SN/T 2835-2011Safety test method of import and export dangerous chemicals. Determination of the chemical oxygen demand (COD) (English PDF)
进出口危险化学品安全试验 化学降解需氧量(COD)测定
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Issued by
General Administration of Customs
Level / Type
National · Recommended
Issue date
February 25, 2011
Implementation date
July 1, 2011
Scope
SN/T 2835-2011 is the English-translated version of 进出口危险化学品安全试验 化学降解需氧量(COD)测定.
SN/T 2835-2011 — This standard specifies the determination of chemical oxygen demand by dichromate method (COD). This standard applies to COD at 30mg/L ~ 700mg/L of water, wherein the chloride content should not exceed 1000mg/L. One Meet these conditions can be directly used to analyze water samples.
If the COD value exceeds 700mg/L, then the sample should be diluted. Based on the maximum fine COD value indeed considering the sample should be 300mg/L ~ 600mg/L.
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Document preview — SN/T 2835-2011
National Standard of the People's Republic of China
- ICS
- 13.300
- Classification
- G 09
Issued by: General Administration of Customs
Contents
- Foreword
- Introduction
- 1 Scope
- 2 Normative references
- 3 Terms and Definitions
- 4 Main technical specifications
- 4.1 Principles
Foreword
This standard was drafted in accordance with GB/T 1.1-2009 rules.
This revised standard adopts ISO 6060. 1989 "Quality determination of chemical oxygen demand" (in English).
On a standard text format according to GB/T 1.1-2009 requirements of the editorial changes.
--- To introduce as part of the standard introduction;
--- 4 to 6 of the first part of the original scope of the standard as of this standard 4.1.4.
This standard is proposed and managed by the National Certification and Accreditation Administration Committee.
This standard drafting units. People's Republic of China Shandong CIQ.
Introduction
Determination of chemical oxygen demand (COD) by the dichromate method can be considered to be a suitable method for measuring the theoretical oxygen, for example, there are Sub-units into the final product inorganic oxygen consumption during total chemical oxidation (see 4.7). Level results close to the theoretical value depends mainly on the to improve the situation oxidation process. The degree of oxidation of organic compounds in a large number of 90% to 100%. For most of the water, the city e.g.
Wastewater, COD value is a realistic method of measuring the theoretical oxygen demand. For other containing large amounts of water under the experimental conditions difficult oxidizing substances it (see 4.7), COD value is a poor method of measuring the theoretical oxygen demand. Some industrial wastewater may be the case.
Therefore, the importance of the COD depends on the composition of the water study. When the result of the determination by the method described in this standard obtained, this it should be remembered.
Import and export of dangerous chemicals test Chemical degradation oxygen demand (COD) determination
1 Scope
This standard specifies the determination of chemical oxygen demand by dichromate method (COD).
This standard applies to COD at 30mg/L ~ 700mg/L of water, wherein the chloride content should not exceed 1000mg/L. One Meet these conditions can be directly used to analyze water samples. If the COD value exceeds 700mg/L, then the sample should be diluted. Based on the maximum fine COD value indeed considering the sample should be 300mg/L ~ 600mg/L.
2 Normative references
The following documents for the application of this document is essential. For dated references, only the dated version suitable for use herein Member. For undated references, the latest edition (including any amendments) applies to this document.
ISO 385 Laboratory glassware Burette Part 1. General requirements ISO 5790. 1979 Industrial Inorganic Chemicals general method used in the determination of chloride content of mercury droplets titration
3 Terms and Definitions
The following terms and definitions apply to this document.
COD chemicaloxygendemand; COD when the amount of a water sample with dichromate oxidizing agent under certain conditions, by the dissolved and suspended materials consumed dichromate the equivalent concentration of oxygen.
4 Main technical specifications
4.1 Principles
4.1.1 within a fixed period of time, quantitative substance dissolved or dispersed in water, this aqueous solution containing a known amount of potassium dichromate and Silver catalyst of concentrated sulfuric acid in the presence of reflux in mercury sulfide. During this time due to the presence of bichromate part of the oxidizable material and Save not enough. The remaining dichromate titration with ammonium ferric sulfate. COD value calculated by the reduction of dichromate.
4.1.2 1mol dichromate (Cr2O2-7) corresponds to 1.5mol oxygen (O2).
4.1.3 If the test portion contains more than 1000mg/L of chloride should be used to modify a step over 1).
1) For samples containing more than 1000mg/L chlorides, the step of modifying the study should be ISO/TC147/SC2 in. For the 30mg/L to Under low-grade COD, the steps are also being considered.
4.1.4 under the given reaction conditions, the organic component is widely peroxide. Containing specific structural elements (for example. pyridine nucleus, nitride Except compounds). Volatile hydrophobic substances may evaporate and thus avoid being oxidized. Inorganic under the reaction conditions to be oxidized Compounds such as.
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This preview omits tables, figures, formulas and parts of the technical clauses. The complete document — 7 pages — is available in the English PDF.
Referenced standards
Normative references
ISO 385 · ISO 5790
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