GB/T 20899.10-2025Methods for chemical analysis of gold ores — Part 10: Determination of antimony content (English PDF)

Foreword

This document is in accordance with the provisions of GB/T 1.1-2020 "Guidelines for standardization work Part 1: Structure and drafting rules for standardization documents" Drafting.

This document is Part 10 of GB/T 20899 “Methods for chemical analysis of gold ores”. GB/T 20899 has published the following 14 part.

— Part 1: Determination of gold content;

— Part 2: Determination of silver content - Flame atomic absorption spectrometry;

— Part 3: Determination of arsenic content;

— Part 4: Determination of copper content;

— Part 5: Determination of lead content;

— Part 6: Determination of zinc content;

— Part 7: Determination of iron content;

— Part 8: Determination of sulfur content;

— Part 9: Determination of carbon content;

— Part 10.Determination of antimony content;

— Part 12.Determination of arsenic, mercury, cadmium, lead and bismuth content - Atomic fluorescence spectrometry;

— Part 13.Determination of lead, zinc, bismuth, cadmium, chromium, arsenic and mercury content - Inductively coupled plasma atomic emission spectrometry;

— Part 14.Determination of thallium content - Inductively coupled plasma atomic emission spectrometry and inductively coupled plasma mass spectrometry;

— Part 15.Determination of copper, lead, zinc, silver, iron, manganese, nickel, cobalt, aluminium, chromium, cadmium, antimony, bismuth, arsenic, mercury, selenium, barium and beryllium content Coupled plasma mass spectrometry.

This document replaces GB/T 20899.10-2007 "Chemical analysis methods of gold ores Part 10.Determination of antimony content" and Compared with GB/T 20899.10-2007, in addition to structural adjustments and editorial changes, the main technical changes are as follows.

a) The measurement range has been changed (see Chapter 1, Chapter 1 of the 2007 edition);

b) Changed the determination method from "Hydride Generation-Atomic Fluorescence Spectrometry" to "Flame Atomic Absorption Spectrometry" (see Chapter 4, 2007 Chapter 3 of the 2011 edition);

c) The sample mass has been changed (see 5.4.2, 2.4.1 of the 2007 edition);

d) Added the method for eliminating interfering elements (see 5.5.3.1);

e) The area of filter paper added has been changed (see 5.5.3.2, 2.4.3.1 of the 2007 edition);

f) The acid addition method and acid concentration have been changed (see 5.5.3.3, 2.4.3.2 of the 2007 edition);

g) The “allowable difference” requirement has been deleted (see 2.6 of the 2007 edition);

h) Added “repeatability” and “reproducibility” requirements (see 5.7).

Please note that some of the contents of this document may involve patents. The issuing organization of this document does not assume the responsibility for identifying patents.

This document is proposed and coordinated by the National Gold Standardization Technical Committee (SAC/TC379).

This document was drafted by: Changchun Gold Research Institute Co., Ltd., Yantai Harbin Engineering University Research Institute, Shenzhen Gold, Silver and Jewelry Inspection Institute Shandong Gold Geology and Mineral Exploration Co., Ltd., Zijin Mining Group Co., Ltd., and SDIC Jincheng Metallurgical Co., Ltd.

Co., Ltd., Shandong Hengbang Smelting Co., Ltd., Yantai Jinao Environmental Protection Technology Co., Ltd., Changchun National Inspection (Jiyuan) Testing Technology Co., Ltd.

Co., Ltd., Changchun Gold Research Institute Yantai Precious Metals Materials Research Institute Co., Ltd., Hunan Chenzhou Mining Co., Ltd., Hunan Nonferrous Metals RESEARCH INSTITUTE LIMITED.

The main drafters of this document are: Lu Xingen, Zhang Yue, Liu Lijia, Han Bingbing, Zhang Hailong, Su Guangdong, Hong Bo, Zhang Yu, Zhou Xuliang, Zou Xiaofen, Ma Run, Wang Lei, Wang Zhiqiang, Mu Yan, Sun Mingxuan, Sun Zhen, Ye Fangfang, Zhang Xuelian, Liu Peng, and Ma Ye.

The previous versions of this document and the documents it replaces are as follows.

— GB/T 20899.10-2007;

— This is the first revision.

Introduction

After the ore is processed by the separation operation, its main components have been enriched in the ore, and the secondary components or other associated metals of the ore have also been GB/T 20899 "Chemical Analysis Methods of Gold Ores" is intended to help gold mining companies accurately understand the main components and impurities of gold ores.

content, which is beneficial to optimize the control parameters of the smelting process, accurately control the consumption of reagents, reduce the interference of impurity elements on the smelting and purification process, and improve the The comprehensive recovery rate of valuable elements can contribute to the efficient recycling of resources, sustainable green and healthy development, and smart mines in the entire gold industry.

GB/T 20899 is planned to consist of 14 parts.

— Part 1: Determination of gold content. The purpose is to specify the fire assay gravimetric method, fire assay enrichment-flame Atomic absorption spectrometry, activated carbon enrichment-flame atomic absorption spectrometry, activated carbon enrichment-iodine titration and the determination of the applicable methods scope.

— Part 2: Determination of silver content flame atomic absorption spectrometry. The purpose is to specify the flame atomic absorption spectrometry method for the determination of silver content in gold ores Absorption spectroscopy and applicable measurement range.

— Part 3: Determination of arsenic content. The purpose is to specify the diethyldithiocarbamate silver spectrophotometric method for the determination of arsenic content in gold ores.

The titration method and potassium dichromate titration method and the applicable determination range of each method.

— Part 4: Determination of copper content. The purpose is to specify the flame atomic absorption spectrometry and thiosulfate method for the determination of copper content in gold ores Sodium titration method and the applicable measurement range of each method.

— Part 5: Determination of lead content. The purpose is to specify the flame atomic absorption spectrometry and ethylenediaminetetramine method for the determination of lead content in gold ores.

Disodium acetate titration method and the applicable determination range of each method.

— Part 6: Determination of zinc content. The purpose is to specify the flame atomic absorption spectrometric method for the determination of zinc content in gold ores and the applicable measurement methods. Set a range.

— Part 7: Determination of iron content. The purpose is to specify the potassium dichromate titration method for the determination of iron content in gold ore and the applicable determination method. scope.

— Part 8: Determination of sulfur content. The purpose is to specify the barium sulfate gravimetric method and combustion-acid-base titration method for the determination of sulfur content in gold ores and the applicable measurement range of each method.

— Part 9: Determination of carbon content. The purpose is to specify the non-aqueous titration method and high-frequency combustion infrared absorption method for the determination of carbon content in gold ores Method and applicable measurement range.

— Part 10.Determination of antimony content. The purpose is to specify the flame atomic absorption spectrometry and cerium sulfate drop method for the determination of antimony content in gold ores The determination method and the applicable measurement range of each method.

— Part 12.Determination of arsenic, mercury, cadmium, lead and bismuth content by atomic fluorescence spectrometry.

Determination of lead and bismuth by hydride generation-atomic fluorescence spectrometry and its applicable determination range.

— Part 13.Determination of lead, zinc, bismuth, cadmium, chromium, arsenic and mercury content - Inductively coupled plasma atomic emission spectrometry.

Inductively coupled plasma atomic emission spectrometry for the determination of lead, zinc, bismuth, cadmium, chromium, arsenic and mercury in specified gold ores and its application measurement range.

— Part 14.Determination of thallium content - Inductively coupled plasma atomic emission spectrometry and inductively coupled plasma mass spectrometry.

The purpose is to determine the amount of thallium in gold ores by inductively coupled plasma atomic emission spectrometry and inductively coupled plasma mass spectrometry Methods and the applicable measurement range of each method.

— Part 15.Determination of the content of copper, lead, zinc, silver, iron, manganese, nickel, cobalt, aluminium, chromium, cadmium, antimony, bismuth, arsenic, mercury, selenium, barium and beryllium The purpose is to determine the content of copper, lead, zinc, silver, iron, manganese, nickel, cobalt, aluminum, chromium, cadmium, antimony, bismuth, arsenic, Determination of mercury, selenium, barium and beryllium by inductively coupled plasma mass spectrometry and applicable determination range.

Chemical analysis methods for gold ores Part 10.Determination of antimony content

1 Scope

This document specifies the method for the determination of antimony in gold ores.

This document is applicable to the determination of antimony content in gold ore. Method 1 Flame atomic absorption spectrometry Determination range. 0.050%~5.00%;

Method 2.Cerium sulfate titration method. Determination range. 2.00%~10.00%.

2 Normative references

GB/T 17433

3 Terms and Definitions

The terms and definitions defined in GB/T 17433 apply to this document.

4 Method 1.Flame Atomic Absorption Spectrometry