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GB/T 16451-2017Natural fatty alcohols (English PDF)

天然脂肪醇

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Issued by

General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China; Standardization Administration of China

Level / Type

National · Recommended

Issue date

December 29, 2017

Implementation date

July 1, 2018

Scope

GB/T 16451-2017 is the English-translated version of 天然脂肪醇.

GB/T 16451-2017 is the Chinese national standard on natural fatty alcohols, in the field of chemical technology. The /T suffix marks it as a recommended standard: it is not compulsory by itself, but it becomes binding as soon as a contract, a tender or a customer specification calls it up - which in practice is how most foreign buyers meet it. It was issued on 29 December 2017 by the General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China; Standardization Administration of China, and has been in force since 1 July 2018. Classification: ICS 71.080.60, CCS G17. This page is published from the official record of the standard held by the Chinese standards administration: the identification, the dates, the classification and the issuing body are taken from there. The clause text, the tables and the numeric limits are in the document itself, which is delivered complete in English translation.

Document preview — GB/T 16451-2017

National Standard of the People's Republic of China

ICS
71.080.60
Classification
G17

Issued by: General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China; Standardization Administration of China

Contents

  • 1 Scope
  • 2 Normative references
  • 3 Product classification
  • 4 Requirements
  • 5 Test methods
  • 5.4 Color
  • 5.6.3 Test procedures Weigh 10 g of specimen (accurate to
  • 5.7.3 Test procedures Accurately weigh 5 g of specimen (accurate to
  • 6 Inspection rules
  • 6.1 Inspection classification
  • 6.2 Batching and sampling rules
  • 7 Marks, packaging, transportation, storage

1 Scope

GB/T 16451-2017 is the Chinese national standard on natural fatty alcohols, in the field of chemical technology. The /T suffix marks it as a recommended standard: it is not compulsory by itself, but it becomes binding as soon as a contract, a tender or a customer specification calls it up - which in practice is how most foreign buyers meet it. It was issued on 29 December 2017 by the General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China; Standardization Administration of China, and has been in force since 1 July 2018. Classification: ICS 71.080.60, CCS G17. This page is published from the official record of the standard held by the Chinese standards administration: the identification, the dates, the classification and the issuing body are taken from there. The clause text, the tables and the numeric limits are in the document itself, which is delivered complete in English translation.

This Standard specifies the product classification, requirements, test methods, inspection rules and marks, packaging, transportation and storage for natural fatty alcohols. This Standard is applicable to a series of fatty primary alcohol products obtained from natural vegetable oils and their derivatives through alcoholysis or hydrolysis, esterification, hydrogenation and distillation.

2 Normative references

The following referenced documents are indispensable for the application of this document. For dated references, only the edition cited applies. For undated references, the latest edition of the referenced document (including any amendments) applies.

GB/T 617, Chemical reagent -- General method for the determination of melting range

GB/T 6682, Water for analytical laboratory use -- Specification and test methods

GB/T 7383-2007, Non-ionic surface active agents -- Determination of hydroxyl value

GB/T 9282.1, Clear liquids -- Estimation of colour by the platinum-cobalt scale -- Part

3 Product classification

Natural fatty alcohols are divided into ten categories according to the carbon chain length. C8~10 alcohols, C12~14 alcohols, C14~16 alcohols, C16~18 alcohols, C8 alcohols, C10 alcohols, C12 alcohols, C14 alcohols, C16 alcohols, and C18 alcohols.

4 Requirements

Natural fatty alcohols have an inherent characteristic odor. The physical and chemical indicators shall meet the requirements in Table

2.When used as cosmetic raw material, they shall also meet the requirements in Table 3.

5 Test methods

Unless otherwise stated, only reagents confirmed to be analytically pure and grade three water in accordance with GB/T6682 are used in the analysis.

5.1 Sample preparation After mixing the samples (solid samples shall be melted and mixed) before sampling test.

5.2 Appearance Put samples in beakers or glass jars. Visually inspect the color and state of the sample at 30°C.

5.4 Color

5.4.1 Specimen processing The solid fatty alcohol specimen needs to be heated to 75°C±5°C. After it is completely melted, immediately pour it into a pre-warmed colorimetric tube.

5.4.2 Determination According to the provisions of GB/T 9282.1.The resulting platinum-cobalt color units are expressed in Hazen.

5.5 Acid value NOTE. The number of milligrams of potassium hydroxide required to neutralize the acidity of 1 g of fatty alcohol specimen is called the acid value.

5.6 Saponification value NOTE. The number of milligrams of potassium hydroxide required to saponify 1 g of fatty alcohol specimen is called the saponification value of fatty alcohol.

5.6.1 Reagents Reagents include.

5.6.3 Test procedures Weigh 10 g of specimen (accurate to

0.001

g) and place it in the conical flask [5.6.2a)]. Use a pipette to transfer 25 mL of

0.1 mol/L potassium hydroxide-ethanol solution. Install the reflux condenser.

5.6.4 Calculation of results The saponification value X2 of fatty alcohol is calculated in KOH, expressed in milligrams per gram (mg/g), and calculated according to formula (2).

5.7 Iodine value NOTE. The number of grams of iodine absorbed per 100 g of fatty alcohol specimen is called iodine value.

5.7.1 Reagents Reagents include.

5.7.2 Instruments Commonly used laboratory instruments and the following.

5.7.3 Test procedures Accurately weigh 5 g of specimen (accurate to

0.001

g) in iodine bottle. Use a graduated cylinder to add 20 mL of carbon tetrac

5.7.4 Calculation of results Fatty alcohol iodine value X3, calculated as I2, expressed in grams per hectogram (g/100 g), is calculated according to formula (3).

5.7.5 Precision The absolute difference between two independent determination results obtained under repeatability conditions is not more than

0.2 g/100 g. The premise is that the case of greater than

0.2 g/100 g does not exceed 5%.

5.8 Hydroxyl value (chemical method) - arbitration method According to the provisions for the acetic anhydride method in GB/T 7383-2007.

5.9 Main component content, hydroxyl value and alkane content (chromatographic method)

6.1 Inspection classification

6.1.1 Type inspection Type inspection items include all items in Chapter

4.Type inspection shall be carried out in the following situations.

6.1.2 Exit-factory inspection The requirements in Table 2 in Chapter 4 are all exit-factory inspection items.

6.2 Batching and sampling rules

6.3 Judgment rules and re-inspection For the test results of physical and chemical indicators, use the rounding value comparison method to determine whether the products are accepted or rejected. If one item fails, twice as many samples can be taken again to reinspect the failed item.

6.4 Arbitration If both parties to the delivery still have disputes over the re-inspection results, they can request arbitration for inspection according to this Standard. The arbitration result shall be the final basis.

7 Marks, packaging, transportation, storage

7.1 Marks Each package of natural fatty alcohol and the accompanying quality certificate shall have the following marks.

7.2 Packaging Bulk fatty alcohol products are generally transported by tank truck or ISOTANK. Generally, fatty alcohol products are packaged in steel drums, composite plastic woven bags or cartons. The barrel mouth of the barreled product shall be sealed. The bagged or boxed product shall be well sealed.

7.3 Transportation Fatty alcohols shall be transported with coverings to avoid direct sunlight, rain and moisture. They shall be lightly loaded and unloaded. Avoid damage to the packaging.

......
This preview omits tables, figures, formulas and parts of the technical clauses. The complete document — 27 pages — is available in the English PDF.

Referenced standards

Similar standards

Editions of GB/T 16451

EditionTitleRevisionStatus
GB/T 16451-2017Natural fatty alcoholscurrent editionCurrent
GB/T 16451-2008Natural fatty alcoholsprevious editionSuperseded

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