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GB/T 6645-2008Granulated electric furnace phosphorous slag used for cement (English PDF)

用于水泥中的粒化电炉磷渣

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Issued by

SAMR; SAC

Level / Type

National · Recommended

Issue date

June 30, 2008

Implementation date

April 1, 2009

Scope

GB/T 6645-2008 is the English-translated version of 用于水泥中的粒化电炉磷渣.

This standard fixes the terms and definitions, technical requirements, test methods and inspection rules for granulated electric furnace phosphorous slag used for cement.

Clause 1 states that it applies to granulated electric furnace phosphorous slag used for cement mixture, and the page records no exclusion.

Its contents run Foreword, 1 Scope, 2 Normative References, 3 Terms and Definitions, 4 Technical Requirements, 5 Test Methods, 6 Inspection Rules, 7 Transportation and Storage, 8 Requirements of Usage and the normative Appendix A, Determination Method of Bulk Weight of Granulated Electric Furnace Phosphorous Slag.

Clause 3 defines granulated electric furnace phosphorous slag as the molten material, whose primary element is calcium silicate, that is obtained when the electric furnace method is used to prepare yellow phosphorus and is then quench granulated.

Clause 4 requires the mass coefficient K of raw phosphorous slag to be not less than 1.1 and the mass fraction of phosphorous pentoxide to be not more than 3.5 %, forbids mixing in foreign substances such as phosphorus mud and requires the radioactivity of the slag to satisfy GB 6566; clause 5 refers the determination of calcium oxide, magnesium oxide, silicon dioxide, aluminium oxide, fluorine and phosphorus pentoxide to the method in JC/T 1088 and sets out the 10 mm circular sieve test for granule content over 10 mm and the grinding of the sample to under 0.16 mm for the radioactivity test; clause 6 fixes the sampling method, treating the slag discharged every half month as one batch and quartering at least 20 kg of mixed sample down to 5 kg for test, and covers type inspection and determination rules.

Clause 7 requires that phosphorus slag in bulk transport not be mixed with other materials and that the wagon or compartment be cleaned, and clause 8 requires a cement enterprise that starts using phosphorous slag from a supply side to carry out an acceptance inspection against all the requirements of chapter 4.

Clause 2 cites GB 175 and GB/T 6003.2, and Appendix A sets out the instruments and the test for bulk weight.

The foreword says the standard was proposed by China Building Materials Federation, is under the jurisdiction of the National Technical Committee on Cements of Standardization Administration of China (SAC/TC 184) and had China Building Materials Academy as its responsible drafting organization.

It replaces GB/T 6645-1986, was issued on 30 June 2008 and has applied since 1 April 2009.

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Document preview — GB/T 6645-2008

National Standard of the People's Republic of China

ICS
91.100.10
Classification
Q 12
Replacing
GB/T 6645-1986

Issued by: State Administration for Market Regulation; Standardization Administration of the PRC

Contents

  • Foreword3
  • 1 Scope4
  • 2 Normative References4
  • 3 Terms and Definitions4
  • 4 Technical Requirements5
  • 5 Test Methods5
  • 6 Inspection Rules6
  • 7 Transportation and Storage7
  • 8 Requirements of Usage7
  • Appendix A (Normative) Determination Method of Bulk Weight of Granulated Electric Furnace Phosphorous Slag8

Foreword

This Standard replaces GB/T 6645-1986 Granulated Electric Furnace Phosphorous Slag Used for Cement Production.

In comparison with GB/T 6645-1986, this Standard has the following main changes.

---NOTE is added to the definition of granulated electric furnace phosphorous slag (Chapter 2 in Version 1986; Chapter 3 in this version);

---Radioactive indexes and corresponding inspection methods of phosphorous slag are added (4.6 in this version; 5.7 in this version);

---Inspection rules specifically stipulate the determination rules of exit-factory inspection and type inspection of phosphorous slag (Chapter 4 in Version 1986; 6.5 in this version);

---Appendix A in the previous standard is modified into determination method of bulk weight of granulated electric furnace phosphorous slag; Appendix B in the previous standard is deleted.

Appendix A in this Standard is normative.

1 Scope

This Standard specifies the terms, definitions, technical requirements, test methods and inspection rules of granulated electric furnace phosphorous slag used for cement.

This Standard is applicable to granulated electric furnace phosphorous slag used for cement mixture.

2 Normative References

Through the quotation in this Standard, clauses in the following documents become clauses in this Standard. In terms of references with a specific date, all the subsequent modification sheets (excluding corrected content) or revised versions are not applicable to this Standard. However, all parties that reach an agreement in accordance with this Standard are encouraged to explore the possibility of adopting the latest versions of these documents. In terms of references without a specific date, the latest versions are applicable to this Standard.

GB 175 Common Portland Cement

GB/T 6003.2 Test Sieves of Perforated Metal Plate

3 Terms and Definitions

The following terms and definitions are applicable to this Standard.

Granulated Electric Furnace Phosphorous Slag When electric furnace method is adopted to prepare yellow phosphorus, molten material, whose primary element is calcium silicate, is obtained. Through quenching granulation, it becomes granulated electric furnace phosphorous slag (phosphorous slag, for short).

4 Technical Requirements

4.1 Mass coefficient K of raw phosphorous slag shall be not less than 1.1.

4.2 In phosphorous slag, mass fraction of phosphorous pentoxide shall be not more than 3.5%.

4.5 Any foreign substances, for example, phosphorus mud, shall not be mixed into it.

4.6 Conduct the inspection in accordance with 5.6, the radioactivity of phosphorous slag shall satisfy relevant requirements in GB 6566.

5 Test Methods

5.1 Calcium Oxide, Magnesium Oxide, Silicon Dioxide, Aluminum oxide, Fluorine Content and Phosphorus Pentoxide Content

Conduct the test in accordance with the method in JC/T 1088.

5.2 Mass Fraction K

Mass fraction of raw phosphorus slag shall be calculated in accordance with Formula (1). The calculation result shall retain two decimal places.

5.4 Granule Content over 10 mm

Use 10 mm circular sieve, whose aperture satisfies the requirement in GB/T 6003.2 to test granule content. Dry phosphorous slag at (105 ± 5) °C to constant weight, then, weigh-take 2 kg of phosphorous slag sample, place it in the sieve. Manually vibrate it, till there is no apparent sample passing through, then, weigh the residue on the sieve.

Mass fraction of granule over 10 mm shall be calculated in accordance with Formula (2). The calculation result shall retain to integer.

5.6 Radioactivity

Grind phosphorous slag powder into refined powder whose granule size shall be less than 0.16 mm.

6 Inspection Rules

6.1 Sampling Method

Phosphorous slag, which is discharged every half a month, shall be deemed as one batch here. Sample can be taken continuously; or an equivalent amount of sample can be taken from over 20 different parts and the total amount of the sample shall be at least 20 kg. After thoroughly mixing the sample, use quartering method to quarter the sample to 5 kg for tests. During sampling, eliminate 150 mm ~ 200 mm surface layer.

6.3 Type Inspection

Under one of the following circumstances type inspection shall be conducted in accordance with all the requirements in Chapter 4.

6.4 Determination Rules

7 Transportation and Storage

In bulk transportation, phosphorus slag shall not be mixed with other materials. Wagon or compartment must be cleaned up, so as to avoid the mixture with foreign substances.

In terms of storage, foreign substances shall not be mixed with phosphorus slag.

8 Requirements of Usage

When a cement enterprise starts using phosphorous slag provided by the supply side, it shall conduct acceptance inspection in accordance with all the requirements in Chapter 4.

Appendix A (Normative) Determination Method of Bulk Weight of Granulated Electric Furnace Phosphorous Slag

A.1 Instruments

A.1.3 Steel ruler

The length of steel ruler shall be not less than 150 mm.

A.1.4 Platform scale

The division value of platform scale shall be not more than 10 g.

A.2.2 Test

In the test of bulk weight, place the bulk weight meter on a stable test table. Thoroughly mix up the sample; block the lower mouth of the funnel. Pour the phosphorous slag sample into the funnel. Open the feed opening, so that phosphorous slag can naturally fall into the bulk weight cylinder. After the cylinder is filled with phosphorous slag, use a steel ruler to scrape redundant phosphorous slag; weigh the mass of the bulk weight cylinder, which is filled with phosphorous slag. […]

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This preview omits tables, figures, formulas and parts of the technical clauses. The complete document — 15 pages — is available in the English PDF.

Referenced standards

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Editions of GB/T 6645

EditionTitleRevisionStatus
GB/T 6645-2008Granulated electric furnace phosphorous slag used for cementcurrent editionCurrent
GB/T 6645-1986Granulated electric furnace phosphorous slag used for cementprevious editionSuperseded

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