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GB/T 36692-2018Cis-1,3,3,3-tetrafluoropropene[HFO-1234ze(Z)] for industrial use (English PDF)

工业用顺式-1,3,3,3-四氟丙烯[HFO-1234ze(Z)]

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Issued by

SAMR; SAC

Level / Type

National · Recommended

Issue date

September 17, 2018

Implementation date

January 1, 2019

Scope

GB/T 36692-2018 is the English-translated version of 工业用顺式-1,3,3,3-四氟丙烯[HFO-1234ze(Z)].

GB/T 36692-2018 is the Chinese product standard for industrial cis-1,3,3,3-tetrafluoropropene, HFO-1234ze(Z) or R1234ze(Z), with the structural formula CF3CH=CFH and a relative molecular mass of 114.04.

It covers the product made from tetrachloropropene, pentafluoropropane and similar raw materials reacted with anhydrous hydrogen fluoride over a catalyst, or by isomerization of trans-HFO-1234ze(E), and then purified.

It specifies the requirements, including a colourless transparent liquid free of visible solid particles, together with the test methods, inspection rules, marking, packaging, transport and storage.

The referenced methods include gas chromatography, sampling of gaseous chemical products, and the determination of non-condensable gases, chlorides, acidity, evaporation residue and moisture in fluoroolefins, plus the filling of liquefied gas cylinders. It was issued on 17 September 2018 and has applied since 1 January 2019.

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Document preview — GB/T 36692-2018

National Standard of the People's Republic of China

ICS
71.080.20
Classification
G 17

Issued by: State Administration for Market Regulation; Standardization Administration of the PRC

Contents

  • Foreword
  • 1 Scope
  • 2 Normative references
  • 3 Requirements

Foreword

This standard was drafted in accordance with the rules given in GB/T 1.1-2009.

1 Scope

This standard specifies the requirements for industrial cis-1,3,3,3-tetrafluoropropene [HFO-1234ze(Z), also referred to as. R1234ze(Z)], Test methods, inspection rules, marking, packaging, transportation and storage.

This standard applies to tetrachloropropene, pentafluoropropane, etc. as raw materials, reacted with anhydrous hydrogen fluoride under the action of a catalyst, or by trans-1,3, 3,3-tetrafluoropropene [HFO-1234ze(E)] isomerization reaction, purified cis-1,3,3,3-tetrafluoropropene [HFO-1234ze(Z)].

Simple structure. CF3CH=CFH

Relative molecular mass. 114.04 (according to 2016 international relative atomic mass)

2 Normative references

The following documents are indispensable for the application of this document. For dated references, only dated versions apply to this document. For undated references, the latest edition (including all amendments) applies to this document.

Preparation of GB/T 601 chemical reagent standard titration solution

Preparation of preparations and products used in GB/T 603 chemical reagent test method

GB/T 6681-2003 General rules for sampling of gas chemical products

GB/T 6682 Analytical laboratory water specifications and test methods

GB/T 8170 Numerical Rounding Rules and Representation and Determination of Limit Values

GB/T 9722 General Rules for Gas Chromatography of Chemical Reagents

GB/T 14193 liquefied gas cylinder filling regulations

GB/T 33063 General method for determination of fluoroolefin non-condensable gases (NCG) for refrigerants

GB/T 33064 General method for determination of fluoroolefin chlorides (Cl-) for refrigerants

GB/T 33065 General method for determination of acidity of fluoroolefins for refrigerants

GB/T 33066 General method for the determination of fluoroolefin evaporation residues

GB/T 34237 General method for determination of moisture of fluoroolefins for refrigerants

3 Requirements

3.1 Appearance. colorless transparent liquid, no visible solid particles.

3.2 Industrial cis-1,3,3,3-tetrafluoropropene shall comply with the requirements of Table 1. […]

......
This preview omits tables, figures, formulas and parts of the technical clauses. The complete document — 15 pages — is available in the English PDF.

Referenced standards

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