GB 26387-2011Safety of toys - Experimental sets for chemistry and related activities (English PDF)

Foreword

All the technical contents of this standard is mandatory. This standard is specific requirements and chemical experiments toy similar activities, and GB 6675 series of standards, GB 19865 (applies to Games A) used in combination. This revised standard adopts BSEN71-4.2007 "experiment toy toy safety chemistry and similar activities." This standard BSEN71-4. Compared to 2007, the main technical differences are as follows:

--- Modify the risk of danger signs and symbols marking requirements;

--- Modify the labeling requirements;

--- Modified Goggle's impact test;

--- Adjustments to the original text of section 5.2.6 "borosilicate glass density determination method of identifying" as Appendix A. This standard Annex A, Annex B normative appendix. The standard proposed by China National Light Industry Council. This standard by the National Toy Standardization Technical Committee (SAC/TC253) centralized. This standard was drafted. Guangdong Entry-Exit Inspection and Quarantine Bureau Technology Center Toys Lab, SZCIQ play With detection technology center, Ningbo CIQ light industrial products testing center, eastern Guangdong CIQ Toy Testing Heart, Guangzhou CVC Testing Institute, Guangdong Alpha Animation and Culture Co., Ltd., Beijing Certification Center of Light. The main drafters of this standard. Liuchong Hua, Han Fang, Jiang Liyuan, Ruan Jian Miao, Wang Yu, Fan Cen Liang, Wang Long. Toys Toys and chemical safety experiment similar activities

1 Scope

GB 26387-2011 is the Chinese national standard on safety of toys - experimental sets for chemistry and related activities, in the field of domestic and commercial equipment, entertainment, sport. It carries no /T suffix, which in the Chinese system means compliance is mandatory: a product or a practice within its scope has to meet it to be lawfully made, sold or carried out in China. It was issued on 12 May 2011 by the General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China; Standardization Administration of China, and has been in force since 15 September 2011. Classification: ICS 97.200.50, CCS Y57. This page is published from the official record of the standard held by the Chinese standards administration: the identification, the dates, the classification and the issuing body are taken from there. The clause text, the tables and the numeric limits are in the document itself, which is delivered complete in English translation.

This standard specifies the particular substances and preparations and chemical experiments toy similar activities can be used and the maximum amount, as well as the class Labeling requirements for toys, the contents list, instructions for use and for testing equipment. This standard applies to chemistry experiment toys and attachments.

2 Normative references

The following documents contain provisions which, through reference in this standard and become the standard terms. For dated references, subsequent Amendments (not including errata content) or revisions do not apply to this standard, however, encourage the parties to the agreement are based on research Whether the latest versions of these documents. For undated reference documents, the latest versions apply to this standard.

GB/T 531 pocket rubber hardness indentation hardness test methods

GB 5296.5 consumer use - Part 5. Toys

GB 6675 National Safety Technical Code for Toys

GB 13690 chemical classification and hazard communication General

ISO 868 plastics and hard rubber durometer using the indentation hardness [Plasticsandebonite-Determinationofin- dentationhardnessbymeansofadurometer (shorehardness)] Requirements and test methods

ISO 8317 open child-resistant packaging reclosable package (Child-resistantpackaging- Requirementsandtestingproceduresforreclosablepackages)

3 Terms and Definitions

The following terms and definitions apply to this standard.

3.1 Chemistry Experiment Toys chemistryset Experimental toys containing one or more chemical substances and/or chemical preparations, whether or not with equipment for chemical testing.

Note. This definition also applies to test toys mineralogy, biology, physics, microscopy, environmental science and other fields, as long as they contain one or more Chemical substances and chemical preparations.

3.2 Additional means supplementaryset Chemical plants and chemical experiments toy sets used in conjunction.

4 Chemicals

4.1 Tables 1 and 2 chemical substances, chemical preparations and chemical indicator can be used to test toys, used in an amount not exceeding the Limit specified in the table. Indicator provided in the form of a solution having a solid content should not exceed the limits specified in Table 2. Table 1 chemical substances and products with limited risk category Chemical substances and preparations of the maximum amount in each toy hazard class a CAS Registry Number Aluminum potassium sulfate b 10g - 10043-67-

5 Hexamethylene tetramine (solid fuel) 10g hazardous, flammable solids h 100-97-

0 Iron/iron b, g 100g flammable solids h 7439-89-

6 Zinc dust and zinc particles 20g flammable when wet h 7440-66-

6 Zinc sulfate (heptahydrate) 20g harmful 7446-20-0 a Chemical Abstracts Service (CAS) registration number only for data usage. b In addition to labeling substances, other substances according to IUPAC rules. c Each toy can only use one of these substances. d only for toys intended for children over 12 years of use. e denatured alcohol (ethanol). f "bad" applies to iodine, which does not apply to ethanol. G substance classification should be based on manufacturer data of the most rigorous self-consistent classification. h danger signs referring to GB 13690. i should give the following risk warnings and safety tips phrases. Clove Risk Warning. may cause skin irritation; Safety Tips. Avoid contact with skin. Table 2 limit indicator and hazard class Indicator name Each toys The maximum amount of Risk category a CAS Registry Number Eosin (eosin) b, d 1g irritating 17372-87-

1 Iodine [2.5% (mass concentration)] of potassium iodide [2.5% (mass concentration Degree)] solution 10mL harmful c 7553-56-

2 Litmus blue b 1g - - Red litmus b 1g - 1393-92-6 A mixture of luminol and sodium sulfate (

5.95 mass fraction) b, d 3g harmful 521-31-3 TABLE 2 (cont.) Indicator name Each toys The maximum amount of Risk category a CAS Registry Number Methyl orange b, d and sodium sulfate mixture (20.80, mass fraction) 3g toxic e 547-58-

0 Methylene Blue b, d 1g harmful 67-73-4 D 1g irritating 143-74-8 phenol red Thymol blue 1g - 76-61-

9 General dispersion strip b 1 package - - a Chemical Abstracts Service (CAS) registration number only for data usage. b In addition to labeling substances, other substances according to IUPAC rules. c "bad" applies to iodine, which does not apply to ethanol. D material classification shall be carried out according to the manufacturer data the most rigorous self-consistent classification. e danger signs referring to GB 13690. If chemical toys containing dangerous substances and preparations in nature, should be the appropriate label on its container.

Note 1. The quality of the chemicals used to meet the requirements of the test, in particular does not contain a clear response and not cause dangerous impurities or components.

Note 2. Book, inks will not bleed or picture indicator far below the relevant toxicological criteria, the amount used in Table 2 are not limiting.

4.2 denatured methylated spirit and Table 3 lists the reagent can be used as specified, but should not be provided with the toy together. Table

3 Chemical Experiment in toys may not be provided but allows maximum concentration of the reagents and hazard category Name of the reagent maximum concentration/(mol/L) hazard class a CAS Registry Number 2 1336-21-6 irritating ammonia 2 7647-01-0 irritating hydrochloric acid Hydrogen peroxide b 1 - 7722-84-0 1 c 1310-73-2 caustic sodium hydroxide solution a Chemical Abstracts Service (CAS) registration number only for data usage. b hydrogen peroxide concentration of 3% (volume fraction) solution. c danger signs referring to GB 13690.

4.3 In addition to Tables 1 and 2 outside the other substances should not be provided together with the toy 1. However, the instructions may not require the use of a dangerous nature Other substances or preparations of substances, such as sugar.

5.1 General Requirements Toys should be attached to the use of chemical experiment instructions, instructions for use should be required to complete the description of the test vessel, eye protection, and the necessary test tube rack. Additional means should be set out in clause 8 the contents of the list, according to

6.3.3 for the label. All tests specified by the manufacturer to evaluate, in particular, the amount of material generated by the test should not be hazardous to health. NOTE. For detailed description of known hazards during use toys especially produced during the test. For example. chemicals and glassware operation, boiling delay, condensed Hot water return to the operating glassware, as well as changes in gas furnaces and other heating devices.

7 Potassium permanganate. sodium sulfate mixture (

1.2 mass fraction) 10g harmful oxidizing h - Silver nitrate g [1% (mass concentration) solution] 10mL harmful 7761-88-

8 Table 1 (continued) Chemical substances and preparations of the maximum amount in each toy hazard class a CAS Registry Number Sodium acetate 20g - 127-09-3 50g of sodium carbonate 497-19-8 irritating Sodium chloride 100g - 7647-14-

8 Owner's Manual

8.1 General Description Instructions should use standard Chinese characters.

6.3 packaging labeling provisions should be repeated on the operating instructions written on the cover. Instructions on the first page should contain a list of the contents of this product. Inventory information should refer to the requirements of

8.2 and 8.3. Each test procedure shall be described in detail. When appropriate, should be adapted to increase the risk of each specific substance in the course of trial operation descriptions, phrases and safety measures occur predictable When the accident first aid information. It should also be given through the use of chemical disposal, including not provided with the toy, but to use during the test substance And preparations. It should be emphasized the need to dispose of these substances, for example. experiment with food. Chemical disposal instructions shall refer to the national regulations regarding the handling of similar substance. Instructions inside pages shall contain the following information.

a) adult supervision and advice (see 8.2);

b) the information required in Chapter 7;

c) security rules (see 8.3).

8.2 adult supervision advice Adult advice should include the following. "A) read the instructions, safety rules, emergency information and reference implementation of the specification to retain for reference.

b) incorrect use of chemicals can cause injuries and health hazards, can only test specification listed.

c) The chemical experiments only toys for children 10 years old or more (under certain circumstances only for children 12 years old or more).

d) due to the ability of children it is different, even within the same age group, adult supervision should determine which tests are appropriate for children Together, safe. Instructions should enable supervisors to assess any particular child for a test of suitability.

e) Before starting the test, the adult should supervise the child or children about the warnings and safety information, with particular attention Acids, alkalis and flammable liquids operations.

f) field test conducted away from food storage place, there should be no obstructions around. Lighting and ventilation to be good, close to the water. Bench should be strong, desktop heat.

g) furnace instructions. "

8.3 Safety Rules Shall set out the following safety rules. "Please read the instructions before use, follow the instructions and keep the manual for reference.

9 Charcoal b 100g - 7440-44-

0 Citric acid 77-92-9 irritating g 20g Clove b, g, 10mL harmful 84961-50-