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YS/T 990.14-2014Methods for chemical analysis of copper matte. Part 14: Determination of zinc content. Atomic absorption spectrmetry and NazEDTA titration methods (English PDF)

冰铜化学分析方法 第14部分:锌量的测定原子吸收光谱法和Na2EDTA滴定法

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Issued by

Ministry of Industry and Information Technology

Level / Type

National · Recommended

Issue date

October 14, 2014

Implementation date

April 1, 2015

Scope

YS/T 990.14-2014 is the English-translated version of 冰铜化学分析方法 第14部分:锌量的测定原子吸收光谱法和Na2EDTA滴定法.

YS/T 990.14-2014 — This section YS/T 990 specifies the method for determination of copper matte zinc content. This section applies to the determination of copper ice zinc content.

1 measured in the range of 0.20% to 2.00%; Tier 2 measurement range 2.00% - 6.00%.

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Document preview — YS/T 990.14-2014

National Standard of the People's Republic of China

ICS
77.120.30
Classification
H 13

Issued by: Ministry of Industry and Information Technology

Contents

  • Foreword
  • 1 Scope
  • 2 Method 1. atomic absorption spectrometry
  • 2.1 Method summary
  • 2.2 Reagents
  • 2.3 Instrument

Foreword

YS/T 990 "Methods for chemical analysis of copper matte" is divided into 18 parts.

--- Part 1. Determination of copper content iodometry;

--- Part 2. Determination of gold and silver atomic absorption spectroscopy and fire assay;

--- Part 3. Determination of sulfur content - Gravimetric method and combustion titration method;

--- Part 4. Determination of the amount of bismuth atomic absorption spectrometry;

--- Part 5. Determination of the amount of fluorine ion selective electrode method;

--- Part 6. Determination of lead content - Atomic absorption spectroscopy and Na2EDTA titration;

--- Part 7. Determination of cadmium content - Atomic absorption spectrometry;

--- Part 8. Determination of arsenic content by hydride generation - atomic fluorescence spectrometry, diethyl dithiocarbamate spectrophotometry silver and potassium bromate titration;

--- Part 9. Determination of iron content dichromate method;

--- Part 10. Determination of silicon dioxide content molybdenum blue spectrophotometric method and silicon potassium fluoride titration;

--- Part 11. Determination of the amount of nickel atom absorption spectrometry;

--- Part 12. Determination of the amount of chromium oxide of aluminum Azure S Spectrophotometry;

--- Part 13. Determination of magnesium oxide content - Atomic absorption spectrometry;

--- Part 14. Determination of the amount of zinc atomic absorption spectrometry and Na2EDTA titration;

--- Part 15. Determination of antimony content - Atomic absorption spectrometry;

--- Part 16. Determination of mercury content - Cold atomic absorption spectrometry;

--- Part 17. Determination of the amount of cobalt atomic absorption spectrometry;

--- Part 18. lead, zinc, nickel, arsenic, bismuth, antimony, calcium, magnesium, cadmium, cobalt content - Inductively coupled plasma atomic emission spectrometry.

This section YS/T Part 14 990.

This section drafted in accordance with GB/T 1.1-2009 given rules.

The non-ferrous metal part by the National Standardization Technical Committee (SAC/TC243) centralized.

This section is responsible for drafting unit. Zhongtiaoshan Nonferrous Metals Group Co., Ltd. Daye Nonferrous Metals Group Holdings Limited.

Part 1 Drafting Unit. Beijing Nonferrous Metal Research Institute.

The unit participated in the drafting Part 1. General Research Institute of Mining and Metallurgy Beijing, People's Republic of China, Ningbo Entry-Yanggu Xiang Light Copper Co., Ltd., Hangzhou Fuchunjiang Smelting Co., Ltd., Tongling Nonferrous Metals Group Holdings Co., Ltd., Yunnan Copper Company Limited.

This section Method 2 drafting units. Zhuzhou Smelter Group Co., Ltd.

This section participated in the drafting Method 2. Beijing General Research Institute of Mining and Metallurgy, Yanggu Yoshimitsu Copper Co., Ltd., Guangzhou Nonferrous Metal Research Institute, cloud Southern Copper Co., Ltd., Hangzhou Fuchunjiang Smelting Co., Ltd.

1 Scope

This section YS/T 990 specifies the method for determination of copper matte zinc content.

This section applies to the determination of copper ice zinc content. 1 measured in the range of 0.20% to 2.00%; Tier 2 measurement range 2.00% - 6.00%.

2 Method 1. atomic absorption spectrometry

2.1 Method summary

After the sample with hydrochloric acid, nitric acid, hydrofluoric acid, perchloric acid is dissolved, using air - acetylene flame atomic absorption spectrometer at a wavelength of 213.9nm Measuring the absorbance of zinc, according to the standard curve method to calculate the amount of zinc.

2.2 Reagents

Unless otherwise indicated, used in the analysis confirmed only for the gifted class pure reagents and distilled or deionized water or equivalent purity.

2.2.1 hydrochloric acid (rho = 1.19g/mL).

2.2.2 nitric acid (rho = 1.40g/mL).

2.2.3 nitric acid (11).

2.2.4 hydrofluoric acid (rho = 1.15g/L).

2.2.5 perchloric acid (rho = 1.68g/L).

2.2.6 standard zinc stock solution. Weigh 1.0000g zinc metal (wZn>=99.99%), placed in 250mL beaker, add 10mL of nitric acid (2.2.3), low heat until completely dissolved, remove nitrogen oxides micro-boiling, cooled and transferred to 1000mL volumetric flask, dilute to the mark, Mix well. 1mL solution containing 1mg zinc.

2.2.7 Zinc standard solution. Pipette 10.00mL standard zinc stock solution (2.2.6) in 100mL volumetric flask, 10mL of nitric acid was added (2.2.3), Dilute with water to volume, and mix. This solution 1mL containing 100µg zinc.

2.3 Instrument

Flame atomic absorption spectrometer, with zinc hollow cathode lamp.

Under optimum working conditions for those who can reach the following indicators can be used.

--- Characteristic concentration. a solution in the measurement matrix consistent solution, characterized in zinc concentration is not more than 0.01µg/mL.

--- Precision. standard solution with the highest concentration of 11 times the absorbance measurements, the standard deviation should not exceed the average absorbance of 1.0%;

The lowest concentration of standard solution used (instead of "zero concentration" standard solution) 11 measuring the absorbance, which shall not exceed the maximum standard deviation 0.5% concentration of the standard average absorbance.

--- Linear curve. the curve according to concentration, is divided into five sections, the difference between the absorbance of the absorbance difference between the highest and the lowest segment of the segment Ratio of not less than 0.85.

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This preview omits tables, figures, formulas and parts of the technical clauses. The complete document — 7 pages — is available in the English PDF.

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