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GB/T 32887-2016Determination of polychlorinated biphenyls in electrical and electronic products - Gas chromatography-mass spectrometry (English PDF)

电子电气产品中多氯联苯的测定 气相色谱-质谱法

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Issued by

SAMR; SAC

Level / Type

National · Recommended

Issue date

August 29, 2016

Implementation date

March 1, 2017

Scope

GB/T 32887-2016 is the English-translated version of 电子电气产品中多氯联苯的测定 气相色谱-质谱法.

GB/T 32887-2016 is the Chinese standard "Determination of polychlorinated biphenyls in electrical and electronic products - Gas chromatography-mass spectrometry".

Its scope clause reads: This standard specifies the method of gas chromatography-mass spectrometry for polychlorinated biphenyls (PCBs) in electrical and electronic products.

This standard applies to the determination of polychlorinated biphenyls in polymer materials for electrical and electronic products with a limit of 0.5 mg/kg. Its clauses include normative reference documents; terms and definitions; principle; reagents or materials.

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Document preview — GB/T 32887-2016

National Standard of the People's Republic of China

ICS
31.020
Classification
L 10

Issued by: State Administration for Market Regulation; Standardization Administration of the PRC

Contents

  • 1 Scope
  • 2 normative reference documents
  • 3 terms and definitions
  • 4 principle
  • 5 reagents or materials

1 Scope

This standard specifies the method of gas chromatography-mass spectrometry for polychlorinated biphenyls (PCBs) in electrical and electronic products.

This standard applies to the determination of polychlorinated biphenyls in polymer materials for electrical and electronic products with a limit of 0.5 mg/kg.

2 normative reference documents

The following documents are indispensable for the application of this document. For dated references, only the dated edition applies to this article

Pieces. For undated references, the latest edition (including all modifications) applies to this document.

Limits for Restricted Substances in Electrical and Electronic Products GB/T 26572-2011

3 terms and definitions

The following terms and definitions apply to this document.

3.1

Polychlorinated biphenyls; polychlorinated biphenyls;

The polychlorinated compounds formed by the substitution of hydrogen on the biphenyl ring with chlorine are collectively represented by the formula C12H (10-n) Cln (1<=n<=10).

4 principle

The extracted samples were extracted with organic solvent, and the extracts were concentrated, purified and fixed. The samples were determined by gas chromatography-mass spectrometry.

The retention time of the target analyte was quantified by qualitative and external standard method.

5 reagents or materials

Unless otherwise stated, all reagents are chromatographic pure.

5.1 Acetone

Analytical purity.

5.2

n-hexane.

5.3 Dichloromethane

Analytical purity.

5.4

Toluene.

5.5 Acetone n-Hexane (1 1)

Prepared from acetone (5.1) and n-hexane (5.2) in volume ratio.

5.6 Dichloromethane n-Hexane (2 8)

Prepared from n-hexane (5.2) and dichloromethane (5.3) in volume ratio.

5.7 Polychlorinated biphenyls (PCBs) Reference material

See Appendix A for PCB reference materials and their purity information.

5.8 Polychlorobenzene Monoclonal stock solution

accurately weighed the appropriate amount of PCB material (5.7), with a small amount of n-hexane (5.2) dissolved, […]

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This preview omits tables, figures, formulas and parts of the technical clauses. The complete document — 15 pages — is available in the English PDF.

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