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GB/T 24526-2009Carbon materials-determination of the total sulphur content (English PDF)

炭素材料全硫含量测定方法

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Issued by

SAMR; SAC

Level / Type

National · Recommended

Issue date

October 30, 2009

Implementation date

May 1, 2010

Scope

GB/T 24526-2009 is the English-translated version of 炭素材料全硫含量测定方法.

GB/T 24526-2009 is the Chinese standard "Carbon materials-determination of the total sulphur content".

Its scope clause reads: This standard specifies the principle of the method Carbon materials total sulfur content of Ai Shika law and Coulomb's law, reagents and materials, equipment, test step Suddenly, the results of calculation and precision, etc., in the arbitration analysis should be used Eschka law.

This standard applies to carbon materials graphite electrodes, graphite scrap, carbon block, graphite anodes, carbon electrode paste type, carbon-based electricity, calcined anthracite, calcined after Petroleum coke - Determination of total sulfur content. Its clauses include ai shika law.

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Document preview — GB/T 24526-2009

National Standard of the People's Republic of China

ICS
29.050
Classification
Q 52

Issued by: State Administration for Market Regulation; Standardization Administration of the PRC

Contents

  • 1 Scope
  • 2 Normative references
  • 3 Ai Shika law
  • 3.1 Principle
  • 3.2 Reagents and materials

1 Scope

This standard specifies the principle of the method Carbon materials total sulfur content of Ai Shika law and Coulomb's law, reagents and materials, equipment, test step

Suddenly, the results of calculation and precision, etc., in the arbitration analysis should be used Eschka law.

This standard applies to carbon materials graphite electrodes, graphite scrap, carbon block, graphite anodes, carbon electrode paste type, carbon-based electricity, calcined anthracite, calcined after

Petroleum coke - Determination of total sulfur content.

2 Normative references

The following documents contain provisions which, through reference in this standard and become the standard terms. For dated references, subsequent

Amendments (not including errata content) or revisions do not apply to this standard, however, encourage the parties to the agreement are based on research

Whether the latest versions of these documents. For undated reference documents, the latest versions apply to this standard.

Determination of total sulfur in GB/T 214 coal

Preparation of GB/T 601 chemical reagent standard titration solution

GB/T 639 chemical reagent anhydrous sodium carbonate

GB/T 649 chemical reagent potassium bromide

GB/T 676 chemical reagent acetic acid (glacial acetic acid)

GB/T 1272 chemical reagents potassium iodide

GB/T 1427 carbon material sampling method

GB/T 1914 chemical analysis filter paper

GB/T 1997 Coke samples and preparation

GB/T 8170 repair value expressed about the rules and limit values and judgment

Determination of GB/T 24527 Carbon materials inherent moisture

3 Ai Shika law

3.1 Principle

Mixing the sample with carbon materials aldrin, burning at a certain temperature, the sample is oxidized to sulfur dioxide and sulfur trioxide,

Oxides of sulfur and sodium carbonate and sulfate regenerated magnesium oxide effect, then added barium chloride solution and generated its barium sulfate precipitation, according to

The quality of barium sulfate in the calculation of carbon materials total sulfur content. The main reaction is as follows.

Sample

O2

-> +++

CO2 -> + H2O + SO2 -> + SO3 ->

3Na2CO3 + 2SO2 + SO3 + O2 (air) -> +++

3Na2SO4 + 3CO2 ->

3MgO + 2SO2 + SO3 + O2 (air -> +++) 3MgSO4

MgSO4 + Na2SO4 + 2BaCl -> +++2 2BaSO4 -> + 2NaCl + MgCl2

3.2 Reagents and materials

3.2.1 Ai Shika reagent

Ai Shika agent (hereinafter referred to as aldrin), weighed 2 parts by mass of chemically pure light magnesium oxide, and 1 part by mass of chemically pure anhydrous carbonate

Sodium (GB/T 639) were mixed and finely ground to a particle size after less than 0.2mm, stored in a sample bottle with a ground port.

3.2.2 hydrochloric acid solution

(1 + 1), a volume of water added to 1 volume of hydrochloric acid (analytical grade) and mix.

3.2.3 barium chloride solution

100g/L, 10g of barium chloride (analytical grade) were dissolved in 100mL water.

GB/T 24203-2024 | GB/T 24528-2009 | GB/T 24527-2009 | […]

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This preview omits tables, figures, formulas and parts of the technical clauses. The complete document — 15 pages — is available in the English PDF.

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