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NB/T 11531-2024Determination of total phosphorus, ammonia nitrogen and permanganate index in coal mine water - Flow injection spectrophotometry (English PDF)

煤矿水中总磷、氨氮、高锰酸盐指数含量的测定流动注射-分光光度法

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Issued by

NEA

Level / Type

Industry · Recommended

Issue date

May 24, 2024

Implementation date

November 24, 2024

Scope

NB/T 11531-2024 is the English-translated version of 煤矿水中总磷、氨氮、高锰酸盐指数含量的测定流动注射-分光光度法.

NB/T 11531-2024 is a Chinese energy industry test method for measuring total phosphorus, ammonia nitrogen and the permanganate index in coal mine water by flow injection spectrophotometry.

It explains how the flow injection analyzer works, injecting a sample into a flowing carrier liquid, reacting it with reagents in a chemical module and passing it through a flow cell for photometric detection, and then gives a separate procedure for each of the three parameters, followed by the test report and waste disposal.

With a 10 mm optical path, the method detection limits are 0.004 mg/L for total phosphorus as P, 0.02 mg/L for ammonia nitrogen as N and 0.20 mg/L for the permanganate index. Issued on 24 May 2024, it has applied since 24 November 2024.

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Document preview — NB/T 11531-2024

National Standard of the People's Republic of China

ICS
13.060.30
Classification
D 04

Issued by: National Energy Administration of the People's Republic of China

Contents

  • Preface
  • 1 Scope
  • 2 Normative references
  • 3 Terms and Definitions
  • 4 Working principle of flow injection analyzer
  • 5 Determination of total phosphorus
  • 6 Determination of ammonia nitrogen
  • 7 Determination of permanganate index
  • 8 Test Report
  • 9 Waste Disposal

Foreword

This document is in accordance with the provisions of GB/T 1.1-2020 "Guidelines for standardization work Part 1: Structure and drafting rules for standardization documents" Drafting.

1 Scope

This document describes the determination of total phosphorus, ammonia nitrogen and permanganate index in coal mine water using flow injection-spectrophotometry.

This document is applicable to the determination of total phosphorus, ammonia nitrogen and permanganate index in coal mine water.

When the detection optical path is 10 mm, the method detection limits and determination limits of total phosphorus, ammonia nitrogen and permanganate index of this method are shown in Table 1.

2 Normative references

The contents of the following documents constitute essential clauses of this document through normative references in this document.

For referenced documents without a date, only the version corresponding to that date applies to this document; for referenced documents without a date, the latest version (including all amendments) applies to this document.

GB/T 6682 Specifications and test methods for water used in analytical laboratories

3 Terms and definitions

There are no terms or definitions that require definition in this document.

4 Working principle of flow injection analyzer

In a closed pipeline, a certain volume of sample is injected into the continuously flowing carrier liquid, and the sample and reagents are reacted in the chemical reaction module according to specific The substances are mixed and reacted in a certain order and proportion, and under the condition of incomplete reaction, they enter the flow detection cell for photometric detection.

5 Determination of total phosphorus

5.1 Principle

Under acidic conditions, various forms of phosphorus in the sample were hydrolyzed at 125°C under high temperature and pressure, and then mixed with potassium persulfate solution for UV disinfection.

The solution is completely oxidized to orthophosphate, which reacts with ammonium molybdate to form phosphomolybdic acid under the catalysis of antimony salt.

......
This preview omits tables, figures, formulas and parts of the technical clauses. The complete document — 15 pages — is available in the English PDF.

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