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GB/T 34694-2017Plastic—Determination of residual chloride content of chlorinated poly (vinyl chloride)resins—Potentiometric titration method (English PDF)

塑料 氯化聚氯乙烯树脂中残余氯含量的测定 电位滴定法

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Issued by

SAMR; SAC

Level / Type

National · Recommended

Issue date

November 1, 2017

Implementation date

May 1, 2018

Scope

GB/T 34694-2017 is the English-translated version of 塑料 氯化聚氯乙烯树脂中残余氯含量的测定 电位滴定法.

GB/T 34694-2017 is the Chinese standard "Plastic—Determination of residual chloride content of chlorinated poly (vinyl chloride)resins—Potentiometric titration method".

Its scope clause reads: This standard specifies the method of determination of residual chlorine content in chlorinated polyvinyl chloride resin. This standard applies to chlorinated polyvinyl chloride resin. Its clauses include terms and definitions; principle; reagent; equipment.

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Document preview — GB/T 34694-2017

National Standard of the People's Republic of China

ICS
83.080.20
Classification
G 32

Issued by: State Administration for Market Regulation; Standardization Administration of the PRC

Contents

  • 1 Scope
  • 2 Normative references
  • 3 Terms and definitions
  • 4 principle
  • 5 reagent
  • 6 equipment

1 Scope

This standard specifies the method of determination of residual chlorine content in chlorinated polyvinyl chloride resin.

This standard applies to chlorinated polyvinyl chloride resin.

2 Normative references

The following documents for the application of this document is essential. For dated references, only the dated version applies to this article

Pieces. For undated references, the latest edition (including all amendments) applies to this document.

GB/T 6682 analytical laboratory water specifications and test methods

GB/T 9725-2007 Chemical reagent potentiometric titration method

3 Terms and definitions

The following terms and definitions apply to this document.

3.1 Residual chlorine

Chloride (Cl-) and/or non-chlorinated free chlorine (Cl2) present in the chlorinated polyvinyl chloride resin.

4 principle

The sample is dissolved in an appropriate solvent, the prescribed electrode immersed in the same sample solution was measured, the titration process, the reference electrode potential

Remain constant, indicating the potential of the electrode changes with the concentration of the tested substance. Before and after the stoichiometry, the concentration of the measured substance in the solution

Changes will lead to dramatic changes in the electrode potential, electrode jump point indicates the end point of the titration.

5 reagent

5.1

General Provisions The reagents and water used in this method, when not specified otherwise, refer to analytical reagents or above and GB/T 6682

The provisions of the three water or rather pure water.

5.2

Hydrogen peroxide.

5.3 hydrochloric acid - dimethylacetamide solution

0.0005mol/L.

Pipette 5mL0.1mol/L hydrochloric acid solution into 1000mL volumetric flask, diluted with dimethyl acetamide to the mark, shake.

5.4

silver nitrate - dimethylacetamide standard titration solution. C = 0.02mol/L. According to Appendix A calibration. Solution stored in brown bottle in. Valid for 1 month.

6 equipment

6.1

General laboratory equipment.

......
This preview omits tables, figures, formulas and parts of the technical clauses. The complete document — 15 pages — is available in the English PDF.

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