Valid

GB/T 43361-2023Gas analysis - Analytical methods validation for hydrogen fuel in proton exchange membrane(PEM) fuel cell applications for road vehicles (English PDF)

气体分析 道路车辆用质子交换膜燃料电池氢燃料分析方法的确认

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Issued by

State Administration for Market Regulation, China National Standardization Administration

Level / Type

National · Recommended

Issue date

November 27, 2023

Implementation date

June 1, 2024

Scope

GB/T 43361-2023 is the English-translated version of 气体分析 道路车辆用质子交换膜燃料电池氢燃料分析方法的确认.

GB/T 43361-2023 — This document specifies the validation rules for analytical methods to ensure hydrogen quality and the requirements for reporting analysis results: It provides relevant measurement results: Recommendations for uncertainty assessment of results (expressed in mole fraction) are given, and are applicable to hydrogen based on the technical requirements for hydrogen in ISO 14687:2019: A list of analytical methods for each impurity in the gas and recommendations to ensure the quality of measurement results and ensure sample integrity: This document applies to proton exchange membrane fuel supplied to road vehicles after sampling from hydrogen filling stations or hydrogenation stations and sending it to laboratories for analysis: Analysis of gaseous hydrogen samples used in batteries: This document does not apply to online monitoring of hydrogen:

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Document preview — GB/T 43361-2023

National Standard of the People's Republic of China

ICS
71.100.20
Classification
G 86

Issued by: State Administration for Market Regulation, China National Standardization Administration

Contents

  • 1 Scope1
  • 2 Normative references1
  • 3 Terms and Definitions1
  • 4 Symbols1
  • 5 Hydrogen quality requirements2
  • 6 Requirements for validation and suitability evaluation of analytical methods2
  • 6.1 General2
  • 6.2 Performance parameters of analytical methods3
  • 6.2.1 List of main performance parameters3
  • 6.2.2 Selectivity3
  • 6.2.3 Detection limit and quantification limit3
  • 6.2.4 Measuring range5
  • 6.2.5 Accuracy5
  • 6.2.6 Precision6
  • 6.2.7 Measurement uncertainty7
  • 6.2.8 Robustness7
  • 6.3 Confirmation report8
  • 6.4 Quality control of analytical methods8
  • 7 Analytical Techniques8
  • 8 Samples10
  • 8.1 Sampling precautions10
  • 8.2 Sampling container10
  • 8.3 Sample10
  • 9 Analysis Report10
  • Appendix A (informative) Technical differences between this document and ISO 21087:2019 and their reasons12
  • Reference13
  • Table A:1 Technical differences between this document and ISO 21087:2019 and their reasons12

Foreword

This document complies with the provisions of GB/T 1.1-2020 "Standardization Work Guidelines Part 1: Structure and Drafting Rules of Standardization Documents" Drafting:

This document is modified to adopt ISO 21087:2019 "Gas Analysis Hydrogen Fuel Analysis Methods Proton Exchange Membrane Fuel for Road Vehicles" Battery":

Compared with ISO 21087:2019, there are many technical differences between this document and the clauses involved in the outer margin of the page:

Single lines (|) are marked: A list of these technical differences and their causes is provided in Appendix A:

The following editorial changes have been made to this document:

---The name of the standard was changed to "Confirmation of hydrogen fuel analysis method for proton exchange membrane fuel cells for gas analysis road vehicles";

---Change xmean to x (see Chapter 4, 6:2:3:1, 6:2:5:1);

---Change xmean' to x' (see Chapter 4, 6:2:5:1);

---Change "ISO 14687:-" to "ISO 14687:2019" (see 6.2:2:2);

---Added explanation of total precision (see 6.2:7:1);

---Changed the "reference materials" in Table 2 (see Table 2):

Please note that some content in this document may be subject to patents: The publisher of this document assumes no responsibility for identifying patents:

1 Scope

This document specifies the validation rules for analytical methods to ensure hydrogen quality and the requirements for reporting analysis results: It provides relevant measurement results:

Recommendations for uncertainty assessment of results (expressed in mole fraction) are given, and are applicable to hydrogen based on the technical requirements for hydrogen in ISO 14687:2019:

A list of analytical methods for each impurity in the gas and recommendations to ensure the quality of measurement results and ensure sample integrity:

This document applies to proton exchange membrane fuel supplied to road vehicles after sampling from hydrogen filling stations or hydrogenation stations and sending it to laboratories for analysis:

Analysis of gaseous hydrogen samples used in batteries:

This document does not apply to online monitoring of hydrogen:

2 Normative reference documents

The contents of the following documents constitute essential provisions of this document through normative references in the text: Among them, the dated quotations for undated referenced documents, only the version corresponding to that date applies to this document; for undated referenced documents, the latest version (including all amendments) applies to this document:

GB/T 6379.3 Accuracy of measurement methods and results (correctness and precision) Part 3: Precision of standard measurement methods intermediate measure GB/T 10628 Determination and calibration comparison method of gas analysis calibration gas mixture composition GB/T 14850 Gas Analysis Vocabulary GB/T 27417 Guidelines for Validation and Validation of Chemical Analysis Methods for Conformity Assessment GB/T 32467 Chemical analysis method validation and internal quality control terms and definitions ISO 12963 Gas analysis Comparative method for determination of the composition of mixed gases based on single-point and two-point calibration (Gasanalysis-pointcalibration) ISBN978-91-87461-59-0 European Guide to Chemistry: Laboratory guidance for method validation and associated rules for the suitability of analytical methods

3 Terms and definitions

The terms and definitions defined in GB/T 6379.3, GB/T 14850, GB/T 27417 and GB/T 32467 apply to this document:

4 Symbols

The following symbols apply to this document:

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This preview omits tables, figures, formulas and parts of the technical clauses. The complete document — 13 pages — is available in the English PDF.

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