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GB/T 39359-2020Integrating sphere method for the test of liquid/solid suspended photocatalytic hydrogen production reaction (English PDF)

积分球法测量悬浮式液固光催化制氢反应

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Issued by

SAMR; SAC

Level / Type

National · Recommended

Issue date

November 19, 2020

Implementation date

June 1, 2021

Scope

GB/T 39359-2020 is the English-translated version of 积分球法测量悬浮式液固光催化制氢反应.

GB/T 39359-2020 fixes the integrating sphere method for measuring the quantum efficiency of suspension liquid-solid photocatalytic hydrogen production reaction systems, and specifies the test system, the measurement content, the test requirements and the data and calculation requirements for it.

Clause 1 states that it applies to the accurate measurement of the spectral absorption characteristics and of the quantum efficiency of hydrogen production in liquid-solid suspension solar photocatalytic hydrogen production reaction systems.

The body runs Scope, Normative references, Terms and definitions, Symbol, Test system, Measurement content, Test requirements and Data and calculation, with three appendices: the basic principles of the optical integrating sphere and a test case, both informative, and a normative appendix on the integrating sphere photocatalytic hydrogen production reaction measurement system.

Clause 2 cites GB/T 8981, GB/T 26179, GB/T 26915 and JC/T 185.

Clause 3 defines the integrating sphere as a hollow sphere for optical measurement whose inner surface is uniformly coated with a highly reflective diffuse medium without wavelength selectivity, so that the irradiance is equal in either direction, and the photocatalytic reaction medium as the medium of the suspension photocatalytic reaction, generally pure water or an aqueous solution.

It then defines three further effects: the self-degradation hydrogen production effect, where the reaction medium itself produces hydrogen under incident light with no catalyst added; the mechanical catalytic hydrogen production effect, where the medium and the photocatalyst produce hydrogen by mechanical means such as stirring without light; and the photothermal catalytic hydrogen production effect, obtained in the spectral section outside the intrinsic absorption of the photocatalyst and the characteristic absorption of the reaction medium, or under modulated incident light.

The draft on the page ends with that clause, so the test system, measurement content and calculation clauses themselves are not shown.

The standard was proposed and is managed by the National Hydrogen Energy Standardization Technical Committee (SAC/TC309); the page gives ICS 27.010 and the Chinese classification F19 and traces it to National Standard Announcement No. 26 of 2020. It was issued on 2020-11-19 and has applied since 2021-06-01.

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Document preview — GB/T 39359-2020

National Standard of the People's Republic of China

ICS
27.010
Classification
F 19

Issued by: State Administration for Market Regulation; Standardization Administration of the PRC

Contents

  • Preface
  • 1 Scope
  • 2 Normative references
  • 3 Terms and definitions
  • 4 Symbol
  • 5 Test system
  • 6 Measurement content
  • 7 Test requirements
  • 8 Data and calculation
  • Appendix A (informative appendix) Basic principles of optical integrating sphere
  • Appendix B (Normative Appendix) Integrating sphere photocatalytic hydrogen production reaction measurement system
  • Appendix C (informative appendix) "Integrating sphere method to measure the reaction efficiency of suspended liquid-solid photocatalytic hydrogen production" test case

Foreword

This standard was drafted in accordance with the rules given in GB/T 1.1-2009.

1 Scope

This standard specifies the testing system, measurement content, and test for measuring the quantum efficiency of the suspension liquid-solid photocatalytic hydrogen production reaction system by the integrating sphere method. Requirements, data and calculation requirements.

This standard applies to the accuracy of the spectral absorption characteristics and the quantum efficiency of hydrogen production in the liquid-solid suspension solar photocatalytic hydrogen production reaction system. measuring.

2 Normative references

The following documents are indispensable for the application of this document. For dated reference documents, only the dated version applies to this file. For undated references, the latest version (including all amendments) applies to this document.

GB/T 8981 Determination of trace hydrogen in gas gas chromatography

GB/T 26179 Spectral radiometric measurement of light source

GB/T 26915 Calculation of Energy Conversion Efficiency and Quantum Yield of Solar Photocatalytic Hydrogen Production System

JC/T 185 Optical Quartz Glass

3 Terms and definitions

The following terms and definitions apply to this document.

3.1 Integrating sphere

Hollow sphere for optical measurement. The inner surface of the ball is uniformly coated with a diffuse reflective medium with high reflectivity and no wavelength selectivity. The irradiance in either direction is equal.

Note: Refer to Appendix A for the basic principle of optical integrating sphere.

3.2 Photocatalytic reaction medium

The medium for the suspension photocatalytic reaction is generally pure water or aqueous solution.

3.3 Self-degradation hydrogen production effect

In the process of photocatalytic hydrogen production, when no catalyst is added, the reaction medium reacts to produce hydrogen under incident light irradiation.

3.4 Mechanical catalytic hydrogen production effect

The reaction medium and photocatalyst produce the effect of hydrogen through mechanical means such as stirring under the condition of no light.

3.5 Photothermal catalytic hydrogen production effect

Select the spectral section other than the intrinsic absorption of the photocatalyst and the characteristic absorption of the reaction medium, and the incident light power and the similar incident light Irradiate under cloth characteristics, or use modulated incident light irradiation to produce the effect of hydrogen.

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This preview omits tables, figures, formulas and parts of the technical clauses. The complete document — 15 pages — is available in the English PDF.

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