GB/T 26008-2020Battery grade lithium hydroxide monohydrate (English PDF)
电池级单水氢氧化锂
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Issued by
SAMR; SAC
Level / Type
National · Recommended
Issue date
June 2, 2020
Implementation date
May 1, 2021
Scope
GB/T 26008-2020 is the English-translated version of 电池级单水氢氧化锂.
GB/T 26008-2020 is the Chinese standard for battery grade lithium hydroxide monohydrate. It gives the technical requirements, the test methods, the inspection rules, the provisions on marking, packaging, transport, storage and quality certificate, and the content of the order form or contract.
It applies to battery grade lithium hydroxide monohydrate produced by any method. Lithium producers, cathode material makers and battery makers use it. Issued on 2 June 2020, it has applied since 1 May 2021, replacing GB/T 26008-2010.
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Document preview — GB/T 26008-2020
National Standard of the People's Republic of China
- ICS
- 77.150.99
- Classification
- H 64
- Replacing
- GB/T 26008-2010
Issued by: State Administration for Market Regulation; Standardization Administration of the PRC
Contents
- Foreword3
- 1 Scope5
- 2 Normative References5
- 3 Terms and Definitions5
- 4 Technical Requirements6
- 5 Test Methods7
- 6 Inspection Rules7
- 7 Marking, Packaging, Transportation, Storage and Quality Certificates9
- 8 Order Form (or Contract) Contents10
- Appendix A (Normative) Determination of Boron Content in Battery-Grade Lithium Hydroxide Monohydrate by Inductively Coupled Plasma Atomic Emission Spectrometry12
- Appendix B (Normative) Determination of Magnetic Impurity Content in Battery-Grade Lithium Hydroxide Monohydrate by Inductively Coupled Plasma Atomic Emission Spectrometry17
Foreword
This Standard was drafted as per the rules specified in GB/T 1.1-2009.
This Standard replaced GB/T 26008-2010 Battery Grade Lithium Hydroxide Monohydrate. Compared with GB/T 26008-2010, this Standard made the major changes as follows.
--- Modify the scope of the standard (see Clause 1 of this Edition; Clause 1 of 2010 Edition);
--- Add the terms and definitions (see Clause 3 of this Edition);
--- Add the product appearance classification (see 4.1.2 of this Edition);
--- Modify the expression method of main content of LiOH (see 4.2 of this Edition; 3.2 of 2010 Edition);
--- Modify the content indicators of some elements (see 4.2 of this Edition; 3.2 of 2010 Edition);
--- Increase the content requirements of boron (see 4.2 of this Edition);
--- Increase the content requirements of magnetic impurity (see 4.3 of this Edition);
--- Add granularity requirements (see 4.4 of this Edition);
--- Modify the sampling provisions (see 6.4 of this Edition; 5.4 of 2010 Edition);
--- Modify the packaging requirements (see 7.2 of this Edition; 6.2 of 2010 Edition);
--- Add "determination of boron content in battery-grade lithium hydroxide monohydrate by inductively coupled plasma atomic emission spectrometry" (see Appendix A of this Edition);
--- Add "determination of magnetic impurity content in battery-grade lithium hydroxide monohydrate by inductively coupled plasma atomic emission spectrometry" (see Appendix B of this Edition).
1 Scope
This Standard specifies the technical requirements, test methods, inspection rules and marking, packaging, transportation, storage, quality certificates and order forms (or contracts) contents of battery grade lithium hydroxide monohydrate.
This standard is applicable to battery grade lithium hydroxide monohydrate produced by various methods.
2 Normative References
The following documents are essential to the application of this document. For the dated documents, only the versions with the dates indicated are applicable to this document; for the undated documents, only the latest version (including all the amendments) are applicable to this document.
GB 190-2009 Packing Symbol of Dangerous Goods
GB/T 191-2008 Packaging - Pictorial Marking for Handling of Goods
GB/T 6678 General Principles for Sampling Chemical Products
GB/T 11064 (all parts) Methods for Chemical Analysis of Lithium Carbonate, Lithium Hydroxide Monohydrate and Lithium Chloride
GB/T 19077 Particle Size Analysis - Laser Diffraction Methods
3 Terms and Definitions
For the purpose of this document, the following terms and definitions apply.
3.1 Magnetic impurity
A substance that can be directly or indirectly absorbed by a ferromagnet.
NOTE: It mainly refers to the magnetic substances in the transition elements, such as iron, chromium, nickel, zinc and their alloys. It refers to the combined amount of four elements of iron, chromium, nickel and zinc in this Standard.
4 Technical Requirements
4.1 Product classification
4.1.1 Battery grade lithium hydroxide monohydrate is divided into three designations according to chemical composition. LiOH·H2O-D1, LiOH·H2O-D2 and LiOH·H2O-D3.
4.1.2 Battery grade lithium hydroxide monohydrate is divided into crystal type and fine powder type according to appearance.
4.2 Chemical composition
The chemical composition of battery grade lithium hydroxide monohydrate shall conform to the provisions of Table 1.
4.3 Magnetic impurity
The magnetic impurity content in the product shall conform to the provisions of Table 2.
5 Test Methods
5.1 The chemical composition of the product shall be analyzed in accordance with the provisions of GB/T 11064 and Appendix A.
5.2 The magnetic impurity of the product shall be analyzed in accordance with the provisions of Appendix B.
5.3 The granularity of the product shall be analyzed in accordance with GB/T 19077.
5.4 The appearance quality of the product shall adopt the visual inspection method.
6 Inspection Rules
6.1 Inspection and acceptance
6.1.1 The product shall be inspected by the supplier to ensure that the product quality meets the requirements of this Standard and the order form (or contract); and fill in the quality certificate.
6.1.2 The purchaser shall inspect the received products in accordance with the provisions of this Standard. If the inspection results are inconsistent with the provisions of this Standard and the order form (or contract), they shall submit to the supplier in written form, which shall be resolved through consultation between the supplier and the purchaser. Objections pertaining to appearance quality shall be submitted within one month from the date of receipt of the product; objections pertaining to other properties shall be submitted within three months from the date of receipt of the product.
If arbitration is required, it shall be negotiated by both parties.
6.2 Batching
Products shall be submitted for acceptance in batches; and each batch of products shall consist of the same designation and the same mixture. The net weight of each batch of products shall not exceed 10t. When supplied in large-batch, the method of batching may be determined through consultation between the supplier and the purchaser.
6.3 Inspection items
Each batch of products shall be inspected for chemical composition, magnetic impurity, granularity, and appearance quality. The inspection items shall conform to the provisions of Table 3.
6.4 Sampling and sample preparation
6.4.1 Sampling method
The product sampling shall use a rigid polyvinyl chloride sampler; and the sampling tube is inserted into the 2/3 bag along the center of the bag. The taken sample is mixed well and then reduced to about 1000g by the quartering method.
6.4.2 Sampling quantity
It shall be performed according to the provisions of GB/T 6678; the sampling quantity shall conform to the provisions of Table 4.
6.5 Determination of inspection results
6.5.1 If the inspection results of chemical composition, magnetic impurity, and granularity of the product are unqualified, double the number of samples from this batch of products shall be taken to repeat the inspection for the unqualified items. If the repeated inspection results are all qualified, the entire batch of products shall be qualified. If there are still unqualified samples in the repeated inspection results, this batch of products is determined to be unqualified.
6.5.2 If the appearance quality of the product is unqualified, this batch of products is determined to be unqualified.
7 Marking, Packaging, Transportation, Storage and Quality Certificates
7.1 Marking
The product shall indicate.
a) Product name;
b) Batch number;
c) Net weight;
d) Designation;
e) Appearance;
f) Name of the supplier;
g) Number of this Standard;
h) Place of origin;
i) "Corrosive substance" mark in Table 2 of GB 190-2009;
j) "Fear of rain" mark in Table 1 of GB/T 191-2008;
k) Production license number for Industrial product.
7.2 Packaging
7.2.1 Crystal type product of battery grade lithium hydroxide monohydrate is packed by bags internally lined polyethylene (PE); externally cover the polypropylene (PP) bags or two to three-layer paper bags. The internal bag is tied or heat-sealed; and the sealing seam of the external bag is firm.
7.2.2 Fine powder type product of battery grade lithium hydroxide monohydrate is lined with aluminum-plastic composite bags and filled with nitrogen for protection; and is packaged with plastic film bags externally. The internal bag is heat-sealed, and the sealing seam of external bag is firm.
7.2.3 If there are other requirements for the packaging method of the product, the supplier and the purchaser shall negotiate. The net weight of each bag is executed according to customer requirements.
7.3 Transportation
Avoid contact with acid when transporting the product; and prevent the packaging bag from being damaged when handling; and pay attention to moisture proof.
7.4 Storage
The product shall be stored in a dry, acid-free environment. The storage period shall not exceed half a year.
8 Order Form (or Contract) Contents
The order form (or contract) for the products listed in this Standard shall include at least the following contents.
a) Product name;
b) Designation;
c) Appearance;
d) Net weight and number of pieces;
e) Number of this Standard;
f) others. […]
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This preview omits tables, figures, formulas and parts of the technical clauses. The complete document — 17 pages — is available in the English PDF.
Referenced standards
Similar standards
Editions of GB/T 26008
| Edition | Title | Revision | Status |
|---|---|---|---|
| GB/T 26008-2020 | Battery grade lithium hydroxide monohydrate | current edition | Current |
| GB/T 26008-2010 | Battery grade lithium hydroxide monohydrate | previous edition | Superseded |
This page sells the current edition, GB/T 26008-2020. Earlier editions are listed for reference only.
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Related Standards
GB 190-2009 — Packing symbol of dangerous goods
GB/T 11064.1-2024 — Methods for chemical analysis of lithium carbonate, lithium hydroxide monohydrate and lithium chloride - Part 1: Determination of lithium carbonate content - Titration
GB/T 11064.10-2013 — Methods for chemical analysis of lithium carbonate, lithium hydroxide monohydrate and lithium chloride - Part 10: Determination of chloride content - Silver chloride nephelometry method
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