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GB/T 39114-2020Nanotechnologies - Characterization of single-wall carbon nanotubes using ultraviolet-visible-near infrared (UV-Vis-NIR) absorption spectroscopy (English PDF)

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Issued by

State Administration for Market Regulation, China National Standardization Administration

Level / Type

National · Recommended

Issue date

October 11, 2020

Implementation date

May 1, 2021

Scope

GB/T 39114-2020 (Nanotechnologies - Characterization of single-wall carbon nanotubes using ultraviolet-visible-near infrared (UV-Vis-NIR) absorption spectroscopy) is available as an English-translated PDF.

GB/T 39114-2020 — This standard provides guidelines for characterizing single-walled carbon nanotubes (SWCNTs) in mixtures using optical absorption spectroscopy. This standard is applicable to the measurement of sample diameter, purity and the mass fraction of metallic SWCNTs in total SWCNTs. When used for nanotube diameter analysis, the applicable diameter range is 1nm~2nm.

Document preview — GB/T 39114-2020

National Standard of the People's Republic of China

ICS
71.040.50
Classification
G 30

Issued by: State Administration for Market Regulation, China National Standardization Administration

Contents

  • 1 Scope1
  • 2 Normative references1
  • 3 Terms, definitions and abbreviations1
  • 3.1 Terms and definitions1
  • 3.2 Abbreviations1
  • 4 General2
  • 4.1 Overview2
  • 4.2 Ultraviolet/visible/near infrared absorption spectroscopy2
  • 4.3 Optical absorption peaks of SWCNTs in the ultraviolet/visible/near infrared region2
  • 4.4 The relationship between SWCNT diameter and optical absorption peak3
  • 4.5 Deriving the purity index from the area of the optical absorption peak3
  • 4.6 Deriving the ratio of metallic SWCNTs from the optical absorption peak area4
  • 5 Ultraviolet/visible/near infrared spectrometer5
  • 6 Sample preparation method5
  • 6.1 General principles5
  • 6.2 D2O dispersion sample preparation when measuring the average diameter and ratio of metallic SWCNTs5
  • 6.3 Preparation of solid film when measuring the average diameter and ratio of metallic SWCNTs6
  • 6.4 DMF dispersion sample preparation when determining purity index6
  • 7 Optical measurement procedures and test conditions6
  • 8 Data analysis and result interpretation7
  • 8.1 Data analysis of SWCNT diameter characterization7
  • 8.2 Data analysis to determine the purity index7
  • 8.3 Data analysis of the ratio of metallic SWCNTs7
  • 9 Measurement uncertainty7
  • 10 Test report8
  • Appendix A (informative appendix) Deduction example of the relationship between SWCNTs optical absorption peak and average diameter9
  • Appendix B (informative appendix) Purity index determination example14
  • Reference16

Foreword

This standard was drafted in accordance with the rules given in GB/T 1.1-2009.

This standard uses the translation method equivalent to ISO /T S10868.2017 ``Nanotechnology single-wall carbon nanotubes UV/visible/near infrared

Absorption spectrum characterization method".

The Chinese documents that have a consistent correspondence with the international documents cited in this standard are as follows.

GB/T 30544.4-2019 Nanotechnology terminology Part 4.Nanostructured materials (ISO /T S80004-4.2011, IDT)

This standard has made the following editorial changes.

---Adjust the sorting of references.

This standard was proposed by the Chinese Academy of Sciences.

This standard is under the jurisdiction of the National Nanotechnology Standardization Technical Committee (SAC/TC279).

Drafting organizations of this standard. National Nanoscience Center, Institute of Physics, Chinese Academy of Sciences.

1 Scope

This standard provides guidelines for characterizing single-walled carbon nanotubes (SWCNTs) in mixtures using optical absorption spectroscopy.

This standard is applicable to the measurement of sample diameter, purity and the mass fraction of metallic SWCNTs in total SWCNTs.

When used for nanotube diameter analysis, the applicable diameter range is 1nm~2nm.

2 Normative references

The following documents are indispensable for the application of this document. For dated reference documents, only the dated version applies to this article

Pieces. For undated references, the latest version (including all amendments) applies to this document.

ISO /T S80004-4 Nanotechnology terminology Part 4.Nanostructured materials

3 Terms, definitions and abbreviations

3.1 Terms and definitions

ISO /T S80004-4 and the following terms and definitions apply to this document.

3.1.1

Purity index

The ratio of SWCNTs to the total carbon mass fraction in the sample defined by the optical method.

Note. The purity index is not the "purity" itself which is usually defined as the percentage of SWCNTs in the total mass of the sample. Cannot be detected due to absorption spectroscopy

The metal impurities of SWCNT samples, so this standard is not used to assess conventional purity. The metal impurity content can be determined by the international technical specification of thermogravimetric analysis

Characterization. Metal impurities are defined as catalyst metal particles, excluding metallic carbon nanotubes. See ISO /T S11308.

3.1.2

Metallic SWCNTs ratio

The composition ratio of metallic SWCNTs defined by the optical method to the total SWCNTs in the sample.

3.2 Abbreviations

The following abbreviations apply to this document.

CMC. Sodium carboxymethyl cellulose

DMF. Dimethylformamide

DOS. density of states

NIR. Near infrared

NMP. N-methyl-2-pyrrolidone

SC. Sodium Cholate

DOC. Sodium deoxycholate

SDS. Sodium Lauryl Sulfate

SDBS. Sodium Dodecylbenzene Sulfonate

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This preview omits tables, figures, formulas and parts of the technical clauses. The complete document — all pages — is available in the English PDF.

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