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GB/T 33822-2025Nano lithium iron phosphate (English PDF)

纳米磷酸铁锂

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Issued by

SAMR; SAC

Level / Type

National · Recommended

Issue date

June 30, 2025

Implementation date

January 1, 2026

Scope

GB/T 33822-2025 is the English-translated version of 纳米磷酸铁锂.

GB/T 33822-2025 is the Chinese national standard covering the cathode powder that goes into an LFP cell — the chemical composition and the impurity limits, the magnetic impurity content and the count of magnetizable particles, the particle size, the specific surface area, the apparent, tap and compacted density, the powder resistivity, the moisture and the pH, the iron ion dissolution rate, and the first discharge specific capacity, initial efficiency and cycle life at room and elevated temperature. Magnetic impurities are counted particle by particle as well as weighed, because one metal particle is enough to short a cell. It replaces GB/T 33822-2017, under the Chinese Academy of Sciences. In force from 1 January 2026. Issued on 30 June 2025, it has been in force since 1 January 2026, replacing GB/T 33822-2017.

Document preview — GB/T 33822-2025

National Standard of the People's Republic of China

ICS
71.060.50
Classification
G 12
Replacing
GB/T 33822-2017

Issued by: State Administration for Market Regulation; Standardization Administration of the PRC

Contents

  • Foreword3
  • 1 Scope6
  • 2 Normative References6
  • 3 Terms and Definitions7
  • 4 Technical Requirements8
  • 5 Test Methods11
  • 6 Inspection Rules14
  • 7 Packaging, Marking, Transportation and Storage16
  • 8 Order Form Contents17
  • Appendix B (normative) Number of Magnetizable Metal Impurity Particles22
  • Appendix C (normative) pH24
  • Appendix D (normative) Iron Ion Dissolution Rate25
  • Bibliography28

1 Scope

This document specifies the technical requirements, inspection rules, packaging, marking, transportation, storage, and order form contents for nano lithium iron phosphate, and describes the corresponding test methods.

This document applies to the manufacturing and inspection of nano lithium iron phosphate, a cathode material for lithium-ion batteries. Molecular formula. LiFePO4.

Relative molecular mass. 157.755 (based on the 2023 international relative atomic mass).

2 Normative References

GB/T 1479.1

GB/T 5162

GB/T 5314

GB/T 6388

GB/T 6682

GB/T 19077

GB/T 19587

GB/T 41232.6

GB/T 41232.8

GB/T 41704-2022

GB/T 42161

GB/T 42260

GB/T 44330

GB/T 45324

3 Terms and Definitions

The following terms and definitions are applicable to this document.

3.1 Magnetic impurities

Impurities in lithium-ion battery cathode materials that can be adsorbed by a magnetic rod with a magnetic induction intensity of not less than 0.5 T (5,000 Gauss).

NOTE. magnetic impurities are usually elemental or compound forms of iron, chromium, nickel and zinc.

[source. GB/T 41704-2022, 3.1, modified]

3.2 Apparent density

The bulk density of powder measured after it has been freely filled into a standard container under specified conditions.

NOTE. the mass per unit volume when the powder is loosely packed.

3.3 Tap density

The mass per unit volume of powder measured after it has been tapped in a container under specified conditions.

3.4 Compacted density

The ratio of the mass of powder sample after it has been compacted under a certain pressure to its occupied volume.

[source. GB/T 41232.2-2021, 3.1.2]

1) Joint Committee on Powder Diffraction Standards.

3.5 Powder resistivity

The ratio of the electric field intensity to the steady-state current density within the powder material.

NOTE. this refers to the volume resistivity per unit volume.

3.6 Specific capacity

The electrochemical capacity of a unit mass of active material under specified conditions for charging or discharging.

[source. GB/T 20252-2014, 3.1, modified]

3.7 Initial charge-discharge efficiency

The percentage of the initial discharge capacity to the charge capacity of an active material under specified conditions.

3.8 Cycle performance

After a certain number of charge-discharge cycles under specified conditions, the percentage of the discharge capacity to the initial discharge capacity of an active material.

4 Technical Requirements

4.1 Appearance

The product shall be gray-black powder with uniform color and no lumps.

4.2 Chemical Composition

4.2.1 The chemical composition of the product shall conform to the provisions of Table 1.

4.6.3 Room-temperature cycle performance

At 25 C  2 C, the full battery shall undergo 1,000 charge-discharge cycles at 1 C. The discharge capacity of the 1,000th cycle shall not be less than 90% of the initial discharge capacity.

NOTE. the initial discharge capacity is generally the discharge capacity after the 2nd or 3rd charge- discharge cycle or determined through negotiation between the supply-side and the demand-side.

4.6.4 High-temperature cycle performance

At 45 C  2 C, the full battery shall undergo 600 charge-discharge cycles at 1 C. The discharge capacity of the 600th cycle shall not be less than 90% of the initial discharge capacity.

5 Test Methods

5.1 Appearance

The product appearance shall be visually inspected.

5.2 Chemical Composition

5.2.1 The determination of iron content shall be carried out in accordance with Appendix A or the method determined through negotiation between the supply-side and the demand-side.

5.2.2 The determination of phosphorus content shall be carried out in accordance with Appendix A or the method determined through negotiation between the supply-side and the demand-side.

5.2.3 The determination of lithium content shall be carried out in accordance with the provisions of Appendix A.

5.2.4 The determination of impurity content shall be carried out in accordance with the provisions of Appendix A.

5.2.5 The determination of carbon content shall be carried out in accordance with the provisions of GB/T 41232.6.

5.2.6 The determination of moisture content shall be carried out in accordance with the provisions of GB/T 41232.8.

5.2.7 The determination of magnetic impurity content shall be carried out in accordance with the provisions of 4.1 in GB/T 41704-2022 or the method determined through negotiation between the supply-side and the demand-side. The determination of the number of magnetizable metal impurity particles shall be carried out in accordance with the provisions of

Appendix B Appendix B

5.3 Physical Properties

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This preview omits tables, figures, formulas and parts of the technical clauses. The complete document — 20 pages — is available in the English PDF.

Referenced standards

Editions of GB/T 33822

EditionTitleRevisionStatus
GB/T 33822-2025Nano lithium iron phosphatecurrent editionCurrent
GB/T 33822-2017Nano lithium iron phosphateprevious editionIn force

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