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GB/T 4702.2-2025Chromium metal - Determination of silicon content - Perchloric acid gravimetric method and molybdenum blue spectrophotometric method (English PDF)

金属铬 硅含量的测定 高氯酸脱水重量法和钼蓝分光光度法

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Issued by

SAMR; SAC

Level / Type

National · Recommended

Issue date

October 31, 2025

Implementation date

May 1, 2026

Scope

GB/T 4702.2-2025 is the English-translated version of 金属铬 硅含量的测定 高氯酸脱水重量法和钼蓝分光光度法.

GB/T 4702.2-2025 is the Chinese standard "Chromium metal - Determination of silicon content - Perchloric acid gravimetric method and molybdenum blue spectrophotometric method".

Its scope clause reads: This document specifies the methods for determining the silicon content in metallic chromium using the perchloric acid dehydration gravimetric method and the molybdenum blue spectrophotometric method.

This document applies to the determination of silicon content in metallic chromium. Determination range (mass fraction). 0.10%~2.00% by perchloric acid dehydration gravimetric method; Molybdenum blue spectrophotometry. 0.10%~0.70%. Its clauses include terms and definitions.

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Document preview — GB/T 4702.2-2025

National Standard of the People's Republic of China

ICS
77.100
Classification
H 11
Replacing
GB/T 4702.2-2008

Issued by: State Administration for Market Regulation; Standardization Administration of the PRC

Contents

  • 1 Scope
  • 2 Normative references
  • 3 Terms and Definitions
  • 4 Method

1 Scope

This document specifies the methods for determining the silicon content in metallic chromium using the perchloric acid dehydration gravimetric method and the molybdenum blue spectrophotometric method.

This document applies to the determination of silicon content in metallic chromium. Determination range (mass fraction). 0.10%~2.00% by perchloric acid dehydration gravimetric method;

Molybdenum blue spectrophotometry. 0.10%~0.70%.

2 Normative references

The contents of the following documents, through normative references within the text, constitute essential provisions of this document. Dated citations are not included.

For references to documents, only the version corresponding to that date applies to this document; for undated references, the latest version (including all amendments) applies.

This document.

GB/T 4010 Sample collection and preparation for chemical analysis of ferroalloys

GB/T 6379.1 Accuracy (correctness and precision) of measurement methods and results - Part 1.General principles and definitions

GB/T 6379.2 Accuracy (correctness and precision) of measurement methods and results - Part 2.Determining the repeatability of standard measurement methods

Basic methods of sex and representation

GB/T 6682 Specifications and test methods for water used in analytical laboratories

GB/T 8170 Rules for rounding off numerical values and the representation and determination of limiting values

GB/T 12806 Laboratory Glassware - Single-mark volumetric flasks

GB/T 12807 Graduated Pipettes for Laboratory Glassware

GB/T 12808 Laboratory Glassware - Single-mark Pipettes

3 Terms and Definitions

This document does not contain any terms or definitions that need to be defined.

4 Method 1.Perchloric acid dehydration by gravimetric method

4.1 Principle

The sample was decomposed with hydrochloric acid and then treated with perchloric acid until it emitted fumes, causing the silicon to form insoluble silicic acid. After filtration and ignition, the sample was weighed. It was then treated with hydrofluoric acid.

The silicon content is calculated by igniting the silicon dioxide after it has volatilized, weighing the resulting product, and then calculating the difference between the two weighings.

4.2 Reagents and Materials

Unless otherwise specified, only reagents confirmed to be of analytical grade shall be used in the analysis, and the water used in the tests shall be of grade III or higher as specified in GB/T 6682.

Distilled water of grade III or higher, deionized water, or water with equivalent purity. […]

......
This preview omits tables, figures, formulas and parts of the technical clauses. The complete document — 25 pages — is available in the English PDF.

Referenced standards

Editions of GB/T 4702.2

EditionTitleRevisionStatus
GB/T 4702.2-2025Chromium metal - Determination of silicon content - Perchloric acid gravimetric method and molybdenum blue spectrophotometric methodcurrent editionCurrent
GB/T 4702.2-2008Chromium metal -- Determination of silicon content -- The perchloric acid gravimetric methodprevious editionIn force
GB/T 4702.2-1984Methods for chemical analysis of chromium metal--The perchloric acid dehydration-gravimetric method for the determination of silicon contentprevious editionObsolete

This page sells the current edition, GB/T 4702.2-2025. Earlier editions are listed for reference only.

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