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GB/T 1270-2023Chemical reagent—Cobalt(II) chloride hexahydrate (English PDF)

化学试剂 六水合氯化钴(氯化钴)

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Issued by

State Administration for Market Regulation; Standardization Administration of China

Level / Type

National · Recommended

Issue date

August 6, 2023

Implementation date

March 1, 2024

Scope

GB/T 1270-2023 is the English-translated version of 化学试剂 六水合氯化钴(氯化钴).

GB/T 1270-2023 — This Standard specifies technical requirements, test methods, inspection rules and packaging as well as marks for chemical reagent - cobalt (II) chloride hexahydrate.

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Document preview — GB/T 1270-2023

National Standard of the People's Republic of China

ICS
71.040.30
Classification
G62

Issued by: State Administration for Market Regulation; Standardization Administration of China

Contents

  • Foreword...3
  • 1 Scope...5
  • 2 Normative references...5
  • 3 Traits...6
  • 4 Specifications...6
  • 5 Tests...6
  • 6 Inspection rules...10
  • 7 Packaging and marks...10

Foreword

This standard gives two levels. analytically-pure and chemically-pure, of which

analytically-pure equivalently uses R 55 "cobalt chloride hexahydrate" in ISO

6353-3.1987 "Reagents for chemical analysis - Part 3.Specifications - Second

series". The differences are as follows.

1 Standard preparation

According to China's national conditions, this Standard adds three chapters.

traits, inspection rules, packaging and marks.

2 Specifications

2.1 Items

According to China's national conditions, this Standard adds nitrate,

manganese, iron, compared with ISO 6353-3.1987.

2.2 Indicators

Analytically-pure nickel and ammonium sulfide without precipitation are stricter

than ISO 6353-3.1987.Other items are the same as ISO 6353-3.1987.

3 Tests

The determination methods for content, sulfate, ammonium sulfide non-

precipitate in this Standard are basically the same as ISO 6353-3.1987.But

there are differences in determination conditions. Experiments show that there

is no significant difference in the results. Other items refer to the corresponding

standards in a set of general test method standards for chemical reagents that

China has developed. This set of standards is basically formulated using ISO

6353-1.1982 "Reagents for chemical analysis - Part 1.General test methods".

This Standard revised and replaced GB 1270-85 "Chemical reagent - Cobalt

chloride". Compared with GB 1270-85, it deleted the level of guaranteed. In

order to adopt the international standard, corresponding changes have been

made in specifications and test methods in this Standard.

This standard will replace GB 1270-85 from the effective date.

This Standard was drafted in accordance with the rules given in GB/T 1.1-2009.

This Standard was proposed by Ministry of Chemical Industry of the People's

Republic of China.

Chemical reagent - Cobalt (II) chloride hexahydrate

Molecular formula. CoCl2-6H2O

Relative molecular mass. 237.93

1 Scope

This Standard specifies technical requirements, test methods, inspection rules

and packaging as well as marks for chemical reagent - cobalt (II) chloride

hexahydrate.

2 Normative references

The following standards contain provisions which, through reference in this

Standard, constitute provisions of this Standard. At the time of publication, the

editions indicated are valid. All standards are subject to revision. The parties

who are using this Standard shall explore the possibility of using the latest

version of the following standards.

GB/T 601-88, Chemical reagent - Preparations of standard volumetric

solutions

GB/T 602-88, Chemical reagent - Preparations of stock standard solutions

GB/T 603-88, Chemical reagent - Preparations of reagent solutions for use

in test methods

GB/T 619-88, Chemical reagent - Regulations for sampling and acceptance

GB 6682-92, Water for analytical laboratory use - Specification and test

methods (eqv ISO 3696.1987)

GB/T 9723-88, Chemical reagent - General rules for flame atomic absorption

spectrometry

GB/T 9738-88, Chemical reagent - General method for the determination of

water insoluble matter (eqv ISO 6353-1.1982)

GB 15346-94, Chemical Reagent - Packaging and Marking

Where,

X - Mass percentage of cobalt chloride hexahydrate, %;

V - Volume of standard titration solution of disodium ethylenediaminetetraacetic

acid, mL;

c - Concentration of ethylenediaminetetraacetic acid disodium standard titration

solution, mol/L;

237.9 - Molar mass of cobalt chloride hexahydrate [M(CoCl2-6H2O)], g/mol;

m - Sample mass, g.

5.2 Water insoluble matter

Weigh 10g of sample. Dissolve in 100mLof boiling water. Cool to room

temperature. Determine according to GB/T 9738.

5.3 Sulfate

5.3.1 Preparation of sulfate-free cobalt chloride hexahydrate solution

Weigh 1g of sample. Dissolve in 20mLof water. Add 10mL of 95% ethanol, 2mL

of hydrochloric acid solution (10%). Under constant shaking, add 5mL of barium

chloride solution in drops (250g/L). Dilute to 50mL. Shake well. Place for

12h~18h. Filter it.

5.3.2 Determination method

Weigh 1g of sample. Dissolve in water. Dilute to 50mL.Take 10mL. Add 5mLof

95% ethanol, 1mL of hydrochloric acid solution (10%). Under constant shaking,

add 3mL of barium chloride solution (250g/L). Dilute to 25mL. Shake well. Place

for 10min. The turbidity of the solution shall not be greater than the standard

comparison solution.

Preparation of standard comparison solution. take 10mL of sulfate-free cobalt

chloride hexahydrate solution and sulfate standard solution that contains the

following quantity.

Analytically-pure

Chemically-pure

Light source. iron hollow cathode lamp;

Wavelength. 248.3nm;

Flame. acetylene-air.

5.6.2 Determination method

Weigh 25g of sample. Dissolve in water. Dilute to 100mL. Take 20mL, four

portions in total. Determine according to the provisions of 6.2.2 in GB/T 9723-

88.

5.7 Nickel

Determine according to the provisions of GB/T 9723, of which.

5.7.1 Instrument conditions

Light source. nickel hollow cathode lamp;

Wavelength. 232.0nm;

Flame. acetylene-air.

5.7.2 Determination method

Weigh 5g of sample. Dissolve in water. Dilute to 100mL. Take 10mL, four

portions in total. Determine according to the provisions of 6.2.2 in GB/T 9723-

88.

5.8 Copper

Determine according to the provisions of GB/T 9723-88.

5.8.1 Instrument conditions

Light source. copper hollow cathode lamp;

Wavelength. 324.8nm;

Flame. acetylene-air.

5.8.2 Determination method

Weigh 25g of sample (take 5g for chemically-pure). Dissolve in water. Dilute to

100mL. Take 20mL, four portions in total. Determine according to the provisions

of 6.2.2 in GB/T 9723-88.

5.9 Zinc

......

......
This preview omits tables, figures, formulas and parts of the technical clauses. The complete document — all pages — is available in the English PDF.

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