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GB/T 24200-2009Determination of phenol and homologues contents of crude phenol (English PDF)

粗酚中酚及同系物含量的测定方法

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Issued by

SAMR; SAC

Level / Type

National · Recommended

Issue date

July 8, 2009

Implementation date

April 1, 2010

Scope

GB/T 24200-2009 is the English-translated version of 粗酚中酚及同系物含量的测定方法.

GB/T 24200-2009 is the Chinese standard "Determination of phenol and homologues contents of crude phenol". Its scope clause reads: This standard specifies the principles of the crude phenol and phenol homologues content determination, reagents and instruments, test procedures, the results of the calculation precision.

This standard applies to the determination of high temperature coal tar fractionation resulting crude phenol and its homologues of phenol content. Its clauses include test principle; reagents and instruments.

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Document preview — GB/T 24200-2009

National Standard of the People's Republic of China

ICS
71.080.90
Classification
G 17

Issued by: State Administration for Market Regulation; Standardization Administration of the PRC

Contents

  • 1 Scope
  • 2 Normative references
  • 3 Test principle
  • 4 Reagents and Instruments

1 Scope

This standard specifies the principles of the crude phenol and phenol homologues content determination, reagents and instruments, test procedures, the results of the calculation precision.

This standard applies to the determination of high temperature coal tar fractionation resulting crude phenol and its homologues of phenol content.

2 Normative references

The following documents contain provisions which, through reference in this standard and become the standard terms. For cited documents with dates, with its

After all of the amendments (not including errata content) or revisions do not apply to this standard, however, encourage each agreement in accordance with this standard

Are Prescriptions can use the latest versions of these documents. For undated reference documents, the latest versions apply to this standard.

GB/T 8170 repair value expressed about the rules and limit values and judgment

YB/T 2305 coking products Glass thermometers

3 Test principle

Take a certain amount of sample, kerosene - xylene mixture as a substrate solution, distilled, evaporated after all distillate with a base effect generated sodium phenol,

Lye ml increments multiplied by its average density, in terms of the mass fraction of phenol and homologs. The reaction is as follows.

C6H5OH + NaOH -> C6H5ONa + H2O

4 Reagents and Instruments

4.1 Kerosene - xylene

5 parts of xylene was mixed with 3 parts kerosene (kerosene must first washed 30% sulfuric acid, according to the proportion of 1.1, after separation

10% sodium hydroxide and, according to the proportion of 1.1, after separation by distillation cut 200 °C ~ 300 °C distillate).

4.2 Toluene

AR.

4.3 Sodium chloride

AR, 400 °C burning dehydration 1h.

4.4 Sodium hydroxide solution

10% (mass fraction) solution, saturated with sodium chloride, the use of filtration.

4.5 retort

copper volume 150mL, wall thickness of not more than 2mm, shown in Figure 1.

Note. Allow the use of benzene retorts.

Millimeters

Figure 1 retort

GB/T 22053-2020 | GB/T 26026-2010 | GB/T 24768-2009 | GB/T 47270-2026 | GB/T 27563-2026 | GB/T 10668-2026 | […]

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This preview omits tables, figures, formulas and parts of the technical clauses. The complete document — 15 pages — is available in the English PDF.

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