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GB/T 23818-2009Determination of imidazolinone herbicide residues in soybean (English PDF)

大豆中咪唑啉酮类除草剂残留量的测定

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Issued by

SAMR; SAC

Level / Type

National · Recommended

Issue date

May 25, 2009

Implementation date

September 1, 2009

Scope

GB/T 23818-2009 is the English-translated version of 大豆中咪唑啉酮类除草剂残留量的测定.

GB/T 23818-2009 is the Chinese standard "Determination of imidazolinone herbicide residues in soybean".

Its scope clause reads: This standard specifies the soybean seeds imazapyr, imazethapyr methyl, imazethapyr methyl, imazethapyr, imazaquin residues in high Performance liquid chromatography and liquid chromatography - mass spectrometry/mass spectrometry.

This standard applies to soybean seeds imazapyr, imazethapyr methyl, imazethapyr methyl, imazethapyr, imazaquin residues Determination. Its clauses include reagents and materials.

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Document preview — GB/T 23818-2009

National Standard of the People's Republic of China

ICS
67.060
Classification
X 04

Issued by: State Administration for Market Regulation; Standardization Administration of the PRC

Contents

  • 1 Scope
  • 2 Normative references
  • 4 Reagents and materials
  • 4.1 acetonitrile
  • 4.2 hexane
  • 4.5 filter
  • 4.6 Standards
  • 4.7 standard stock solution
  • 5.1 High performance liquid chromatograph
  • 5.2 Liquid chromatography - mass spectrometry/mass
  • 5.4 Sample sieve
  • 5.5 Analysis of balance

1 Scope

This standard specifies the soybean seeds imazapyr, imazethapyr methyl, imazethapyr methyl, imazethapyr, imazaquin residues in high

Performance liquid chromatography and liquid chromatography - mass spectrometry/mass spectrometry.

This standard applies to soybean seeds imazapyr, imazethapyr methyl, imazethapyr methyl, imazethapyr, imazaquin residues

Determination.

2 Normative references

The following documents contain provisions which, through reference in this standard and become the standard terms. For dated references, subsequent

Amendments (not including errata content) or revisions do not apply to this standard, however, encourage the parties to the agreement are based on research

Whether the latest versions of these documents. For undated reference documents, the latest versions apply to this standard.

GB/T 6682 analytical laboratory use specifications and test methods (GB/T 6682-2008, ISO 3696. 1987, MOD)

Principle 3

The sample was extracted with dichloromethane, gel permeation chromatography and liquid-liquid distribution method purified by high performance liquid chromatography and liquid chromatography - mass spectrometry/mass spectrometry

Determination, external standard.

4 Reagents and materials

Unless otherwise noted, all reagents were of analytical grade water as a water GB/T 6682 regulations.

4.1 acetonitrile

chromatography.

4.2 hexane

chromatographically pure.

4.3

dichloromethane.

4.4

phosphoric acid.

4.5 filter

0.22µm, organic phase.

4.6 Standards

4.6.1

imazapyr (imazapyr, CASNo.81334-34-1). purity greater than or equal to 99%.

4.6.2

imazapic (imazapic, CASNo.104098-48-8). purity greater than or equal to 99%.

4.6.3

imazethapyr acid methyl ester (imazamethabenz-methyl, CASNo.81405-85-8). not less than 99.5% purity.

4.6.4

imazethapyr (imazethapyr, CASNo.81335-77-5). purity greater than or equal to 99%.

4.6.5

imazaquin (imazaquin, CASNo.81335-37-7). not less than 99.5% purity.

4.7 standard stock solution

accurately weighed separately each standard 10mg (accurate to 0.1mg), dissolved in acetonitrile and set the volume to 100mL,

Preparation of a concentration of 100µg/mL standard stock solution of each standard stock solution at 0 °C ~ 4 °C stored.

5. Apparatus

5.1 High performance liquid chromatograph

equipped with a UV detector.

5.2 Liquid chromatography - mass spectrometry/mass

with an electrospray ionization source.

5.3

mill.

5.4 Sample sieve

mesh size 0.425mm.

5.5 Analysis of balance

a sense of 0.1mg and 1mg.

GB/T 23504-2009 | GB/T 22507-2008 | GB/T 22509-2008 | GB/T 23816-2009 | GB/T 23815-2009 | GB/T 23814-2009 | […]

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This preview omits tables, figures, formulas and parts of the technical clauses. The complete document — 15 pages — is available in the English PDF.

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