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GB/T 23204-2008Determination of 519 pesticides and related chemicals residues in teas - GC-MS method (English PDF)

茶叶中519种农药及相关化学品残留量的测定 气相色谱-质谱法

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Issued by

SAMR; SAC

Level / Type

National · Recommended

Issue date

December 31, 2008

Implementation date

May 1, 2009

Scope

GB/T 23204-2008 is the English-translated version of 茶叶中519种农药及相关化学品残留量的测定 气相色谱-质谱法.

GB/T 23204-2008 is the Chinese standard "Determination of 519 pesticides and related chemicals residues in teas - GC-MS method".

Its scope clause reads: This standard specifies the green tea, black tea, Pu'er tea, oolong tea 490 pesticides and related chemicals (see Appendix A and Appendix F) residue Gas chromatography - mass spectrometry, as well as green tea, black tea, Pu'er tea, oolong tea 29 acidic herbicide residues gas chromatography - Mass spectrometry.

This standard applies to green tea, black tea, Pu'er tea, oolong tea 490 pesticides and related chemicals residues in the qualitative identification, which may be set Determination of the amount of pesticides and related chemicals 453 kinds, as well as green tea, black tea, Pu'er tea, oolong tea dichloro picolinic acid, acid tone of chlorophenoxy acetic Acid, dicamba, 2-methyl-4-chloro, 2,4-D acid, bromoxynil, 2,4-D, triclopyr acid, 1-naphthaleneacetic acid, 5-chloro-phenol, 2,4 , 5 drops of propionic acid, Chloramben, 2-methyl -4- neoprene acid, 2,4,5-T, fluroxypyr, 2,4-D acid, bentazone, ioxynil, picloram, quinclorac, fluazifop Ling, haloxyfop, straw fluorine, acifluorfen, ethyl sulfide grass, fenhexamid, quizalofop, bispyribac 29 acidic herbicide residues Determination.

453 kinds of pesticides and related chemicals present standard quantitative determination of the detection limit of 0.001mg/kg ~ 0.500mg/kg (see attached Record A), 29 acidic herbicide method detection limit of 0.01mg/kg.

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Document preview — GB/T 23204-2008

National Standard of the People's Republic of China

Classification
X 04

Issued by: State Administration for Market Regulation; Standardization Administration of the PRC

Contents

  • Introduction
  • 1 Scope
  • 2 Normative references
  • 3 Tea 490 pesticides and related chemicals residues by gas chromatography - mass spectrometry
  • 3.1 Principle
  • 3.2 Reagents and materials
  • 3.3 Instrument
  • 3.4 Sample Preparation and Storage
  • 3.5 Determination of Step
  • 3.6 Calculation Results
  • 3.7 Precision
  • 4 tea 29 acidic herbicide residues by gas chromatography - mass spectrometry
  • 4.1 Principle
  • 4.2 Reagents and materials
  • 4.3 Instrument
  • 4.4 Sample Preparation and Storage
  • 4.5 Determination of Step
  • 4.6 Calculation Results
  • Appendix A (informative) tea 490 pesticides and related chemicals Chinese and English name, the detection limit,
  • Annex B (informative) retention time tea 490 pesticides and related chemicals and the internal standard compound,
  • Annex C (informative) tea 490 pesticides and related chemicals A, B, C, D, E, F six groups
  • Annex D (informative) tea 490 pesticides and related chemicals in the tea matrix reference materials
  • Annex E (informative) tea 490 pesticides and related chemicals precision data table
  • Annex F (informative) tea 490 pesticides and related chemicals English name Chinese control index
  • Annex G (informative) tea 29 acidic herbicide retention time, ion quantitative and qualitative ion
  • Appendix H (informative) tea 29 acidic herbicide selected ion monitoring packet table
  • Annex I (informative) tea 29 acidic herbicide Standards SIM chromatograms
  • Appendix J (informative) tea 29 acidic herbicide precision data table

1 Scope

This standard specifies the green tea, black tea, Pu'er tea, oolong tea 490 pesticides and related chemicals (see Appendix A and Appendix F) residue

Gas chromatography - mass spectrometry, as well as green tea, black tea, Pu'er tea, oolong tea 29 acidic herbicide residues gas chromatography -

Mass spectrometry.

This standard applies to green tea, black tea, Pu'er tea, oolong tea 490 pesticides and related chemicals residues in the qualitative identification, which may be set

Determination of the amount of pesticides and related chemicals 453 kinds, as well as green tea, black tea, Pu'er tea, oolong tea dichloro picolinic acid, acid tone of chlorophenoxy acetic

Acid, dicamba, 2-methyl-4-chloro, 2,4-D acid, bromoxynil, 2,4-D, triclopyr acid, 1-naphthaleneacetic acid, 5-chloro-phenol, 2,4 , 5 drops of propionic acid,

Chloramben, 2-methyl -4- neoprene acid, 2,4,5-T, fluroxypyr, 2,4-D acid, bentazone, ioxynil, picloram, quinclorac, fluazifop

Ling, haloxyfop, straw fluorine, acifluorfen, ethyl sulfide grass, fenhexamid, quizalofop, bispyribac 29 acidic herbicide residues

Determination.

453 kinds of pesticides and related chemicals present standard quantitative determination of the detection limit of 0.001mg/kg ~ 0.500mg/kg (see attached

Record A), 29 acidic herbicide method detection limit of 0.01mg/kg.

2 Normative references

The following documents contain provisions which, through reference in this standard and become the standard terms. For dated references, subsequent

Amendments (not including errata content) or revisions do not apply to this standard, however, encourage the parties to the agreement are based on research

Whether the latest versions of these documents. For undated reference documents, the latest versions apply to this standard.

GB/T 6379.1 measurement methods and results of Accuracy (trueness and precision) - Part 1. General principles and definitions (GB/T 6379.1-2004, ISO 5725-1.1994, IDT)

GB/T 6379.2 measurement methods and results of Accuracy (trueness and precision) - Part 2. Determine the standard measurement method to repeat

Of the basic methods of reproduction (GB/T 6379.2-2004, ISO 5725-2.1994, IDT)

SN/T 0918-2000 and export of tea sampling method

3 Tea 490 pesticides and related chemicals residues by gas chromatography - mass spectrometry

3.1 Principle

Homogenized sample with acetonitrile extraction, solid-phase extraction (SPE), eluted with acetonitrile - toluene pesticides and related chemicals, gas chromatography - mass spectrometry detection

Measurement, internal standard.

3.2 Reagents and materials

3.2.1 acetonitrile

chromatography.

3.2.2 Toluene

pure class distinctions.

3.2.3 acetone

AR, redistilled.

3.2.4 dichloromethane

chromatography.

3.2.5 n-hexane

AR, redistilled.

3.2.6 Methanol

chromatographically pure.

3.2.7 Anhydrous sodium sulfate

AR. 650 °C burning 4h, stored in a desiccator, cool reserve.

3.2.8

acetonitrile - toluene (3 + 1, volume ratio).

......
This preview omits tables, figures, formulas and parts of the technical clauses. The complete document — 62 pages — is available in the English PDF.

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