GB/T 33320-2016Adhesives in food packaging materials and containers (English PDF)
食品包装材料和容器用胶粘剂
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Issued by
SAMR; SAC
Level / Type
National · Recommended
Issue date
December 13, 2016
Implementation date
July 1, 2017
Scope
GB/T 33320-2016 is the English-translated version of 食品包装材料和容器用胶粘剂.
GB/T 33320-2016 is the Chinese standard "Adhesives in Food Packaging Materials and Containers". Its scope clause reads: This Standard specifies the terms and definitions, classification, specifications, test methods, inspection rules, and marking, packaging, transportation and storage.
This Standard applies to the production, management and testing of adhesives in food packaging materials and containers. Its clauses include application scope; terms and definitions; classification of adhesives; requirements; general test conditions; test methods; inspection rules; marking, packaging, transportation and storage.
It was issued by the General Administration of Quality Supervision, Inspection and Quarantine on DECEMBER 23, 2016 and took effect on JULY 1, 2017.
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Document preview — GB/T 33320-2016
National Standard of the People's Republic of China
- ICS
- 83.180
- Classification
- G 39
Issued by: State Administration for Market Regulation; Standardization Administration of the PRC
Contents
- Foreword3
- 1 Application Scope4
- 2 Normative References4
- 3 Terms and Definitions5
- 4 Classification of Adhesives5
- 5 Requirements6
- 6 General Test Conditions7
- 7 Test Methods7
- 8 Inspection Rules12
- 9 Marking, Packaging, Transportation and Storage13
- Bibliography15
Foreword
This Standard was drafted in accordance with the rules given in GB/T 1.1-2009.
1 Application Scope
This Standard specifies the terms and definitions, classification, specifications, test methods, inspection rules, and marking, packaging, transportation and storage.
This Standard applies to the production, management and testing of adhesives in food packaging materials and containers.
2 Normative References
The following referenced documents are indispensable for the application of this document. For dated references, only the edition dated applies to this document. For undated references, the latest edition of the referenced documents (including all amendments) applies to this Standard.
GB/T 1633, Plastics - Thermoplastic Materials - Determination of Vicat Softening Temperature (VST)
GB/T 2791, Adhesives - T Peel Strength Test Method for a Flexible-to-flexible Test Sample Assembly
GB/T 2793, Test Method for Nonvolatile Content of Adhesives
GB/T 2794, Determination for Viscosity of Adhesives - Single Cylinder Rotational Viscometer Method
GB/T 2943, Terms of Adhesive
GB/T 3682, Determination of the Melt Mass-Flow Rate (MFR) and the Melt Volume- Flow Rate (MVR) of Thermoplastics
GB/T 8170, Rules of Rounding off for Numerical Values and Expression and Judgement of Limiting Values
GB 9685, Hygienic Standards for Uses of Additives in Food Containers and Packaging Materials
GB/T 14518, Determination of the pH of Adhesives
GB/T 15332, Determination of the Softening Point of Hot-melt Adhesives - Ball and Ring Method
GB/T 20740, Adhesive - Sampling
GB/T 30778, Polyvinyl Acetate-acrylate Emulsion Adhesive for the Laminating of Paper/polymer Films at Room Temperature
HG/T 3075, The Specification for Package, Mark, Transportation and Storage of Adhesive Products
HG/T 3660, Testing Methods for Melt Viscosity of Hot-melt Adhesives
HG/T 4362, Water-based Laminating Adhesive Used in Paper with Polymer Films by Heating Process
JJF 1070, Rules of Metrological Testing for Net Quantity of Products in Prepackages with Fixed Content
3 Terms and Definitions
For the purposes of this document, the following terms and definitions and those defined in GB/T 2943 apply.
3.1 Heat sealing
The technique through which food packaging materials or containers are sealed under heating conditions to achieve certain functions.
3.2 Cold sealing
The technique through which food packaging materials or containers are sealed under the conditions of normal temperature to achieve certain functions.
4 Classification of Adhesives
4.1 In accordance with the dispersion media, the adhesives in food packaging materials and containers mainly include solvent-based adhesives, solvent-free adhesives and water-based adhesives.
4.2 In accordance with the purposes, the adhesives in food packaging materials and containers mainly include laminating adhesives, coextrusion adhesives and sealing adhesives.
a) all test films are transparent films without pollution, printing or coating;
b) the thickness of PET films is 12 µm and the thickness of PE films is 70 µm;
c) no slipping agent of PE films separates out and the surface tension of PE films after the corona treatment >= 38 mN/m.
7 Test Methods
7.8.2.3 The peel strength test is conducted as specified in GB/T 2791. The separation speed of the tester is changed from (100 ± 10) mm/min to (300 ± 10) mm/min.
7.8.2.2 Sample preparation
a) dilute and mix up adhesives in accordance with the operating instructions of adhesives;
b) apply the diluted adhesives uniformly on PET films and control the adhesive applying quantity (dry adhesive quantity) at 2.0 g/m² ~ 3.5 g/m²;
c) dry the PET films applied with adhesives for 2 min at 80°C to make the solvent fully evaporate and laminate PE films through the heating roll at 50°C ~ 70°C;
d) use heating and pressure composite roll (steel roll to rubber roll, the Shore A hardness of the rubber roll not lower than 85°) to press the laminated film, with the laminating pressure >= 1.0 MPa and the temperature controlled at 55°C ~ 60°C;
e) the laminated sample is conditioned for 48 h at 50°C ~ 55°C.
7.8.3 Peel strength of solvent-free polyurethane adhesives for laminating
7.8.3.1 Film materials
As in 7.8.2.1.
7.8.3.2 Sample preparation
a) prepare adhesives in accordance with the proportion of two components in accordance with the operating instructions of adhesives and mix up;
b) apply the adhesives mixed up on PET films on the solvent-free filming machine and control the adhesive applying quantity (dry adhesive quantity) within 1.8 g/m² ~ 2.2 g/m²;
c) press the PET films coated with adhesives and PE films, controlling the temperature of heating roll at 50°C ~ 65°C, and finish laminating after cooling PET/PE laminating films;
d) conduct curing under the curing conditions specified in the product specifications (at certain temperature and within certain time) of laminated samples and cut into sample strips as standby.
8 Inspection Rules
8.1 Batching and sampling
Inspection is conducted by batch and a batch consists of adhesives of the same material, composition and production process. The sampling quantity is as specified in GB 20740.
8.2 Delivery inspection
8.2.1 Delivery inspection for adhesives for laminating
8.2.1.1 The items of the delivery inspection of water-based adhesives include appearance, pH, nonvolatile content and viscosity.
8.2.1.2 The items of the delivery inspection of solvent-based adhesives include appearance, viscosity and nonvolatile content.
8.2.1.3 The items of the delivery inspection of solvent-free adhesives include appearance and viscosity.
8.2.2 Delivery inspection of adhesives for extrusion
The items of the delivery inspection include appearance, vicat softening temperature and melting rate.
8.2.3 Delivery inspection of adhesives for sealing
8.2.3.1 The items of the delivery inspection of hot melt adhesives include appearance, melting viscosity and softening temperature.
8.2.3.2 The items of the delivery inspection of water-based adhesives include appearance, pH, nonvolatile content and viscosity.
8.3 Type inspection
The type inspection is a full inspection. During normal production, the type inspection shall be conducted each year, as well as in one of the following situations.
a) when the trial-manufacture of a new product is evaluated;
b) when there is any significant change in materials or production processes which may influence the product quality;
c) when production is resumed after a production halt for more than half a year;
d) when there is significant difference between the results of delivery inspection and those of last type inspection; […]
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This preview omits tables, figures, formulas and parts of the technical clauses. The complete document — 15 pages — is available in the English PDF.
Referenced standards
Normative references
- GB/T 1633Plastics - Thermoplastic materials - Determination of Vicat softerning temperature(VST)
- GB/T 2791Adhesives, T peel strength test method for a flexible-to-flexible test specimen assembly
- GB/T 2793Test method for the non-volatile content of adhesives
- GB/T 2794Determination for viscosity of adhesives
- GB/T 2943Terms of adhesives
- GB/T 3682Determination of the melt mass-flow rate (MFR) and the melt volume-flow rate (MVR) of thermoplastics
HG/T 3660
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Related Standards
GB 9685-2016 — National food safety standard - Standard for the use of additives in food contact materials and articles
GB 9685-2025 — National Food Safety Standard — Standard for Uses of Additives in Food Contact Materials and Their Products
GB/T 14518-1993 — Determination of the pH of adhesives
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