of density are clarified;

-- The content related to precision is added;

-- "Appendix C (Informative) Differences between this part of GB/T 1033 and

Method D in GB/T 1033-1986" is added.

For ease of use, this part makes the following editorial changes to ISO 1183-2.2004.

-- The foreword of ISO 1183-2:2004 is deleted;

-- According to the writing rules of Chinese standards, the Appendix B of the

original English text is changed into Appendix A of this standard, and the

Plastics - Methods for determining the density of non-

cellular plastics - Part 2: Density gradient column method

WARNING: The application of this part may involve some dangerous materials,

operations or equipment. This part does not address all possible safety issues

related to the application. The user of this part is responsible for establishing the

safety and health terms applicable to this part and determining the use

specifications of this part before use.

1 Scope

This part of GB/T 1033 specifies the method for determining the density of non-cellular

plastics using a density gradient column.

This standard applies to molded or extruded non-porous non-cellular plastic solid

particles.

NOTE: Density is usually used to examine the changes in the physical structure or composition of plastic

materials, and is also used to evaluate the homogeneity of samples or specimens. The density of plastic

materials is usually also closely related to the preparation method of the specimen. In this case, the

detailed method of specimen preparation shall be included in the relevant specifications of the material.

2 Normative references

The clauses in the following documents become clauses of this part through reference

in this part of GB/T 1033. For all dated referenced documents, all subsequent

amendments (excluding errata) or revisions are not applicable to this part. However,

parties to agreements based on this part are encouraged to study whether the latest

versions of these documents can be used. For all undated referenced documents, the

latest versions are applicable to this part.

GB/T 1033.1-2008 Plastics - Methods for determining the density of non-cellular

plastics - Part 1: Immersion method, liquid pyknometer method and titration

method (ISO 1183-1:2004, IDT)

GB/T 2035-2008 Terms and definitions for plastics (ISO 472:1999, IDT)

GB/T 2918-1998 Plastics - Standard atmospheres for conditioning and testing (idt

ISO 291:1997)

GB/T 6379.2-2004 Accuracy (trueness and precision) of measurement methods

NOTE: The diameter of the specimen is usually less than 5 mm.

5.4 Test steps

5.4.1 Preparation and calibration of glass floats
5.4.1.1 The glass floats (5.1.3) shall be nearly spherical objects made by any convenient

method, not more than 8 mm in diameter and fully annealed.

5.4.1.2 To prepare glass floats of a certain density range, prepare a series of about 500

mL of mixed solutions prepared in different proportions from the two immersion

solutions (5.2). The density range of the mixed solutions shall cover the entire range of

density measured by the density gradient column (5.1.1). Gently place the floats in these

mixed solutions at room temperature.

Select an appropriate glass float and adjust it according to the following steps to

approximately match the density of the corresponding mixed liquid:

a) Polish the glass float on a glass plate with a dilute slurry of silicon carbide

with a particle size of less than 38 µm (400 mesh) or another suitable abrasive.

b) Etch the glass float with hydrofluoric acid.

5.4.1.3 Determine the exact density of each glass float obtained above. Gently place a

float in the mixed solution (5.2) placed in the liquid thermostatic bath (5.1.2). The

temperature of the liquid thermostatic bath (t °C±0.1 °C) is the operating temperature

of the density gradient column (23 °C or 27 °C). If the float sinks, add the heavier one

of the two liquids (conversely, if the float ascends, add the lighter liquid) and then gently

stir the mixture to make it uniform. After stirring evenly, observe whether the float is

stable and motionless in the mixed solution. If the float moves up or down, adjust the

density of the mixed solution again according to the above steps until the float can

remain stationary for at least 30 minutes.

5.4.1.4 When the float reaches equilibrium, the density of the mixed liquid is recorded

as the density of the float. The density of the mixed liquid is determined by the liquid

pycnometer method (method B) in GB/T 1033.1-2008 or other appropriate methods.

The density of each float shall be accurate to 0.0001 g/cm3. If necessary, buoyancy shall

be calibrated according to Chapter 6 of GB/T 1033.1-2008.

NOTE: Calibrated glass floats may also be available from approved suppliers.

5.4.2 Preparation of density gradient columns

This part does not describe in detail the preparation method of density gradient columns.

Appendix B provides two reference methods.

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This preview omits tables, figures, formulas and parts of the technical clauses. The complete document — 18 pages — is available in the English PDF.

Referenced standards

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