GB/T 26370-2020Hygienic requirements for disinfectant containing bromine (English PDF)
含溴消毒剂卫生要求
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Issued by
SAMR; SAC
Level / Type
National · Recommended
Issue date
June 2, 2020
Implementation date
January 1, 2021
Scope
GB/T 26370-2020 is the English-translated version of 含溴消毒剂卫生要求.
GB/T 26370-2020 sets the hygienic requirements for bromine-containing disinfectants. It gives the raw material requirements, the technical requirements, the scope of application, the methods of use, the inspection methods, and the provisions on packaging, transport, storage, marking, labelling and instructions.
It applies to disinfectants whose bactericidal component is bromochloro-5,5-dimethylhydantoin or 1,3-dibromo-5,5-dimethylhydantoin. Disinfectant makers, water treatment operators and health inspectors use it.
Issued on 2 June 2020, it has applied since 1 January 2021, replacing GB 26370-2010.
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Document preview — GB/T 26370-2020
National Standard of the People's Republic of China
- ICS
- 11.080
- Classification
- C 50
- Replacing
- GB 26370-2010
Issued by: State Administration for Market Regulation; Standardization Administration of the PRC
Contents
- Foreword3
- 1 Scope6
- 2 Normative References6
- 3 Terms and Definitions7
- 4 Requirements for Raw Materials7
- 5 Technical Requirements7
- 6 Application Range9
- 7 Use Methods9
- 8 Inspection Methods9
- 9 Packaging, Transportation and Storage10
- 10 Marking, Label and Instruction Manual11
- Appendix A (Normative) Determination of Bromochloro-5,5-Dimethylhydantoin Content and Available Halogen (by Cl) Content12
- Appendix B (Normative) Determination of 1,3-Dibromo-5,5-Dimethylhydantoin Content and Available Bromine (by Br) Content15
Foreword
This Standard was drafted as per the rules specified in GB/T 1.1-2009.
This Standard replaced GB/T 26370-2010 Hygienic Standard for Disinfectants with Bromine. Compared with GB/T 26370-2010, this Standard has the major technical changes as follows:
--- Delete "Precautions" and "This Standard is not applicable the disinfectants combined the bromochloro-5,5-dimethylhydantoin or 1,3-dibromo-5,5-dimethylhydantoin with effective ingredients of other disinfectants" from the scope of the standard (see Clause1 of 2010 Edition);
--- Add the normative references (see Clause 2 of this Edition);
--- Modify the terms and definitions of bromine-containing disinfectants (see 3.1 of this Edition; 3.1 of 2010 Edition);
--- Delete the terms and definitions of general object surfaces (see 3.4 of 2010 Edition);
--- Modify the raw material requirements (see Clause 4 of this Edition; Clause 4 of 2010 Edition);
--- Delete the sensory attribute requirements (see 5.1 of 2010 Edition);
--- Increase the mass fraction requirements of bromine and chlorine (see Table 1 of this Edition);
--- Modify the requirements for the mass fraction of bromochloro-5,5-dimethylhydantoin, available halogen (by Cl) and loss on drying (see Table 1 of this Edition; Table 1 of 2010 Edition);
--- Delete the available halogen reduction rate index requirements within the validity period (see Table 1 of 2010 Edition);
--- Modify the requirements for the mass fraction of 1,3-dibromo-5,5-dimethylhydantoin, available bromine (by Br) and loss on drying (see Table 2 of this Edition; Table 2 of 2010 Edition);
--- Delete the available bromine reduction rate index requirements within the validity period (see Table 2 of 2010 Edition);
--- Increase the weight difference of the disinfectant product tablets produced by using bromochloro-5,5-dimethylhydantoin disinfectant or 1,3-dibromo-5,5-dimethylhydantoin disinfectant and other non-disinfecting factors (accessories); […]
1 Scope
This Standard specifies the raw material requirements, technical requirements, application scope, use methods, inspection methods, packaging, transportation and storage, marking, labeling and instruction manual of bromine-containing disinfectants.
This Standard is applicable to disinfectants that use bromochloro-5,5-dimethylhydantoin or 1,3-dibromo-5,5-dimethylhydantoin as the bactericidal component.
2 Normative References
The following documents are essential to the application of this document. For the dated documents, only the versions with the dates indicated are applicable to this document; for the undated documents, only the latest version (including all the amendments) is applicable to this document.
GB/T 191 Packaging - Pictorial Marking for Handling of Goods
GB/T 601 Chemical Reagent - Preparations of Standard Volumetric Solutions
GB/T 603 Chemical Reagent--Preparations of Reagent Solutions for Use in Test Methods
GB/T 6682 Water for Analytical Laboratory Use - Specification and Test Methods
GB/T 21845 Chemicals - Water Solubility Test
GB/T 23849 1,3-Dibromo-5,5-dimethylhydantoin
GB/T 23854 Bromochloro-5,5-dimethylhydantoin
Pharmacopoeia of the People's Republic of China (2015 Edition, Four Volumes)
Technical Standard for Disinfection (2002 Edition) [Ministry of Health (WFJF (2002) No.282]
3 Terms and Definitions
For the purpose of this document, the following terms and definitions apply.
3.1 Disinfectant containing bromine
The disinfectant, after dissolving in water, can be hydrolyzed to generate hypobromous acid and has a sterilizing effect.
3.2 Available bromine
The amount of bromine equivalent to the oxidizing ability of bromine-containing disinfectant, and measuring the oxidizing ability of bromine-containing disinfectant.
NOTE: Its content is expressed by mass concentration (mg/L) or mass fraction (%).
3.3 Available halogen
The total amount of halogen equivalent to the oxidizing ability of halogen-containing disinfectants, and measuring the oxidizing ability of halogen-containing disinfectant.
NOTE: Its content is expressed by mass concentration (mg/L) or mass fraction (%).
4 Requirements for Raw Materials
4.1 Bromochloro-5,5-dimethylhydantoin shall meet the technical index requirements for qualified products specified in GB/T 23854. If accessories are added, the accessories shall comply with relevant standards and regulations.
4.2 1,3-Dibromo-5,5-dimethylhydantoin shall meet the technical index requirements for qualified products specified in GB/T23849. If accessories are added, the accessories shall comply with relevant standards and regulations.
5 Technical Requirements
5.1 Physical and chemical index
5.1.1 Bromochloro-5,5-dimethylhydantoin disinfectant
The mass requirements shall comply with the provisions of Table 1. […]
8 Inspection Methods
8.2 Determination of solubility
It shall be carried out as per GB/T 21845.
8.3 Determination of loss on drying
8.3.1 1,3-Dibromo-5,5-dimethylhydantoin disinfectant shall be carried out as per the method specified in GB/T 23849.
8.3.2 Bromochloro-5,5-dimethylhydantoin disinfectant shall be carried out as per the method specified in GB/T 23854.
8.4 Determination of weight difference for tablets
It shall be carried out as per the method stipulated in The Pharmacopoeia of the People's Republic of China (2015 Edition, Four Volumes).
8.5 Determination of the disintegration time limit of effervescent tablets
It shall be carried out as per the method stipulated in The Pharmacopoeia of the People's Republic of China (2015 Edition, Four Volumes).
8.6 Determination of disinfection effect
It shall be carried out as per Technical Standard for Disinfection (2002 Edition).
9 Packaging, Transportation and Storage
9.1 Packaging
It shall meet the requirements of GB/T 23849 or GB/T 23854.
9.2 Transportation
During transportation, it shall not be mixed with other goods; and is forbidden to transport together with acids or alkalis, easily oxidized organic matter, and reducing substances. Covers shall be provided to prevent sunlight, rain, and moisture; and the packaging shall be kept intact and clearly marked.
9.3 Storage
It shall be stored in a cool, dry place; protected from the sun, rain, and moisture. It is forbidden to store together with acids or alkalis and easily oxidized organics and […]
Appendix A (Normative) Determination of Bromochloro-5,5-Dimethylhydantoin Content and Available Halogen (by Cl) Content
A.1 Principle
In acid solutions, bromine-containing disinfectants may oxidize potassium iodide to iodine. Use starch solution as indicator to titrate the generated iodine by sodium thiosulfate solution; and calculate the content of available halogen (by Cl) based on the consumed amount of sodium thiosulfate solution.
A.2 Reagents or materials
Safety Tips: Sulfuric acid is a strong acid and is corrosive, so pay attention to it when using. When splashing on the body, rinse with plenty of water, avoid inhalation or contact with skin.
Unless otherwise specified, the reagents used in this method are all analytically pure; and the test water is the Class-I water specified in GB/T 6682.
A.2.1 Potassium iodide solution: 300g/L potassium iodide (analytically-pure) solution.
A.2.2 Sulfuric acid solution: it is prepared by adding 1 portion of 95%~98% analytically-pure sulfuric acid to 5 portions of deionized water.
A.2.3 Starch indicator: 10g/L starch solution, prepared according to GB/T 603
A.2.4 Sodium thiosulfate solution: 0.1mol/L sodium thiosulfate titrant, prepared and calibrated according to GB/T 601
A.3 Apparatus
A.3.1 Electronic analytical balance: accuracy of 0.1mg.
A.3.2 Magnetic stirrer.
A.4 Test procedures
A.4.1 Powders and granules may be weighed directly; and tablets are weighed after grinding with a dry mortar.
A.4.2 Weigh 0.15g of sample (accurate to 0.0001g); add it to a dry and clean 250mL […]
Appendix B (Normative) Determination of 1,3-Dibromo-5,5-Dimethylhydantoin Content and Available Bromine (by Br) Content
B.1 Principle
In acid solutions, bromine-containing disinfectants may oxidize potassium iodide to iodine. Use starch solution as indicator to titrate the generated iodine by sodium thiosulfate solution; and calculate the available bromine content and 1,3-dibromo-5,5-dimethylhydantoin content according to the consumed amount of sodium thiosulfate solution.
B.2 Reagents or materials
Safety Tips: Sulfuric acid is a strong acid and is corrosive, so pay attention to it when using. When splashing on the body, rinse with plenty of water, avoid inhalation or contact with skin.
Unless otherwise specified, the reagents used in this method are analytically-pure, and the test water is the Class-I water specified in GB/T 6682.
B.2.1 Potassium iodide: analytically-pure
B.2.2 Sulfuric acid solution: it is prepared by adding 1 portion of 95% ~ 98% analytically-pure sulfuric acid to 8 portions of deionized water.
B.2.3 Starch indicator: 5g/L starch solution, prepared according to GB/T 603
B.2.4 Sodium thiosulfate solution: 0.1mol/L sodium thiosulfate titrant, prepared and calibrated according to GB/T 601
B.3 Apparatus
B.3.1 Electronic analytical balance: accuracy of 0.1mg.
B.3.2 Magnetic stirrer.
B.4 Test procedures
B.4.1 Powders and granules may be weighed directly; and tablets shall be weighed after grinding with a dry mortar. […]
......
This preview omits tables, figures, formulas and parts of the technical clauses. The complete document — 15 pages — is available in the English PDF.
Referenced standards
Normative references
- GB/T 191Graphical symbols marking for handling and storage of packages
- GB/T 601Chemical Reagent - Preparations of Standard Volumetric Solutions
- GB/T 603Chemical reagent - Preparations of reagent solutions for use in test methods
- GB/T 6682Water for analytical laboratory use - Specification and test methods
- GB/T 21845Chemicals -- Water solubility test
- GB/T 238491,3-Dibromo-5,5-dimethylhydantoin
Similar standards
Editions of GB/T 26370
| Edition | Title | Revision | Status |
|---|---|---|---|
| GB/T 26370-2020 | Hygienic requirements for disinfectant containing bromine | current edition | Current |
| GB 26370-2010 | Hygienic requirements for disinfectant containing bromine | previous edition | Superseded |
This page sells the current edition, GB/T 26370-2020. Earlier editions are listed for reference only.
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