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GB/T 27842-2011Chemicals - Test method for dynamic surface tension - Fast-bubble technique (English PDF)

化学品 动态表面张力的测定 快速气泡法

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Issued by

General Administration of Quality Supervision, Inspection and Quarantine of the People’s Republic of China

Level / Type

National · Recommended

Issue date

December 30, 2011

Implementation date

August 1, 2012

Scope

GB/T 27842-2011 is the English-translated version of 化学品 动态表面张力的测定 快速气泡法.

GB/T 27842-2011 — This Standard specifies the principle, significance and use, apparatus, reagents and materials, calibration and standardization, test procedure, calculations and report of the determination of dynamic surface tension using chemicals by fast-bubble technique.

This Standard is applicable to the determination of the specific free energy of a liquid- gas surface a short time after formation of the surface. This Standard is applicable to liquids with vapor pressures up to 30.0 kPa and kinematic viscosities up to 4.0 mm/s at the test temperature. NOTE. Higher viscosities have not yet been investigated.

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Document preview — GB/T 27842-2011

National Standard of the People's Republic of China

Classification
A 80

Issued by: General Administration of Quality Supervision, Inspection and Quarantine of the People’s Republic of China

Contents

  • Foreword...3
  • 1 Scope...4
  • 2 Normative references...4
  • 3 Terms, definitions and symbols...4
  • 4 Principle of test method...6
  • 5 Significance and use...6
  • 6 Apparatus...6
  • 7 Reagents and materials...8
  • 8 Calibration and standardization...8
  • 9 Test procedure...10
  • 10 Calculations...11
  • 11 Report...11
  • Annex A (normative) Warning statements...13
  • Bibliography...16

Foreword

This Standard is drafted in accordance with the rules given in GB/T 1.1-2009.

This Standard is the same as ASTM D3825-90.2005 "Standard test method for

dynamic surface tension by the fast-bubble technique) (English version) in terms of

technical content.

The following editorial modifications have been made in this Standard.

- REPLACE "this test method" WITH "this Standard";

- DELETE the foreword, keywords and other informative parts of the original ASTM;

- CONVERT all units and their values INTO China's legal units of measurement;

- ADD heading to the original figures and tables missing heading, and ADJUST the

number of the figures, tables and equations in the whole text.

This Standard is proposed by and is under the jurisdiction of National Technical

Committee on Hazardous Chemicals of Standardization Administration of China

(SAC/TC 251).

Drafting organizations of this Standard. China Academy of Inspection and Quarantine,

China National Chemical Economic and Technical Development Center, Jiangsu Coal

Chemical Engineering Design and Research Institute Co., Ltd., Sinochem Chemical

Standardization Institute.

Main drafters of this Standard. Li Xi, Chen Huiming, Wang Xiaobing, Yang Ting, Guo

Xinyu.

Chemicals - Test method for dynamic

surface tension - Fast-bubble technique

IMPORTANT NOTE. 1.5 This Standard does not purport to address all of the

safety concerns (if any) associated with its use. It is the responsibility of the

user of this Standard to consult and establish appropriate safety and health

practices and determine the applicability of regulatory limitations prior to use.

For specific warning statements, see 7.3, 7.4, and 7.5.

1 Scope

This Standard specifies the principle, significance and use, apparatus, reagents and

materials, calibration and standardization, test procedure, calculations and report of

the determination of dynamic surface tension using chemicals by fast-bubble

technique.

This Standard is applicable to the determination of the specific free energy of a liquid-

gas surface a short time after formation of the surface.

This Standard is applicable to liquids with vapor pressures up to 30.0 kPa and

kinematic viscosities up to 4.0 mm/s at the test temperature.

NOTE. Higher viscosities have not yet been investigated.

2 Normative references

The following referenced documents are indispensable for the application of this

document. For dated references, only the edition cited applies. For undated references,

the latest edition of the referenced document (including any amendments) applies.

ASTM D1193 Specification for reagent water

ASTM D1331 Test methods for surface and interfacial tension of solutions of

surface-active agents

ASTM E1 Specification for ASTM liquid-in-glass thermometers

3 Terms, definitions and symbols

3.1 Terms and definitions

7 Reagents and materials

7.1 Purity of reagents. Reagent grade chemicals shall be used in all tests. Other grades

may be used, provided it is first ascertained that the reagent is of sufficiently high purity

to permit its use without lessening the accuracy of the determination.

7.2 Purity of water. Unless otherwise indicated, references to water shall be

understood to mean reagent water conforming to ASTM D1193, Type III.

7.3 Calibration liquids. reagent grade, covering a wide range of surface tension.

Acetone, toluene, ethanol, and methanol have been found satisfactory for this purpose.

a) Acetone. (Warning. Extremely flammable. Vapors may cause flash fire. See

A.1 of Annex A).

b) Toluene. (Warning. Flammable. Vapor harmful. See A.6 of Annex A).

c) Methanol. (Warning. Flammable. Vapor harmful. See A.5 of Annex A).

d) Ethanol. (Warning. Flammable. Denatured. See A.4 of Annex A).

7.4 Cleaning solution. chromic-sulfuric acid (Warning. Causes severe burns. A

recognized carcinogen strong oxidizer, contact with organic material can cause

fire. Hygroscopic. See A.2 of Annex A).

7.5 Nitrogen. of purity that is suitable to avoid reaction with test liquid and less than

100 mg/L CO2 with amines (Warning. Compressed gas under high pressure. See

A.3 of Annex A).

8 Calibration and standardization

8.1 Clean the bubbler with cleaning solution, and rinse with water (Warning. Causes

severe burns. A recognized carcinogen. Strong oxidizer, contact with organic

material may cause fire. Hygroscopic. A.2 of Annex A). Condition by soaking in

water for 48 h followed by a final rinse with water.

8.2 Set up the apparatus as shown in Figure 2, and bring the thermostat to the desired

temperature.

NOTE. If a test temperature is not specified, 25 °C ± 0.1 °C is recommended.

Annex A

(normative)

Warning statements

A.1 Acetone

Extremely flammable. Vapors may cause flash fire.

Keep away from heat, sparks, and open flame.

Keep container dosed.

Use with adequate ventilation.

Vapors may spread long distances and ignite explosively.

Avoid build-up of vapors and eliminate all sources of ignition, especially non-explosion

proof electrical apparatus and heaters.

Avoid prolonged breathing of vapor or spray mist.

Avoid contact with eyes and skin.

In case of spillage absorb and flush with large volumes of water.

In case of fire use water, dry chemical, CO2, or foam.

A.2 Chromic Acid (Cleaning Solution)

Causes severe bums. A recognized carcinogen.

Strong oxidizer - contact with other material can cause fire. Hygroscopic.

Do not get in eyes, on skin, on clothing.

Avoid breathing vapor or mist.

Keep container closed.

Use with adequate ventilation.

Do not take internally.

Wash thoroughly after handling.

In case of spillage soak up with excess sodium carbonate and

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This preview omits tables, figures, formulas and parts of the technical clauses. The complete document — 16 pages — is available in the English PDF.

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