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GB/T 45729-2025Test methods for active ion concentration in laser material (English PDF)

激光材料中激活离子浓度测试方法

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Issued by

SAMR; SAC

Level / Type

National · Recommended

Issue date

May 30, 2025

Implementation date

September 1, 2025

Scope

GB/T 45729-2025 is the English-translated version of 激光材料中激活离子浓度测试方法.

GB/T 45729-2025 is the Chinese national standard covering how much neodymium or ytterbium is actually in a laser glass, crystal, ceramic or fibre — the sample preparation and the clean environment the trace work needs, the four methods of ICP optical emission, ICP mass spectrometry, X-ray fluorescence and electron probe microanalysis, the glow discharge alternative, the recommended standard solutions and working conditions, the concentration calculation, and the uncertainty that decides whether two laboratories agree. First edition, under the China Machinery Industry Federation. In force from 1 September 2025. Issued on 30 May 2025, it has been in force since 1 September 2025.

Document preview — GB/T 45729-2025

National Standard of the People's Republic of China

ICS
31.260
Classification
L 51

Issued by: State Administration for Market Regulation; Standardization Administration of the PRC

Contents

  • PrefaceIII
  • IntroductionIV
  • 1 Scope1
  • 2 Normative references1
  • 3 Terms and Definitions1
  • 4 Test Conditions2
  • 4.1 Environmental Requirements2
  • 4.2 Test materials and equipment2
  • 4.3 Sample requirements3
  • 5 Test Method3
  • 5.1 Overview3
  • 5.2 Inductively Coupled Plasma Optical Emission Spectroscopy (ICP-OES)4
  • 5.3 Inductively Coupled Plasma Mass Spectrometry (ICP-MS)6
  • 5.4 X-ray fluorescence spectrometry (XRF)7
  • 5.5 Electron Probe Microanalysis (EPMA)8
  • 6 Data Processing10
  • 6.1 Calculation of activation ion concentration10
  • 6.2 Uncertainty analysis and assessment10
  • 7 Test Report11
  • Appendix A (Informative) Glow Discharge Mass Spectrometry12
  • A.1 Test Principles12
  • A.2 Instruments12
  • A.3 Test Preparation12
  • A.4 Test Step12
  • Appendix B (Informative) Recommended standard solutions and test working conditions14
  • B.1 Recommended ICP-OES series standard solutions and working conditions14
  • B.2 Recommended ICP-MS series standard solutions and working conditions15
  • B.3 Recommended XRF working conditions16
  • B.4 Recommended EPMA working conditions17
  • References19

Foreword

This document is in accordance with the provisions of GB/T 1.1-2020 "Guidelines for standardization work Part 1: Structure and drafting rules for standardization documents" Drafting.

Please note that some of the contents of this document may involve patents. The issuing organization of this document does not assume the responsibility for identifying patents.

This document was proposed by the China Machinery Industry Federation.

This document is under the jurisdiction of the National Optical Radiation Safety and Laser Equipment Standardization Committee (SAC/TC284).

This document was drafted by: Shanghai Institute of Optics and Precision Mechanics, Chinese Academy of Sciences, the 11th Institute of China Electronics Technology Group Corporation, The 209th Research Institute of China Ordnance Industry, Chengdu Dongjun Laser Co., Ltd., Beijing Leishengqiang Technology Co., Ltd., Chinese Academy of Sciences Shanghai Institute of Ceramics, Shanghai Institute of Applied Physics, Chinese Academy of Sciences, and Laser Fusion Research Center, China Academy of Engineering Physics.

The main drafters of this document are: Xu Yongchun, Hu Junjiang, Zhou Qinling, Sun Yutong, Ye Dahua, Zhou Shibin, Wang Congjuan, Feng Tao, Xu Min, Zhu Jianhui, Li Qing, Cong Haixia, Wang Fang, Chen Wei, Chen Shubin, Yu Chunlei, Hu Lili, and Chu Chu.

Introduction

Solid-state lasers and fiber lasers play an increasingly important role in industrial processing, communications, medical treatment, lidar, and scientific research.

As the core working material in solid lasers and fiber lasers, laser materials convert pump light into The laser is replaced by a laser of a specific wavelength. Commonly used laser materials include laser glass, laser crystal, laser ceramic and laser fiber. The concentration of active ions is One of the key performance indicators of laser materials, it plays an important role in the performance evaluation of laser materials and the development of lasers.

The test of the concentration of activated ions in laser materials lacks standardized test methods and cannot meet the development requirements of laser materials, lasers and laser technology.

In order to meet the development needs, it is urgent to formulate unified testing standards.

This document was developed to define in one document common test methods for the concentration of active ions in different types of laser materials.

There are inductively coupled plasma optical emission spectrometry (ICP-OES), inductively coupled plasma mass spectrometry (ICP-MS), X-ray fluorescence spectrometry (XRF), electron probe microanalysis (EPMA) and glow discharge mass spectrometry (GD-MS), etc.

The formulation of this document is conducive to the research and development, production and application of laser materials, and is conducive to the standardized application of laser material product standards.

Test method for active ion concentration in laser materials

1 Scope

This document describes the test method for the concentration of active ions in laser materials and specifies the test conditions, sample preparation, test procedures and data.

The processing process and test report format are given.

This document is applicable to the test of the concentration of activated ions in the range of (0.001~150)x1020ion/cm3 in laser materials.

The tests of other ion concentrations such as sensitization shall be carried out for reference.

2 Normative references

GB/T 4930

GB/T 6682

GB/T 14666

GB/T 15074

GB/T 15313

GB/T 16597

GB/T 17366

GB/T 21636

GB/T 23942

GB/T 25915.1

GB/T 27418

GB/T 39486

JJG196

3 Terms and definitions

The terms and definitions defined in GB/T 14666, GB/T 15313 and GB/T 21636 and the following apply to this document.

3.1 Laser materiallaser material

A solid gain medium that converts pump light energy into laser light by activating ions.

Note 1.Laser materials usually consist of two parts. active ions and solid matrix materials.

Note 2.Solid matrix materials usually include glass, crystal, ceramics and optical fiber.

3.2 Active ion

Metal ions whose energy level structure can achieve population inversion under the action of pump light.

Note. The main activating ions are transition metal ions such as titanium (Ti), chromium (Cr), manganese (Mn), cobalt (Co), nickel (Ni), etc.; rare earth metal ions such as cerium (Ce), praseodymium (Pr), Neodymium (Nd), samarium (Sm), gadolinium (Gd), terbium (Tb), dysprosium (Dy), holmium (Ho), erbium (Er), thulium (Tm), ytterbium (Yb), etc.

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This preview omits tables, figures, formulas and parts of the technical clauses. The complete document — 24 pages — is available in the English PDF.

Referenced standards

Editions of GB/T 45729

EditionTitleRevisionStatus
GB/T 45729-2025Test methods for active ion concentration in laser materialcurrent editionCurrent

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