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GB/T 13025.12-2012General test method in salt industry - Determination of barium (English PDF)

制盐工业通用试验方法 钡的测定

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Issued by

General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China; Standardization Administration of China

Level / Type

National · Recommended

Issue date

June 29, 2012

Implementation date

December 1, 2012

Scope

GB/T 13025.12-2012 is the English-translated version of 制盐工业通用试验方法 钡的测定.

GB/T 13025.12-2012 is the twelfth part of the Chinese national series of general test methods for the salt industry, and it gives the method for determining barium in salt products.

It is a graphite-furnace atomic absorption method: the prepared sample is injected into a graphite furnace atomizer, the barium it contains is dissociated into an atomic vapour by high-temperature evaporation, and the ground-state atoms absorb the resonance line of a barium hollow-cathode lamp, the absorption intensity being proportional to the barium concentration over a certain range.

The document covers the principle, the reagents - analytical-grade reagents and grade 2 water to GB/T 6682-2008, an ammonium nitrate solution and a vanadium solution made from vanadium pentoxide - the apparatus, the analytical procedure, the calculation and the accuracy.

It replaces GB/T 13025.12-1994, was issued on 29 June 2012 and has applied since 1 December 2012.

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Document preview — GB/T 13025.12-2012

National Standard of the People's Republic of China

ICS
71.060.50
Classification
X35

Issued by: General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China; Standardization Administration of China

Contents

  • Foreword3
  • 1 Scope5
  • 2 Normative References5
  • 3 Principle5
  • 4 Reagents5
  • 5 Apparatus6
  • 6 Analytical Procedure6
  • 7 Calculation7
  • 8 Accuracy7

Foreword

This Standard belongs to a complete group of general test method standards in salt industry; the complete group comprises the following 13 parts at present; and other test method standards will be developed in the future, if necessary.

-- GB/T 13025.1 General Test Method in Salt Industry - Determination of Grain Size -- GB/T 13025.2 General Test Method in Salt Industry - Determination of Whiteness -- GB/T 13025.3 General Test Method in Salt Industry - Determination of Moisture -- GB/T 13025.4 General Test Method in Salt Industry - Determination of Insoluble Matter -- GB/T 13025.5 General Test Method in Salt Industry - Determination of Chloride -- GB/T 13025.6 General Test Method in Salt Industry - Determination of Calcium And Magnesium -- GB/T 13025.7 General Test Method in Salt Industry - Determination of Iodine -- GB/T 13025.8 General Test Method in Salt Industry - Determination of Sulfate -- GB/T 13025.9 General Test Method in Salt Industry - Determination of Lead -- GB/T 13025.10 General Test Method in Salt Industry - Determination of Ferrocyanide -- GB/T 13025.11 General Test Method in Salt Industry - Determination of Fluoride -- GB/T 13025.12 General Test Method in Salt Industry - Determination of Barium -- GB/T 13025.13 General Test Method in Salt Industry - Determination of Arsenic This Standard is the part 12 of GB/T 13025.

This Standard was drafted in accordance with the rules given in GB/T 1.1-2009.

This Standard replaces GB/T 13025.12-1994, General Test Method in Salt Industry - Determination of Barium Ion. Compared with GB/T 13025.12-1994, the main technical differences of this Standard, except editorial modifications, are as follows.

-- it optimizes the conditions and parameters of graphite furnace;

1 Scope

This Part of GB/T 13025 specifies the method for determination of barium in salt products.

This Standard applies to the determination of barium in salt products.

2 Normative References

The following referenced documents are indispensable for the application of this document. For dated references, only the edition dated applies to this document. For undated references, the latest edition of the referenced document (including any amendments) applies to this Standard.

GB/T 6682-2008 Water for Analytical Laboratory Use - Specification and Test Methods

3 Principle

Sample is injected into a graphite furnace atomizer after it is processed properly; the barium contained dissociated into an atomic vapour in the graphite pipe through high temperature evaporation; the ground state atoms absorbs the resonance line emitted from barium hollow cathode lamp, and its absorption intensity is proportional to the concentration of barium within a certain range.

4 Reagents

4.1 Specifications of reagents

Unless otherwise specified, only reagents identified as Analytical Grade and Grade 2 water as specified in GB/T 6682-2008 are used in the analysis.

4.2 Ammonium nitrate (300 g/L)

Measure 30 g of ammonium nitrate; use water to dilute to 100 mL.

4.3 Vanadium solution (1.0 g/mL)

Weigh 0.178 5 g of vanadium pentoxide; dissolve in 100 mL of hydrochloride acid (5 + […]

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This preview omits tables, figures, formulas and parts of the technical clauses. The complete document — 8 pages — is available in the English PDF.

Referenced standards

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Editions of GB/T 13025.12

EditionTitleRevisionStatus
GB/T 13025.12-2012General test method in salt industry - Determination of bariumcurrent editionCurrent
GB/T 13025.12-1994General test method in salt industry-Determination of barium ionprevious editionSuperseded

This page sells the current edition, GB/T 13025.12-2012. Earlier editions are listed for reference only.

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