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GB/T 26300-2020Nickel cobalt manganese composite hydroxide (English PDF)

镍钴锰三元素复合氢氧化物

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Issued by

SAMR; SAC

Level / Type

National · Recommended

Issue date

September 29, 2020

Implementation date

August 1, 2021

Scope

GB/T 26300-2020 is the English-translated version of 镍钴锰三元素复合氢氧化物.

GB/T 26300-2020 is the Chinese standard for nickel cobalt manganese composite hydroxide. It gives the classification, the technical requirements, the test methods, the inspection rules, the provisions on packaging, marking, transport, storage and quality certificate, and the content of the purchase order or contract.

It applies to nickel cobalt manganese composite hydroxide with the chemical formula NixCoyMn1-x-y(OH)2, where x+y < 1, x > 0 and y > 0. Precursor makers, cathode material producers and battery makers use it.

Issued on 29 September 2020, it has applied since 1 August 2021, replacing GB/T 26300-2010.

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Document preview — GB/T 26300-2020

National Standard of the People's Republic of China

ICS
77.150.40
Classification
H 71
Replacing
GB/T 26300-2010

Issued by: State Administration for Market Regulation; Standardization Administration of the PRC

Contents

  • Foreword3
  • 1 Scope5
  • 2 Normative references5
  • 3 Classification6
  • 4 Technical requirements7
  • 5 Test methods8
  • 6 Inspection rules9
  • 7 Packaging, marking, transport, storage and quality certificate10
  • 8 Order form (or contract)12
  • Annex A (normative) Calculation method of quantity fraction of nickel, cobalt and manganese species13

1 Scope

This Standard specifies classification, technical requirements, test methods, inspection rules, packaging, marking, transportation, storage, quality certificate and purchase order (or contract) for nickel cobalt manganese composite hydroxide.

This Standard is applicable to nickel cobalt manganese composite hydroxide. Its chemical formula is NixCoyMn1-x-y(OH)2 (where x+y< 1, x>0 and y>0).

2 Normative references

The following referenced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies.

GB/T 1479.1, Metallic powders - Determination of apparent density - Part 1: Funnel method

GB/T 5162, Metallic powders - Determination of tap density

GB/T 5314, Powders for powder metallurgical purposes - Sampling

GB/T 8170, Rules of rounding off for numerical values & expression and judgement of limiting values

GB/T 19077, Particle size analysis - Laser diffraction methods

GB/T 19587, Determination of the specific surface area of solids by gas adsorption using the BET method

3 Classification

3.1 Designation

The designation of the product consists of the capital letters NCMH followed by 6 digits.

The naming rules of product designation are shown in Figure 1. If the mass fraction of the substance is a single digit, add 0 before the single digit.

3.2 Code

The product code is divided into two types. 3-digit and 4-digit.

When the amount of nickel, cobalt, and manganese in the product is an integer multiple of ten, use 3-digit code. The 3-digit numbers are the values obtained by dividing the amount fraction of nickel, cobalt, and manganese by ten. The product with the chemical formula Ni1/3Co1/3Mn1/3(OH)2 is a special case.

4 Technical requirements

4.1 Chemical composition

4.1.1 Nickel, cobalt, manganese content

The contents of nickel, cobalt and manganese are calculated in two ways. the combined amount of nickel, cobalt and manganese and the amount fraction of nickel, cobalt and manganese substances.

4.1.2 Impurity content

The impurity content of the product shall meet the requirements in Table 2.

4.2 Physical properties

4.2.1 The bulk density of the product shall not be less than 0.50g/cm³.

4.2.2 The tap density of the product shall not be less than 1.10g/cm³.

4.2.3 Laser particle size (D50) of the product. 2.00µm ~21.00µm. The particle size distribution is negotiated by both supplier and buyer.

4.3 Magnetic foreign matter

The magnetic foreign matter content of the product shall not exceed 0.0000100%.

4.4 Moisture content

The moisture content of the product shall not exceed 1.0%.

4.5 Appearance quality

4.6 Other

If the buyer has special requirements for the product, it can be negotiated by both the supplier and the buyer.

5 Test methods

5.1 Chemical composition

5.2 Physical properties

5.2.1 The measurement of bulk density shall be carried out in accordance with the provisions of GB/T 1479.1.

5.2.2 The tap density is measured in accordance with the provisions of GB/T 5162.

5.2.3 The laser particle size (D50) is measured in accordance with the provisions of GB/T 19077.

5.3 Magnetic foreign matter

The determination of the content of magnetic foreign matter in the product is carried out according to the provisions of Annex K in GB/T 24533-2019.

5.4 Moisture content

The determination method of product moisture content shall be negotiated by both the supplier and the buyer.

6 Inspection rules

6.1 Inspection and acceptance

6.2 Batching

Products shall be submitted for inspection in batches. Each batch shall be composed of nickel cobalt manganese composite hydroxide of the same production cycle, the same designation, and the same specification. The weight of a single batch is not more than 10t.

6.3 Inspection items

Each batch of products shall be inspected for chemical composition, physical properties, moisture content, magnetic foreign matter and appearance quality.

6.4 Sampling and sample preparation

6.5 Judgment of test results

6.5.1 According to the rounding value comparison method stipulated in GB/T 8170, it is judged whether the inspection result conforms to this Standard.

7 Packaging, marking, transport, storage and quality certificate

7.1 Packaging

7.2 Marking

The outer packaging of the product shall be printed with trademarks and labels, which indicate. […]

7.3 Transportation and storage

Products shall be stacked in a ventilated and dry place. During transportation and storage, the packaging shall be prevented from cracking and moisture agglomeration.

The product has a shelf life of 1 year from the date of production.

7.4 Quality certificate

Each batch of products shall be accompanied by a quality certificate, indicating. […]

8 Order form (or contract)

The order form (or contract) for ordering the products listed in this Standard shall contain the following. […]

Annex A (normative) Calculation method of quantity fraction of nickel, cobalt and manganese species

A.1 Calculation method

A.1.3 The amount of manganese in nickel cobalt manganese composite hydroxide is calculated by xMn. Values are expressed in percent (%). Calculate according to formula (A.3). […]

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This preview omits tables, figures, formulas and parts of the technical clauses. The complete document — 15 pages — is available in the English PDF.

Referenced standards

Similar standards

Editions of GB/T 26300

EditionTitleRevisionStatus
GB/T 26300-2020Nickel cobalt manganese composite hydroxidecurrent editionCurrent
GB/T 26300-2010Nickel cobalt manganese composite hydroxideprevious editionSuperseded

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