GB/T 35212.4-2023Analysis and evaluation methods of gas and solution and desulfurization decarbonization and sulfur recovery for natural gas treating plant—Part 4: Determination of sodium、magnesium、calcium in alkanol amine desulfurization by ion chromatography (English PDF)
天然气处理厂气体及溶液分析与脱硫、脱碳及硫磺回收分析评价方法 第4部分:用离子色谱法测定醇胺脱硫溶液中钠、镁、钙离子组成
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Issued by
SAMR; SAC
Level / Type
National · Recommended
Issue date
May 23, 2023
Implementation date
September 1, 2023
Scope
GB/T 35212.4-2023 is the English-translated version of 天然气处理厂气体及溶液分析与脱硫、脱碳及硫磺回收分析评价方法 第4部分:用离子色谱法测定醇胺脱硫溶液中钠、镁、钙离子组成.
GB/T 35212.4-2023 is Part 4 of GB/T 35212 and gives the ion chromatography method for measuring the sodium, magnesium and calcium ion content of the alkanolamine solution used in a natural gas treating plant.
It describes the principle of the method, the reagents and materials, the instruments and equipment, the test procedure, the treatment of the test data and the precision, and it defines the guard column and the separation column.
The measuring ranges are 0.1 mg/L to 10000 mg/L for the sodium ion and 0.3 mg/L to 10000 mg/L for the magnesium and calcium ions. An informative annex shows the chromatograms of a typical alkanolamine desulfurization solution.
It cites GB/T 6682 for the laboratory water, was issued on 23 May 2023 and has applied since 1 September 2023.
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Document preview — GB/T 35212.4-2023
National Standard of the People's Republic of China
- ICS
- 75.020
- Classification
- E 24
Issued by: State Administration for Market Regulation; Standardization Administration of the PRC
Contents
- Preface
- Introduction
- 1 Scope
- 2 Normative references
- 3 Terms and Definitions
- 4 Method principle
- 5 Reagents and Materials
- 6 Instruments and Equipment
- 7 Test Step
- 8 Experimental data processing
- 9 Precision
- Appendix A (informative) Chromatograms of sodium, magnesium and calcium ions in typical alcohol amine desulfurization solutions
Foreword
This document is in accordance with the provisions of GB/T 1.1-2020 "Guidelines for Standardization Work Part 1: Structure and Drafting Rules for Standardization Documents" drafting.
This document is GB/T 35212 "Analysis and evaluation methods for gas and solution in natural gas treatment plants, desulfurization, decarbonization and sulfur recovery" Part 4: GB/T 35212 has issued the following parts.
--- Part 1: Gas and solution analysis;
--- Part 2: Analysis of desulfurization and decarburization solvents;
---Part 3: Technical requirements and analysis and evaluation methods for sulfur recovery and tail gas treatment catalysts;
--- Part 4: Determination of sodium, magnesium and calcium ion composition in alcohol amine desulfurization solution by ion chromatography.
Introduction
During the production process of amine desulfurization and decarburization, solution pollution will be caused by various reasons. The metal cation sodium, magnesium, calcium ion in the desulfurization solution of p-alkanolamine The analysis of the subcomponents is to monitor the quality of the alcohol amine desulfurization solution and ensure the smooth operation of the amine desulfurization and decarburization production process. The content of these cations Quantity is one of the important indicators to judge the performance change of desulfurization solution.
GB/T 35212 "Analysis and Evaluation Methods of Gas and Solution in Natural Gas Treatment Plants and Desulfurization, Decarbonization and Sulfur Recovery" aims to standardize natural gas The technical standardization document proposed for gas purification production activities to ensure efficient production of natural gas is proposed to consist of 4 parts.
--- Part 1: Gas and solution analysis. The aim is to establish a general and operational analysis for natural gas processing plant gases and solutions evaluation method.
--- Part 2: Analysis of desulfurization and decarburization solvents. The objective is to establish operational analytical Evaluation methods, and the corresponding technical requirements.
--- Part 3: Sulfur recovery and tail gas treatment catalyst technical requirements and analysis and evaluation methods. intended for natural gas processing plants Sulfur recovery and tail gas treatment catalysts establish operable analysis and evaluation methods, and specify the corresponding technical requirements.
--- Part 4: Determination of sodium, magnesium and calcium ion composition in alcohol amine desulfurization solution by ion chromatography. intended for natural gas processing plants The determination of the metal cation content in the alcohol amine desulfurization solution establishes an operable analysis and evaluation method, and stipulates the corresponding technical technical requirements.
WARNING: This document does not address security issues related to its application. Before using this document, it is the user's responsibility to establish appropriate safety and Protective measures, and clarify its limited scope of use.
1 Scope
This document describes the principle of the test method, reagents and materials, instruments and Equipment, test procedures, test data processing and precision.
This document is applicable to the composition analysis of metal cations in alcohol amine desulfurization solution. The types and determination ranges of metal cations are shown in Table 1.
2 Normative references
The contents of the following documents constitute the essential provisions of this document through normative references in the text. Among them, dated references For documents, only the version corresponding to the date is applicable to this document; for undated reference documents, the latest version (including all amendments) is applicable to this document.
GB/T 6682 Analytical laboratory water specifications and test methods
3 Terms and Definitions
The following terms and definitions apply to this document.
3.1 Guard column
A chromatographic column that is placed before the separation column and is used to protect the separation column from contamination by impurities such as particles or irreversible retentates.
3.2 Separation column
According to the retention characteristics of the ions to be measured, the ion-exchange chromatographic column that separates the ions to be measured before detection.
......
This preview omits tables, figures, formulas and parts of the technical clauses. The complete document — 15 pages — is available in the English PDF.
Referenced standards
Normative references
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Related Standards
GB/T 6682-2008 — Water for analytical laboratory use - Specification and test methods
GB/T 35212.1-2017 — Analysis and evaluation methods of gas and solution and desulfurization decarbonization and sulfur recovery for natural gas treating plant—Part 1: Gas and solution analysis
GB/T 35212.2-2017 — Analysis and evaluation methods of gas and solution and desulfurization decarbonization and sulfur recovery for natural gas treating plant—Part 2: Analysis of alkanolamine desulfurization decarbonization solvent
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