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GB/T 37602-2019Ship and offshore engineering steel for low temperature service (English PDF)

船舶及海洋工程用低温韧性钢

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Issued by

SAMR; SAC

Level / Type

National · Recommended

Issue date

June 4, 2019

Implementation date

May 1, 2020

Scope

GB/T 37602-2019 is the English-translated version of 船舶及海洋工程用低温韧性钢.

GB/T 37602-2019 is the Chinese standard "Ship and offshore engineering steel for low temperature service". Its scope clause reads: This standard specifies the designation method, order content, size, shape, weight, and technical requirements of low-temperature toughness steel for ships and marine engineering.

Requirements, test methods, inspection rules, packaging, marking and quality certificates. This standard applies to carbon-manganese low-temperature steel and nickel-based low-temperature steel for liquefied gas carriers, polar ships and low-temperature marine engineering.

Steel plate larger than 60mm, section steel with thickness or diameter not larger than 50mm (hereinafter referred to as steel).

Its clauses include grade indication method; order content; size, shape, weight; technical requirements; test method; impact test 3/batch gb/t 2975 gb/t 229; residual magnetic piece by piece/piece by piece-negotiation; inspection rules; packaging, marking and quality certificate.

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Document preview — GB/T 37602-2019

National Standard of the People's Republic of China

ICS
77.140.50
Classification
H 46

Issued by: State Administration for Market Regulation; Standardization Administration of the PRC

Contents

  • 1 Scope
  • 2 Normative references
  • 3 Grade indication method
  • 4 Order content
  • 5 Size, shape, weight
  • 6 Technical requirements
  • 7 Test method
  • 2 Tensile test 1/batch GB/T 2975 GB/T 228.1
  • 3 Impact test 3/batch GB/T 2975 GB/T 229
  • 4 Tensile test in thickness direction 3/batch GB/T 5313 GB/T 5313
  • 5 Nondestructive testing one by one-NB/T 47013.3
  • 8 Residual magnetic piece by piece/piece by piece-negotiation
  • 9 Surface quality piece by piece/piece by piece-visual inspection and measurement
  • 10 Dimensions and Shapes Sheet by Piece/Piece-Appropriate Gages for Accuracy
  • 8 Inspection rules
  • 9 Packaging, marking and quality certificate

1 Scope

This standard specifies the designation method, order content, size, shape, weight, and technical requirements of low-temperature toughness steel for ships and marine engineering.

Requirements, test methods, inspection rules, packaging, marking and quality certificates.

This standard applies to carbon-manganese low-temperature steel and nickel-based low-temperature steel for liquefied gas carriers, polar ships and low-temperature marine engineering.

Steel plate larger than 60mm, section steel with thickness or diameter not larger than 50mm (hereinafter referred to as steel).

2 Normative references

The following documents are essential for the application of this document. For dated references, only the dated version applies to this article

Pieces. For undated references, the latest version (including all amendments) applies to this document.

GB/T 222 steel product chemical composition allowable deviation

GB/T 223.5 Determination of acid-soluble silicon and total silicon content in steel. Reduced silicate molybdate spectrophotometry

GB/T 223.9 Determination of aluminum content in iron, steel and alloys Chromazurol S spectrophotometric method

GB/T 223.12 Methods for chemical analysis of iron, steel and alloys-Sodium carbonate separation-Diphenylcarbazide photometric method for the determination of chromium content

GB/T 223.14 Methods for chemical analysis of iron, steel and alloys Determination of vanadium content by tantalum reagent extraction spectrophotometry

GB/T 223.19 Methods for chemical analysis of iron, steel and alloys-New copperine-chloroform extraction photometric method for determination of copper content

GB/T 223.23 Determination of nickel content in steels and alloys Butadione oxime spectrophotometric method

GB/T 223.25 Methods for chemical analysis of iron, steel and alloys. Determination of nickel content by butanedione oxime gravimetric method

GB/T 223.26 Determination of molybdenum content in steels and alloys thiocyanate spectrophotometric method

GB/T 223.37 Methods for chemical analysis of iron, steel and alloys-Distillation separation-Indophenol blue photometric method for determination of nitrogen content

GB/T 223.40 Determination of niobium content in steels and alloys Chlorosulfenol S spectrophotometric method

GB/T 223.62 Methods for chemical analysis of iron, steel and alloys Determination of phosphorus content by butyl acetate extraction spectrophotometry

GB/T 223.63 Methods for chemical analysis of iron, steel and alloys--The sodium periodate (potassium) spectrophotometric method for the determination of manganese content

GB/T 223.67 Determination of sulfur content in iron, steel and alloys Methylene blue spectrophotometric method

GB/T 223.69 Determination of carbon content in steel and alloys. Gas volume method after combustion in a tube furnace

GB/T 228.1 Tensile test for metallic materials-Part 1. Test method at room temperature

GB/T 229 Charpy pendulum impact test method for metallic materials

GB/T 247 General requirements for packaging, marking and quality certificates of steel plates and strips

GB/T 706 hot rolled section steel

GB/T 709 size, shape, weight and tolerance of hot-rolled steel plate and steel strip

GB/T 2101 General requirements for acceptance, packaging, marking and quality certificate of section steel

GB/T 2975 Sampling location and sample preparation for mechanical properties test of steel and steel products

GB/T 4336 Determination of multi-element content in carbon steel and low-alloy steels by spark discharge atomic emission spectrometry (conventional method)

GB/T 5313 thickness direction steel plate

GB/T 6803 Non-plastic transition temperature drop weight test method for ferritic steel

GB/T 8170 Numerical rounding rules and expression and judgment of limit values

GB/T 17505 General technical conditions for steel and steel product delivery

GB/T 20066 Sampling and sample preparation methods for determination of chemical composition of steel and iron

GB/T 20123 Determination of total carbon and sulfur content in iron and steel. Infrared absorption method after combustion in high frequency induction furnace (conventional method)

GB/T 20124 Determination of nitrogen content in iron and steel. Inert gas fusion thermal conductivity method (conventional method)

GB/T 20125 Determination of multi-element content in low alloy steels by inductively coupled plasma emission spectrometry

GB/T 21143 Unified test method for quasi-static fracture toughness of metallic materials

NB/T 47013.3 Non-destructive testing of pressure equipment. Part 3. Ultrasonic testing

3 Grade indication method

3.1

The steel grade, thickness direction (Z direction) performance level and classification shall meet the requirements of Table 1.

Table 1 Steel grades, thickness direction (Z direction) performance levels and classification

Grade thickness direction (Z direction) grade classification

LT32-1, LT32-2, LT32-3

LT36-1, LT36-2, LT36-3

LT40-1, LT40-2, LT40-3

Z25, Z35 carbon-manganese low temperature steel

0.5NiA, 0.5NiB, 1.5Ni, 2.25Ni

3.5Ni, 5Ni, 9Ni

Z25, Z35 nickel series low temperature steel 3.2 The grade of carbon-manganese low-temperature steel consists of the first letter LT representing the English lowtemperature of low temperature, the specified yield strength level, and the low-temperature toughness.

Sex level (1, 2 and 3) consists of 3 parts. The grade of nickel-based low temperature steel consists of the average content of nickel and the symbol of chemical element (Ni).

composition.

Example 1. LT32-2.

LT --- represents the first letter LT of English Lowtemperature;

32 --- represents the specified yield strength level;

2 --- represents low temperature toughness level.

Example 2. 3.5Ni.

Ni --- a chemical element symbol representing nickel.

3.3

When the purchaser requires the steel plate to have the thickness direction performance, add the representative thickness direction (Z direction) performance level after the grade specified in Table 1.

Symbol, for example. LT32-2-Z35.

4 Order content

A contract or order placed under this standard shall include the following.

a) the number of this standard;

b) grades;

c) specifications;

d) weight (quantity);

e) dimensional and unevenness accuracy;

f) delivery status;

g) Special requirements.

5 Size, shape, weight

5.1

The size, shape, weight and allowable deviation of the steel plate shall meet the requirements of GB/T 709.The deviation under the thickness of the steel plate is limited to -0.3mm, and

Should ensure that the average thickness of the steel plate is not less than the nominal thickness.

5.2

The size, shape, weight and allowable deviation of section steel shall meet the requirements of GB/T 706.

5.3

The density of 9Ni steel shall be implemented as 7.89g/cm3, and the density of other steel grades shall be implemented as 7.85g/cm3.

6 Technical requirements

6.1 Grade and chemical composition

6.1.1

The grade and chemical composition (smelting analysis) of the steel shall meet the requirements in Table 2.

Table 2 Steel grades and chemical composition (smelting analysis)

Grade

Chemical composition a, b, c (mass fraction) /%

C Mn Si PS Ni other elements

LT32-1

LT32-2

LT36-1

LT36-2

LT40-1

LT40-2

<=0.18

LT32-3

LT36-3

LT40-3

<=0.16

0.70 ~ 1.60 0.10 ~ 0.50 <=0.025 <=0.025 <=0.80

Cu<=0.35

Cr<=0.25

Mo<=0.08

Nb<=0.05

V<=0.10

Als >= 0.015

N<=0.015

0.5NiA <=0.14 0.70 ~ 1.50 0.10 ~ 0.50 <=0.025 <=0.010 0.15 ~ 0.80

0.5NiB <=0.16 0.85 ~ 1.70 0.10 ~ 0.50 <=0.025 <=0.010 0.15 ~ 0.85

1.5Ni <=0.14 0.30 ~ 1.50 0.10 ~ 0.35 <=0.025 <=0.020 1.30 ~ 1.70

2.25Ni <=0.13 0.30 ~ 1.50 0.10 ~ 0.35 <=0.025 <=0.020 2.00 ~ 2.50

3.5Ni <=0.12 0.30 ~ 0.80 0.10 ~ 0.35 <=0.025 <=0.020 3.20 ~ 3.80

5Ni <=0.12 0.30 ~ 0.90 0.10 ~ 0.35 <=0.025 <=0.020 4.70 ~ 5.30

9Ni <=0.10 0.30 ~ 0.90 0.10 ~ 0.35 <=0.025 <=0.020 8.50 ~ 10.0

Cu<=0.35

Cr<=0.25

Mo<=0.08

Als >= 0.015

N<=0.012 a For 0.5NiA and 0.5NiB, Cr Mo Cu<=0.50%; for 1.5Ni ~ 9Ni, Cr Mo Cu<=0.60%.

b For 0.5NiA and 0.5NiB with a thickness of not less than 40mm, the lower limit of the Ni content is 0.30%.

c The content of acid-soluble aluminum (Als) can be replaced by the total aluminum (Alt) content. At this time, Alt should not be less than 0.020%.

6.1.2

According to the requirements of the acquirer, each grade can provide the smelting analysis carbon equivalent (Ceq), the value of which is to be determined by both parties. Carbon Equivalent (Ceq)

Equation (1) calculates.

Ceq = C Mn/6 (Cr Mo V)/5 (Ni Cu)/15 (1) 6.1.3 When the purchaser requires to guarantee the thickness direction performance of the steel sheet, the S content shall meet the requirements of GB/T 5313.

6.1.4

The allowable deviation of the chemical composition of the finished steel shall meet the requirements of GB/T 222.

6.2 Smelting method

Steel is smelted by converter or electric furnace and should be refined outside the furnace. All steels should be killed steel with aluminum deoxidation.

6.3 Delivery status

The delivery status of the steel shall meet the requirements in Table 3.

Table 3 Delivery status

Classification grade delivery status

Carbon-manganese low temperature steel

LT32-1, LT32-2, LT32-3

LT36-1, LT36-2, LT36-3

LT40-1, LT40-2, LT40-3

Controlled rolling, thermo mechanical rolling (TMCP), normalizing or quenching and tempering

Nickel low temperature steel

0.5NiA, 0.5NiB, 1.5Ni, 2.25Ni, 3.5Ni Thermomechanical rolling (TMCP), normalizing, normalizing or tempering

5Ni normalized, normalized or tempered

9Ni twice normalized or tempered

6.4 Mechanical properties

6.4.1

The mechanical properties of steel shall meet the requirements in Table 4.

Table 4 Mechanical properties

Grade

Stretching test

Upper yield strength

ReH/MPa not less than tensile strength

Rm/MPa

Elongation after breaking

A /% not less than

Charpy (V-notch) impact testa

Material thickness t/mm

Test temperature

T/°C

Impact absorption energy KV2/J

Portrait Landscape not less than

Minimum design

Temperature/°C

LT32-1 315 440 ~ 570 22

<=25 -20

> 25 ~ 30 -25

> 30 ~ 35 -30

> 35 ~ 40 -35

> 40 ~ 60 -40

41 27 -15

LT32-2 315 440 ~ 570 22

<=25 -40

> 25 ~ 30 -45

> 30 ~ 35 -50

> 35 ~ 40 -55

> 40 ~ 60 -60

41 27 -35

LT32-3 315 440 ~ 570 22

<=25 -60

> 25 ~ 30 -65

> 30 ~ 35 -70

> 35 ~ 40 -75

> 40 ~ 60 -80

41 27 -55

Table 4 (continued)

Grade

Stretching test

Upper yield strength

ReH/MPa not less than tensile strength

Rm/MPa

Elongation after breaking

A /% not less than

Charpy (V-notch) impact testa

Material thickness t/mm

Test temperature

T/°C

Impact absorption energy KV2/J

Portrait Landscape not less than

Minimum design

Temperature/°C

LT36-1 355 490 ~ 630 21

<=25 -20

> 25 ~ 30 -25

> 30 ~ 35 -30

> 35 ~ 40 -35

> 40 ~ 60 -40

41 27 -15

LT36-2 355 490 ~ 630 21

<=25 -40

> 25 ~ 30 -45

> 30 ~ 35 -50

> 35 ~ 40 -55

> 40 ~ 60 -60

41 27 -35

LT36-3 355 490 ~ 630 21

<=25 -60

> 25 ~ 30 -65

> 30 ~ 35 -70

> 35 ~ 40 -75

> 40 ~ 60 -80

41 27 -55

LT40-1 390 510 ~ 660 20

<=25 -20

> 25 ~ 30 -25

> 30 ~ 35 -30

> 35 ~ 40 -35

> 40 ~ 60 -40

41 27 -15

LT40-2 390 510 ~ 660 20

<=25 -40

> 25 ~ 30 -45

> 30 ~ 35 -50

> 35 ~ 40 -55

> 40 ~ 60 -60

41 27 -35

LT40-3 390 510 ~ 660 20

<=25 -60

> 25 ~ 30 -65

> 30 ~ 35 -70

> 35 ~ 40 -75

> 40 ~ 60 -80

41 27 -55

Table 4 (continued)

Grade

Stretching test

Upper yield strength

ReH/MPa not less than tensile strength

Rm/MPa

Elongation after breaking

A /% not less than

Charpy (V-notch) impact testa

Material thickness t/mm

Test temperature

T/°C

Impact absorption energy KV2/J

Portrait Landscape not less than

Minimum design

Temperature/°C

0.5NiA 285 420 ~ 530 24

<=25 -60

> 25 ~ 30 -65

> 30 ~ 35 -70

> 35 ~ 40 -75

> 40 ~ 60 -80

41 27 -55

0.5NiB 355 490 ~ 610 22

<=25 -60

> 25 ~ 30 -65

> 30 ~ 35 -70

> 35 ~ 40 -75

> 40 ~ 60 -80

41 27 -55

1.5Ni 275 470 ~ 640 22

<=25 -65

> 25 ~ 30 -70

> 30 ~ 35 -75

> 35 ~ 40 -80

> 40 ~ 60 -85

41 27 -60

2.25Ni 305 500 ~ 660 22

<=25 -70

> 25 ~ 30 -75

> 30 ~ 35 -80

> 35 ~ 40 -85

> 40 ~ 60 -90

41 27 -65

3.5Ni 345 440 ~ 690 21

<=25 -95

> 25 ~ 30 -100

> 30 ~ 35 -105

> 35 ~ 40 -110

> 40 ~ 60 -115

41 27 -90

5Ni 390 520 ~ 710 21

<=25 -110

> 25 ~ 30 -115

> 30 ~ 35 -120

> 35 ~ 40 -125

> 40 ~ 60 -130

41 27 -105

9Ni 490 640 ~ 830 19 <=60 -196 41 27 -165 a The horizontal value of shock absorption energy is applicable to steel plates, and the vertical value is applicable to profile steels.

6.4.2

Charpy (V-notch) shock absorption energy is calculated based on the arithmetic mean of 3 samples

The specified value in Table 4 is low, but it should not be lower than 70% of the specified value.

6.4.3

Thickness (Z-direction) performance The reduction in thickness in the thickness direction shall meet the requirements of GB/T 5313.

6.5 Surface quality

6.5.1

There should be no cracks, bubbles, scars, folds or pressing on the steel surface which are harmful to use. Steel should not be visual

Visible layers.

6.5.2

The surface of the steel is allowed to have a thin layer of iron oxide scale, rust that does not hinder the inspection of the surface defects, and the inferiority caused by the iron oxide scale falling off.

Significant surface roughness, indentation and other local defects, but its depth should not be greater than half of the thickness tolerance, and the minimum allowable steel should be guaranteed thickness.

6.5.3

When there are harmful defects on the steel surface, cleaning is allowed. The cleaning place should be smooth without edges and corners, and the minimum allowable thickness of the steel should be guaranteed.

6.5.4

The steel shall not be repaired.

6.6 Nondestructive testing

6.6.1

Thickness (Z direction) performance steel plates shall be subjected to ultrasonic testing one by one.The testing method shall be in accordance with NB/T 47013.3.

The supply and demand sides negotiate and determine. After the supply and demand parties negotiate and indicate in the contract, other testing methods and qualification levels can be determined.

6.6.2

According to the requirements of the purchaser, non-destructive testing of other steels can also be carried out after consultation between the supply and demand parties.

6.7 Special requirements

According to the requirements of the purchaser, the drop hammer test, the crack tip opening displacement (CTOD) test, and the residual magnetism test can be performed after consultation between the supply and demand sides.

7 Test method

7.1 Chemical composition

The chemical composition analysis of steel is usually carried out according to GB/T 4336, GB/T 20123, GB/T 20124 or other general methods.

Press GB/T 223.5, GB/T 223.9, GB/T 223.12, GB/T 223.14, GB/T 223.19, GB/T 223.23, GB/T 223.25,

GB/T 223.26, GB/T 223.37, GB/T 223.40, GB/T 223.62, GB/T 223.63, GB/T 223.67, GB/T 223.69 or

GB/T 20125.

7.2 Other inspection items

The test method for each batch of steel inspection items shall meet the requirements of Table 5.

Table 5 Inspection items, sampling quantity, sampling method and test method

Sampling method Sampling method Test method

1 chemical composition 1 per furnace GB/T 20066 see 7.1

2 Tensile test 1/batch GB/T 2975 GB/T 228.1

3 Impact test 3/batch GB/T 2975 GB/T 229

4 Tensile test in thickness direction 3/batch GB/T 5313 GB/T 5313

5 Nondestructive testing one by one-NB/T 47013.3

6 drop weight test 2/furnace quarter width, sampling on the thickest steel plate GB/T 6803

Table 5 (continued)

Sampling method Sampling method Test method

Crack tip opening displacement (CTOD)

3/quarter width of furnace, sampling on the thickest steel plate GB/T 21143

8 Residual magnetic piece by piece/piece by piece-negotiation

9 Surface quality piece by piece/piece by piece-visual inspection and measurement

10 Dimensions and Shapes Sheet by Piece/Piece-Appropriate Gages for Accuracy

7.3 Small size specimen impact test

The impact test specimens of steel plates shall be transverse specimens, and the impact test specimens of profile steels shall be longitudinal specimens. For steel plates with a thickness of less than 12mm,

Charpy (V-notch) impact test is performed with a small-sized sample.When the thickness of the steel plate is> 8mm ~ < 12mm, the sample size is 7.5mm ×

When the thickness is 10mm × 55mm and the steel plate thickness is 6mm ~ 8mm, the sample size is 5mm × 10mm × 55mm. Less than 6mm

The steel plate may not be subjected to an impact test. The conversion relationship between the impact absorption energy of the small sample and the standard sample is shown in Table 6.

Table 6 Conversion relationship between impact absorption energy of small-size samples and standard samples

Conversion factor of width of small sample/mm and impact absorption energy of standard sample

5 2/3

7.4 Dimension inspection

7.4.1

The size and shape of the steel shall be checked with suitable measuring tools.

7.4.2

The average thickness of the steel plate is measured as follows.

a) The average thickness of the steel plate can be measured by automatic or manual methods;

b) Measurement position of the side of the steel plate. When using the automatic method to measure, the distance from the side to the side is not less than 10mm and not more than 300mm.

Measurement within the area; when measuring by manual method, measure within a range of not less than 10mm and not more than 100mm from the side;

c) Refer to Figure 1 for the schematic diagram of the average thickness measurement of the steel plate. As shown in Figure 1, select at least two lines for measurement, and select at least three for each line.

Measurement points (when there are more than 3 measurement points, the measurement points of each line should be consistent), and the average thickness of the steel plate is calculated according to the average value.

Figure 1 Schematic diagram of average thickness measurement of steel plates

8 Inspection rules

8.1

Inspection and acceptance of steel shall be carried out by the supplier's quality supervision and inspection department.

8.2

Steel plates shall be accepted in batches. Each batch of steel plates shall consist of steel plates of the same grade, same furnace number, same thickness, and the same rolling or heat treatment system.

Among them, steel sheets delivered in thermomechanical rolling (TMCP) and controlled rolling conditions should be sampled one by one, normalizing, normalizing and tempering, twice normalizing and tempering,

Quenching and tempering should be sampled by heat treatment.

8.3

Section steels shall be batches with the same furnace number, same specifications, the same rolling method and the same heat treatment system (maximum weight of each batch is 10t).

8.4

The batch of steel plates with performance requirements in the thickness direction shall meet the requirements of GB/T 5313.

8.5

The sampling quantity and sampling method of each batch of steel shall meet the requirements in Table 5.

8.6

The re-inspection and determination rules for the mechanical properties of steel plates shall meet the requirements of GB/T 17505.

8.7

The re-inspection and determination rules for the mechanical properties of section steel shall meet the requirements of GB/T 2101.

8.8

The re-inspection and judgment rules of the Z-direction steel thickness direction shall comply with the requirements of GB/T 5313.

8.9

The test results of mechanical properties and chemical composition are compared by the rounded value comparison method. The rounded rules shall meet the requirements of GB/T 8170.

9 Packaging, marking and quality certificate

The packaging, marking and quality certificate of steel shall meet the requirements of GB/T 247 and GB/T 2101.

......
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