GB/T 4702.2-2025Chromium metal - Determination of silicon content - Perchloric acid gravimetric method and molybdenum blue spectrophotometric method (English PDF)
金属铬 硅含量的测定 高氯酸脱水重量法和钼蓝分光光度法
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Issued by
SAMR; SAC
Level / Type
National · Recommended
Issue date
October 31, 2025
Implementation date
May 1, 2026
Scope
GB/T 4702.2-2025 is the English-translated version of 金属铬 硅含量的测定 高氯酸脱水重量法和钼蓝分光光度法.
GB/T 4702.2-2025 is the Chinese standard "Chromium metal - Determination of silicon content - Perchloric acid gravimetric method and molybdenum blue spectrophotometric method".
Its scope clause reads: This document specifies the methods for determining the silicon content in metallic chromium using the perchloric acid dehydration gravimetric method and the molybdenum blue spectrophotometric method.
This document applies to the determination of silicon content in metallic chromium. Determination range (mass fraction). 0.10%~2.00% by perchloric acid dehydration gravimetric method; Molybdenum blue spectrophotometry. 0.10%~0.70%. Its clauses include terms and definitions.
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Document preview — GB/T 4702.2-2025
National Standard of the People's Republic of China
- ICS
- 77.100
- Classification
- H 11
- Replacing
- GB/T 4702.2-2008
Issued by: State Administration for Market Regulation; Standardization Administration of the PRC
Contents
- 1 Scope
- 2 Normative references
- 3 Terms and Definitions
- 4 Method
1 Scope
This document specifies the methods for determining the silicon content in metallic chromium using the perchloric acid dehydration gravimetric method and the molybdenum blue spectrophotometric method.
This document applies to the determination of silicon content in metallic chromium. Determination range (mass fraction). 0.10%~2.00% by perchloric acid dehydration gravimetric method;
Molybdenum blue spectrophotometry. 0.10%~0.70%.
2 Normative references
The contents of the following documents, through normative references within the text, constitute essential provisions of this document. Dated citations are not included.
For references to documents, only the version corresponding to that date applies to this document; for undated references, the latest version (including all amendments) applies.
This document.
GB/T 4010 Sample collection and preparation for chemical analysis of ferroalloys
GB/T 6379.1 Accuracy (correctness and precision) of measurement methods and results - Part 1.General principles and definitions
GB/T 6379.2 Accuracy (correctness and precision) of measurement methods and results - Part 2.Determining the repeatability of standard measurement methods
Basic methods of sex and representation
GB/T 6682 Specifications and test methods for water used in analytical laboratories
GB/T 8170 Rules for rounding off numerical values and the representation and determination of limiting values
GB/T 12806 Laboratory Glassware - Single-mark volumetric flasks
GB/T 12807 Graduated Pipettes for Laboratory Glassware
GB/T 12808 Laboratory Glassware - Single-mark Pipettes
3 Terms and Definitions
This document does not contain any terms or definitions that need to be defined.
4 Method 1.Perchloric acid dehydration by gravimetric method
4.1 Principle
The sample was decomposed with hydrochloric acid and then treated with perchloric acid until it emitted fumes, causing the silicon to form insoluble silicic acid. After filtration and ignition, the sample was weighed. It was then treated with hydrofluoric acid.
The silicon content is calculated by igniting the silicon dioxide after it has volatilized, weighing the resulting product, and then calculating the difference between the two weighings.
4.2 Reagents and Materials
Unless otherwise specified, only reagents confirmed to be of analytical grade shall be used in the analysis, and the water used in the tests shall be of grade III or higher as specified in GB/T 6682.
Distilled water of grade III or higher, deionized water, or water with equivalent purity. […]
......
This preview omits tables, figures, formulas and parts of the technical clauses. The complete document — 25 pages — is available in the English PDF.
Referenced standards
Normative references
- GB/T 4010Ferroalloys sampling and preparation of samples for chemical analysis
- GB/T 6379.1Accuracy (trueness and precision) of measurement methods and results -- Part 1: General principles and definitions
- GB/T 6379.2Accuracy (trueness and precision) of measurement methods and results - Part 2: Basic method for the determination of repeatability and reproducibility of a standard measurement method
- GB/T 6682Water for analytical laboratory use - Specification and test methods
- GB/T 8170Rules of rounding off for numerical values & expression and judgement of limiting values
- GB/T 12806Laboratory glassware -- One-mark volumetric flasks
Editions of GB/T 4702.2
| Edition | Title | Revision | Status |
|---|---|---|---|
| GB/T 4702.2-2025 | Chromium metal - Determination of silicon content - Perchloric acid gravimetric method and molybdenum blue spectrophotometric method | current edition | Current |
| GB/T 4702.2-2008 | Chromium metal -- Determination of silicon content -- The perchloric acid gravimetric method | previous edition | In force |
| GB/T 4702.2-1984 | Methods for chemical analysis of chromium metal--The perchloric acid dehydration-gravimetric method for the determination of silicon content | previous edition | Obsolete |
This page sells the current edition, GB/T 4702.2-2025. Earlier editions are listed for reference only.
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Related Standards
GB/T 12806-2011 — Laboratory glassware -- One-mark volumetric flasks
GB/T 12807-2021 — Laboratory glassware - Graduated pipettes
GB/T 12808-2015 — Laboratory glassware - One mark pipettes
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