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GB/T 8943.4-2008Paper, board and pulp -- Determination of calcium and magnesium (English PDF)

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Issued by

Standardization Administration of China

Level / Type

National · Recommended

Issue date

January 4, 2008

Implementation date

September 1, 2008

Scope

GB/T 8943.4-2008 (Paper, board and pulp -- Determination of calcium and magnesium) is available as an English-translated PDF.

GB/T 8943.4-2008 — GB/T 8943 provisions of this part of the two methods, namely EDTA complexometric titration (Method A) and flame atomic absorption spectrophotometry (Method B), determination of paper, board and pulp calcium and magnesium content, should arbitration by flame atomic absorption spectrophotometry (Method B).

When the paper, board and pulp calcium and magnesium content of greater than each 200mg/kg, you can use EDTA complexometric titration (Method A). This section applies to a variety of paper, board and pulp - Determination of calcium and magnesium content.

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Document preview — GB/T 8943.4-2008

National Standard of the People's Republic of China

ICS
85.060
Classification
Y 30
Replacing
GB/T 8943.4-1988

Issued by: Standardization Administration of China

Contents

  • Foreword
  • 1 Scope
  • 2 Normative references
  • 3 Method A. EDTA complexometric titration
  • 3.1 Principle
  • 3.2 Reagents

Foreword

GB/T 8943 is divided into four parts.

--- GB/T 8943.1 "paper, board and pulp - Determination of copper content";

--- GB/T 8943.2 "paper, board and pulp - Determination of iron content";

--- GB/T 8943.3 "paper, board and pulp - Determination of manganese content";

--- GB/T 8943.4 "Paper, paperboard and pulp calcium and magnesium content determination." this part of GB/Part 4 T 8943, and 777 corresponding to the international standard ISO .2001 "Paper, board and pulp calcium content law". This part is GB/T 8943.4-1988 "Pulp, paper and paperboard, calcium, magnesium Determination Act" amendments.

The partial modification of international standards ISO 777:2001.

This part of International Standard ISO 777:2001 compared to the following changes.

--- Adding a new test method (see Section 3 of this chapter).

This part of ISO 777:2001 technical differences are listed in Appendix A.

This part of ISO 777:2001 structure comparison are listed in Appendix B.

This Part replaces GB/T 8943.4-1988.

This portion of the GB/T 8943.4-1988 have compared the following changes.

--- Increased warnings;

--- Increasing the normative references;

--- Modify some narrative statement.

This section of the Appendices A and B are informative appendices.

This part is proposed by the China National Light Industry Council.

This part of the National Standardization Technical Committee under the jurisdiction of the paper industry.

This part of the paper by the Zhejiang Provincial Quality Supervision, Inspection Station is responsible for drafting.

1 Scope

GB/T 8943 provisions of this part of the two methods, namely EDTA complexometric titration (Method A) and flame atomic absorption spectrophotometry (Method B), determination of paper, board and pulp calcium and magnesium content, should arbitration by flame atomic absorption spectrophotometry (Method B).

When the paper, board and pulp calcium and magnesium content of greater than each 200mg/kg, you can use EDTA complexometric titration (Method A).

This section applies to a variety of paper, board and pulp - Determination of calcium and magnesium content.

2 Normative references

The following documents contain provisions which, through GB/T reference in this 8943 constitute provisions of this part. For dated references Documents, all subsequent amendments (not including errata content) or revisions do not apply to this section, however, encourage the present section Research on the parties to reach an agreement to use the latest versions of these documents. For undated references, the latest version applies to this section.

GB/T 450 to take a sample of paper and cardboard (GB/T 450-2002, eqv ISO 186:1994) GB/T 462 Paper and board Determination of moisture (GB/T 462-2003, ISO 287. 1985, MOD) GB/T 740 pulp samples taken (GB/T 740-2003, ISO 7213:1991, IDT) GB/T 741 Determination of pulp sample moisture (GB/T 741-2003, ISO 638. 1978, MOD) GB/T 742 paper, paperboard and pulp residue (ash) determination (900 °C) (GB/T 742-2003, ISO 2144:1997, MOD)

3 Method A. EDTA complexometric titration

3.1 Principle

The sample was ashed and the residue (ash) is dissolved in hydrochloric acid, and diluted to volume. Take one part of the solution was adjusted to pH = 12, calcium indicator, with EDTA standard solution titration, the standard solution of calcium consumption to calculate the content of the sample.

Another part of the solution with ammonia buffer adjusted to pH = 10. In KB indicator (an acidic chrome blue K mixed indicator) with EDTA titration, EDTA solution volume consumed is the sum of calcium and magnesium consumption.

By the total amount of calcium consumed to calculate the difference between the amount of EDTA magnesium content of the sample.

3.2 Reagents

All reagents used for testing should be analytical grade (AR), test water should be distilled or deionized water.

3.2.1 EDTA standard solution. Ba (EDTA) = 1/56mol/L, dissolved 6.635g of EDTAC10H14O8N2Na2 · 2H2O) (GB 1401) in distilled water and diluted to 1L.

3.2.2 Zinc standard solution. Weigh 1g analytically pure metallic zinc particles (weighing accuracy 0.1mg) in 150mL conical flask, 6mol/L hydrochloric acid solution Liquid 10mL ~ 20mL completely dissolved and transferred to 1L volumetric flask, dilute to the mark with distilled water, according to the equation (1) calculate the standard zinc solution concentration.

Ba = 65.38 m1

......
This preview omits tables, figures, formulas and parts of the technical clauses. The complete document — 7 pages — is available in the English PDF.

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