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GB/T 15922-2010Method for chemical analysis of cobalt ores - Determination of cobalt content (English PDF)

钴矿石化学分析方法 钴量测定

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Issued by

SAMR; SAC

Level / Type

National · Recommended

Issue date

November 10, 2010

Implementation date

February 1, 2011

Scope

GB/T 15922-2010 is the English-translated version of 钴矿石化学分析方法 钴量测定.

GB/T 15922-2010 is the Chinese standard "Method for chemical analysis of cobalt ores - Determination of cobalt content". Its scope clause reads: This standard specifies the acid dissolution or alkali fusion after separating prepared acidic solution, spectrophotometric determination of cobalt ore cobalt atomic absorption method.

This standard applies to the determination of cobalt content of cobalt ore. Measuring range. 0.05% to 2.0% cobalt. Its clauses include reagents.

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Document preview — GB/T 15922-2010

National Standard of the People's Republic of China

ICS
73.060
Classification
D 42
Replacing
GB/T 15922-1995

Issued by: State Administration for Market Regulation; Standardization Administration of the PRC

Contents

  • 1 Scope
  • 2 Normative references
  • 4 Reagents
  • 4.8 aqua regia
  • 4.12 Cobalt standard solution

1 Scope

This standard specifies the acid dissolution or alkali fusion after separating prepared acidic solution, spectrophotometric determination of cobalt ore cobalt atomic absorption method.

This standard applies to the determination of cobalt content of cobalt ore.

Measuring range. 0.05% to 2.0% cobalt.

2 Normative references

The following documents contain provisions which, through reference in this standard and become the standard terms. For dated references, subsequent

Amendments (not including errata content) or revisions do not apply to this standard, however, encourage the parties to the agreement are based on research

Whether the latest versions of these documents. For undated reference documents, the latest versions apply to this standard.

Laboratory use specifications and test methods GB/T 6682 Analysis

Principle 3

Sample hydrofluoric acid, after aqua regia, perchloric acid decomposition with hydrochloric acid dissolved salt (or sodium peroxide, sodium hydroxide melt ore, water extraction, filtration,

The precipitate was dissolved in hydrochloric acid) in 5% hydrochloric acid medium, atomic absorption spectrophotometer, at a wavelength of 252.1nm, using air - acetylene fire

Flame, cobalt absorbance was measured to calculate the amount of cobalt.

4 Reagents

Unless otherwise indicated, the use of analytical reagents and in line with GB/T 6682 or equivalent purity distilled water in the analysis.

4.1

sodium peroxide.

4.2

sodium hydroxide.

4.3

hydrochloride (rho1.19g/mL).

Nitrate 4.4 (rho1.40g/mL).

4.5

Hydrofluoric acid (rho1.13g/mL). WARNING. Hydrofluoric acid is toxic and corrosive, the operation should wear gloves to prevent skin contact 4.6 perchloric acid (rho1.67g/mL). Warning. explosive materials, careful 4.7 ethanol.

4.8 aqua regia

[hydrochloric acid (4.3) nitrate (4.4)] = (31), freshly prepared.

4.9

hydrochloride (11).

4.10

nitric acid (11).

4.11

Sodium hydroxide solution (20g/L).

4.12 Cobalt standard solution

Weigh 0.1000g of cobalt metal (mass fraction >=99.99%), placed in 100mL beaker covered with a watch glass, along

Beibi added 20mL of nitric acid (4.10), heated and dissolved, evaporated on a water bath. With a small amount of water purged Petri dish, was added 5mL hydrochloric acid (4.3),

Evaporated on a water bath, repeat. Was added 10mL of hydrochloric acid (4.3) to dissolve the cobalt salt, cooled and transferred to 1000mL volumetric flask, and dilute with water

Release to the mark. Cobalt concentration of the solution is 0.10mg/mL.

......
This preview omits tables, figures, formulas and parts of the technical clauses. The complete document — 15 pages — is available in the English PDF.

Similar standards

Editions of GB/T 15922

EditionTitleRevisionStatus
GB/T 15922-2010Method for chemical analysis of cobalt ores - Determination of cobalt contentcurrent editionCurrent
GB/T 15922-1995Method for chemical analysis of cobalt ores - Determination of cobalt contentprevious editionSuperseded

This page sells the current edition, GB/T 15922-2010. Earlier editions are listed for reference only.

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