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GB 31604.2-2016Food safety national standard -- Food contact materials and products -- Determination of potassium permanganate consumption (English PDF)

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Issued by

National Health and Family Planning Commission of China

Level / Type

National · Mandatory

Issue date

August 31, 2016

Implementation date

March 1, 2017

Scope

GB 31604.2-2016 (Food safety national standard -- Food contact materials and products -- Determination of potassium permanganate consumption) is available as an English-translated PDF.

GB 31604.2-2016 — This Standard specifies the determination method of potassium permanganate consumption in food contact materials and products. This Standard is applicable to the determination of potassium permanganate consumption in food contact materials and products.

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Document preview — GB 31604.2-2016

National Standard of the People's Republic of China

Issued by: National Health and Family Planning Commission of China

Contents

  • Foreword...3
  • 1 Scope...4
  • 2 Principle...4
  • 3 Reagents and Materials...4
  • 4 Analytical Procedures...5
  • 5 Expression of Analytical Results...6
  • 6 Precision...7

Foreword

This Standard replaced the determination of potassium permanganate consumption

stipulated in the following standards, such as GB/T 5009.60-2003 Method for Analysis

of Hygienic Standard of Products of Polyethylene, Polystyrene and Polypropyrene for

Food Packaging, GB/T 5009.61-2003 Method for Analysis of Hygienic Standard of

Products of Tripolycyanamide for Food Packaging, GB/T 5009.64-2003 Method for

Analysis of Hygienic Standard of Rubber Sheet (Ring) for Food Use, GB/T 5009.65-

2003 Method for Analysis of Hygienic Standard of Rubber Sealing Ring for Pressure

Cooker for Food Use, GB/T 5009.66-2003 Method for Analysis of Hygienic Standard

of Nipple of a Feeding Bottle, GB/T 5009.67-2003 Method for Analysis of Hygienic

Standard of Product of Polyvinyl Chloride for Food Packaging, GB/T 5009.68-2003

Method for Analysis of Hygienic Standard of Perchlorovinyl-Coating for Inner Wall of

Food Container, GB/T 5009.69-2003 Method for Analysis of Hygienic Standard of

Epoxy Phenolic Coatings for Inner Wall of Food Cans, GB/T 5009.70-2003 Method for

Analysis of Hygienic Standard of Epoxy Coating For Inner Wall of Food Container,

GB/T 5009.79-2003 Hygienic Analytical Method of Rubber Hose for Food Use, GB/T

5009.80-2003 Method for Analysis of Hygienic Standard of Polytetrafluorethylene

Coating for Inner Wall of Food Cotainer, GB/T 5009.98-2003 Method for Analysis of

Hygienic Standard of Unsaturated Polyester Resin and Glass Fibre Reinforced

Products, GB/T 5009.99-2003 Method for Analysis of Hygienic Standard of

Polycarbonate Resin Used as Food Containers and Packaging, GB/T 5009.100-2003

Method for Analysis of Hygienic Standard of Products of Foamed Polystyrene for Food

Packaging.

Compared with GB/T 5009.60-2003, GB/T 5009.61-2003, GB/T 5009.64-2003, GB/T

5009.65-2003, GB/T 5009.66-2003, GB/T 5009.67-2003, GB/T 5009.68-2003, GB/T

5009.69-2003, GB/T 5009.70-2003, GB/T 5009.79-2003, GB/T 5009.80-2003, GB/T

5009.98-2003, GB/T 5009.99-2003, and GB/T 5009.100-2003, this Standard has the

major changes as follows.

--- Modified the standard name into "National Food Safety Standard on

Determination of Potassium Permanganate Consumption in Food Contact

Materials and Products";

--- Modified the standard scope;

--- Modified the calculation formula and unit.

National Food Safety Standard –

Food Contact Materials and Products –

Determination of potassium permanganate consumption

1 Scope

This Standard specifies the determination method of potassium permanganate

consumption in food contact materials and products.

This Standard is applicable to the determination of potassium permanganate

consumption in food contact materials and products.

2 Principle

Under acidic condition, use standard potassium permanganate solution to titrate the

sample soaking solution; calculate the potassium permanganate consumption in the

sample according to the volume of titration solution consumed by the sample.

3 Reagents and Materials

Unless otherwise is specified, all reagents used in this method shall be analytically

pure, while the water used shall be Class-II water stipulated in GB/T 6682.

3.1 Reagents

3.2 Preparation of reagents

3.2.1 Sulfuric acid solution (1+2). take 100mL of sulfuric acid, carefully add 200mL of

water, then mix evenly.

3.2.2 0.04% potassium permanganate solution. weigh 0.4g of potassium

permanganate, add water dissolved to 1000mL.

3.2.3 Standard oxalic acid solution. prepare, calibrate or

commercialize the products according to GB/T 601.

3.2.4 Standard oxalic acid titration solution. absorb

10.0mL of standard oxalic acid solution, place into the 100mL

volumetric flask, use water to make constant volume to the scale.

3.3 Standard substance

Standard potassium permanganate solution. prepare,

calibrate or commercialize products according to GB/T 601.

3.4 Preparation of standard solution

Standard potassium permanganate titration solution. absorb

10.0mL standard potassium permanganate solution, place

into 100mL volumetric flask, use water to make constant volume to the scale.

4 Analytical Procedures

4.1 Sampling method

Operate according to GB 5009.156.

4.2 Specimen cleaning

Operate according to GB 5009.156.

4.3 Selection of food simulation substance and simulation condition of

specimen

Operate according to corresponding product standard.

4.4 Pre-treatment method for migration test of specimen

Operate according to GB 5009.156.

4.5 Determination of specimen

4.5.2 Titration

Accurately absorb 100mL of water soaking solution (sampling amount can be adjusted

as per the actual situation), place into the 250mL conical flask treated as above; add

5mL of sulfuric acid (1+2) and 10.0mL of standard potassium permanganate titration

solution (0.01mol/L); then add 2 glass beads; after accurately boiling for 5min,

immediately add 10.0mL of standard oxalic acid titration solution (0.01mol/L);

5 Expression of Analytical Results

5.1 The potassium permanganate consumption in the specimen shall be calculated

as per Formula (1).

5.2 Calculation of the potassium permanganate consumption in the specimen as per

the actual use situation shall abide by Formula (2).

6 Precision

The absolute difference between the two independent determination results obtained

under the repeated conditions shall not exceed 20% arithmetic mean.

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This preview omits tables, figures, formulas and parts of the technical clauses. The complete document — 7 pages — is available in the English PDF.

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