GB/T 39114-2020Nanotechnologies - Characterization of single-wall carbon nanotubes using ultraviolet-visible-near infrared (UV-Vis-NIR) absorption spectroscopy (English PDF)
纳米技术 单壁碳纳米管的紫外/可见/近红外吸收光谱表征方法
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Issued by
State Administration for Market Regulation, China National Standardization Administration
Level / Type
National · Recommended
Issue date
October 11, 2020
Implementation date
May 1, 2021
Scope
GB/T 39114-2020 is the English-translated version of 纳米技术 单壁碳纳米管的紫外/可见/近红外吸收光谱表征方法.
GB/T 39114-2020 — This standard provides guidelines for characterizing single-walled carbon nanotubes (SWCNTs) in mixtures using optical absorption spectroscopy.
This standard is applicable to the measurement of sample diameter, purity and the mass fraction of metallic SWCNTs in total SWCNTs. When used for nanotube diameter analysis, the applicable diameter range is 1nm~2nm.
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Document preview — GB/T 39114-2020
National Standard of the People's Republic of China
- ICS
- 71.040.50
- Classification
- G 30
Issued by: State Administration for Market Regulation, China National Standardization Administration
Contents
- 1 Scope1
- 2 Normative references1
- 3 Terms, definitions and abbreviations1
- 3.1 Terms and definitions1
- 3.2 Abbreviations1
- 4 General2
- 4.1 Overview2
- 4.2 Ultraviolet/visible/near infrared absorption spectroscopy2
- 4.3 Optical absorption peaks of SWCNTs in the ultraviolet/visible/near infrared region2
- 4.4 The relationship between SWCNT diameter and optical absorption peak3
- 4.5 Deriving the purity index from the area of the optical absorption peak3
- 4.6 Deriving the ratio of metallic SWCNTs from the optical absorption peak area4
- 5 Ultraviolet/visible/near infrared spectrometer5
- 6 Sample preparation method5
- 6.1 General principles5
- 6.2 D2O dispersion sample preparation when measuring the average diameter and ratio of metallic SWCNTs5
- 6.3 Preparation of solid film when measuring the average diameter and ratio of metallic SWCNTs6
- 6.4 DMF dispersion sample preparation when determining purity index6
- 7 Optical measurement procedures and test conditions6
- 8 Data analysis and result interpretation7
- 8.1 Data analysis of SWCNT diameter characterization7
- 8.2 Data analysis to determine the purity index7
- 8.3 Data analysis of the ratio of metallic SWCNTs7
- 9 Measurement uncertainty7
- 10 Test report8
- Appendix A (informative appendix) Deduction example of the relationship between SWCNTs optical absorption peak and average diameter9
- Appendix B (informative appendix) Purity index determination example14
- Reference16
Foreword
This standard was drafted in accordance with the rules given in GB/T 1.1-2009.
This standard uses the translation method equivalent to ISO /T S10868.2017 ``Nanotechnology single-wall carbon nanotubes UV/visible/near infrared
Absorption spectrum characterization method".
The Chinese documents that have a consistent correspondence with the international documents cited in this standard are as follows.
GB/T 30544.4-2019 Nanotechnology terminology Part 4.Nanostructured materials (ISO /T S80004-4.2011, IDT)
This standard has made the following editorial changes.
---Adjust the sorting of references.
This standard was proposed by the Chinese Academy of Sciences.
This standard is under the jurisdiction of the National Nanotechnology Standardization Technical Committee (SAC/TC279).
Drafting organizations of this standard. National Nanoscience Center, Institute of Physics, Chinese Academy of Sciences.
1 Scope
This standard provides guidelines for characterizing single-walled carbon nanotubes (SWCNTs) in mixtures using optical absorption spectroscopy.
This standard is applicable to the measurement of sample diameter, purity and the mass fraction of metallic SWCNTs in total SWCNTs.
When used for nanotube diameter analysis, the applicable diameter range is 1nm~2nm.
2 Normative references
The following documents are indispensable for the application of this document. For dated reference documents, only the dated version applies to this document. For undated references, the latest version (including all amendments) applies to this document.
ISO /T S80004-4 Nanotechnology terminology Part 4.Nanostructured materials
3 Terms, definitions and abbreviations
3.1 Terms and definitions
ISO /T S80004-4 and the following terms and definitions apply to this document.
3.1.1
Purity index
The ratio of SWCNTs to the total carbon mass fraction in the sample defined by the optical method.
Note. The purity index is not the "purity" itself which is usually defined as the percentage of SWCNTs in the total mass of the sample. Cannot be detected due to absorption spectroscopy
The metal impurities of SWCNT samples, so this standard is not used to assess conventional purity. The metal impurity content can be determined by the international technical specification of thermogravimetric analysis
Characterization. Metal impurities are defined as catalyst metal particles, excluding metallic carbon nanotubes. See ISO /T S11308.
3.1.2
Metallic SWCNTs ratio
The composition ratio of metallic SWCNTs defined by the optical method to the total SWCNTs in the sample.
3.2 Abbreviations
The following abbreviations apply to this document.
CMC. Sodium carboxymethyl cellulose
DMF. Dimethylformamide
DOS. density of states
NIR. Near infrared
NMP. N-methyl-2-pyrrolidone
SC. Sodium Cholate
DOC. Sodium deoxycholate
SDS. Sodium Lauryl Sulfate
SDBS. Sodium Dodecylbenzene Sulfonate
......
This preview omits tables, figures, formulas and parts of the technical clauses. The complete document — 37 pages — is available in the English PDF.
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