Superseded

GB/T 18333.2-2015Zinc-air batteries for electric road vehicle (English PDF)

电动汽车用锌空气电池

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Issued by

General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China

Level / Type

National · Recommended

Issue date

February 4, 2015

Implementation date

September 1, 2015

Scope

GB/T 18333.2-2015 is the English-translated version of 电动汽车用锌空气电池.

GB/T 18333.2-2015 — This standard specifies the terms and definitions, symbols, requirements, test methods, inspection rules, marks, packaging, transport and storage of the zinc-air batteries for electric vehicles (abbreviated as battery).

This standard applies to the zinc-air battery used for the electric vehicles which are supplemented energy through mechanical switching methods.

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Document preview — GB/T 18333.2-2015

National Standard of the People's Republic of China

ICS
43.080
Classification
T 47

Issued by: General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China

Contents

  • Foreword...3
  • 1 Scope...4
  • 2 Normative references...4
  • 3 Terms and definitions...4
  • 4 Symbol...5
  • 5 Requirements...6
  • 6 Test methods...8
  • 7 Testing rules...17
  • 8 Marks, packaging, transport and storage...18

Foreword

This Standard was drafted in accordance with the rules specified in GB/T

1.1-2009.

This Standard replaces GB/Z 18333.2-2001 Zinc-air batteries for electric road

vehicle. As compared with GB/Z 18333.2-2001, besides the editorial changes,

the main technical changes are as the follows.

- MODIFY the applicable scope of this Standard;

- MODIFY the test object and the corresponding test items; as for the cell, it

mainly assesses the safety performance; as for the module, it assesses

the electrical performance and safety performance;

- ADD the I5 detection capacity, I3 detection power characteristics, high &

low temperature discharge capacity, charge retention, and battery

repetitiveness after replacing the negative electrode and the electrolyte;

- ADD the safety performance requirements and test methods of the cell

(see 5.1.10 and 6.2.10);

- ADD battery module, appearance, polarity, dimension and mass,

pourability, discharge performance, safety performance, vibration

resistance requirements and test methods (see 5.2 and 6.3);

- MODIFY the service life requirements and test methods for the air cathode

(see 5.1.9 and 6.2.9).

This standard was proposed by the Ministry of Industry and Information

Technology.

This standard shall be under the jurisdiction of National Automotive

Standardization Technical Committee (SAC/TC 114).

The drafting organizations of this Standard. Wuhan Hongyuan Weili New

Energy Technology Co., Ltd., Dongfeng Yangtse (Wuhan) Co., Ltd., Tianjin

University, China Electronics Technology Group Corporation 18th Research

Institute, China Automotive Technology Research Center.

1 Scope

This standard specifies the terms and definitions, symbols, requirements, test

methods, inspection rules, marks, packaging, transport and storage of the

zinc-air batteries for electric vehicles (abbreviated as battery).

This standard applies to the zinc-air battery used for the electric vehicles which

are supplemented energy through mechanical switching methods.

2 Normative references

The following documents are essential to the application of this document. For

the dated documents, only the versions with the dates indicated are applicable

to this document; for the undated documents, only the latest version (including

all the amendments) are applicable to this Standard.

GB/T 2423.17-2008 Environmental testing for electric and electronic

products – Part 2. Test method – Test Ka. Salt mist (IEC 60068-2-11. 1981,

IDT)

GB/T 2900.41 Electrotechnical terminology – Primary and secondary cells

and batteries [IEC 60050 (482). 2003, IDT]

GB/T 19596 Terminology of electric vehicles

3 Terms and definitions

The terms and definitions as defined in GB/T 2900.41 and GB/T 19596 as well

as those shown below are applicable to this document.

3.1

Zinc air battery

It is a device which uses the oxygen in the air as the cathode active

substance, the zinc as the anode active substance, the alkaline solution as

electrolyte, so as to convert the chemical energy into electrical energy.

3.2

Mechanical switching zinc air battery

It refers to the zinc air battery which realizes energy supplementation

through mechanically replacing the zinc electrode and electrolyte.

3.3

Cell

It refers to a basic unit device which directly converts the chemical energy

into electrical energy. It is composed of electrode, diaphragm, electrolyte,

housing and terminal; AND meanwhile it has multiple energy replenishment

process design.

3.4

Module

It refers an assembly which combines more than one cell through series

connection, parallel connection, and series & parallel combined connection,

only has one pair of positive & negative output terminals, AND is used as a

power supply. It is allowed for this assembly to be with an electronic control

system.

3.5

Rated capacity

It is the energy (Wh) discharged by the cell under room temperature at I5 (A)

current until reaching to the final voltage, which is supplied by the enterprise,

hereinafter shortly referred to as the rated capacity.

4 Symbol

The following symbols apply to this document.

C5 – The 5-hour rated capacity, in the unit of ampere hour (Ah);

C5' – The 5-hour actual capacity after standing for 7 days, in the unit of

ampere hour (Ah);

I5 – The 5-hour rate discharge current, its value is equal to C5/5, in the unit

of ampere (A);

I3 – The 3-hour rate discharge current, its value is equal to C3/3, in the unit

of ampere (A);

It shall conduct test within 1 month after the zinc electrode is fabricated. Before

test, all the battery cases shall be injected of electrolyte solution, AND be

standing for over 24 hours. In all the soaked battery cases, RE-INJECT new

electrolyte solution, and PLACE in the zinc electrode to be tested, which form

the cell or module test sample, AND it shall be under full charge state.

6.2 Cell test

6.2.1 Appearance

Visual inspection

6.2.2 Polarity

USE the voltmeter to check the terminal voltage of the cell under test, to see

whether it is consistent with the terminal polarity identification.

6.2.3 Dimension and mass
6.2.3.1 USE the general or special meter to measure the cell dimensions.
6.2.3.2 USE the general or special weighing scale to weigh the cell mass.
6.2.4 Pourability

TILT the cell under test from the height direction (Y direction) along the

horizontal direction (X direction) for 90°; HOLD it for 30 s; CONDUCT visual

inspection.

6.2.5 Discharge performance test

At 25°C ± 2°C conditions.

a) The cell is discharging at I5 AND the final voltage is 0.8V; MEASURE its

discharge time; CALCULATE the discharge capacity C5; REPLACE the

negative electrode and electrolyte; REPEAT test for 3 times;

CALCULATE the discharge capacity average value;

b) The cell is discharging at I3 AND the final voltage is 0.8V; MEASURE its

discharge time; CALCULATE the discharge capacity C3; REPLACE the

negative electrode and electrolyte; REPEAT test for 3 times;

CALCULATE the discharge capacity average value.

6.2.6 Low temperature test

PLACE the cell under test into the temperature -20°C ± 2°C environmental test

chamber for 12h; then MAKE it discharge at I5 AND the final voltage at 0.6V;

6.2.10 Safety and reliability tests

All safety tests are conducted under conditions having sufficient environmental

protection; if there is active protection circuit, it shall be removed.

6.2.10.1 Short circuit test

After the cell is fully charged through mechanical switching method as

specified in 6.1.3, LET the cell be standing at the 25 °C ± 2 °C test

environment conditions for 30 min; USE an appropriate conductor (resistance

<= 5 mohm) to directly make short circuit between the positive terminal AND

negative terminal of the cell for 50 s. OBSERVE it for 1 h.

6.2.10.2 Drop test

After the cell is fully charged through mechanical switching method as

specified in 6.1.3, LET the cell be standing at the 25 °C ± 2 °C test

environment conditions for 30 min; when the cell terminal is downwards,

MAKE it drop onto the cement floor under gravity from 1.5 m height;

OBSERVE it for 1 h.

6.2.10.3 Heating test

After the cell is fully charged through mechanical switching method as

specified in 6.1.3, CONDUCT the heating test in accordance with the following

steps.

a) PLACE the cell into the temperature box; MAKE the box temperature

increase to 130 °C ± 2°C at the rate of 5 °C/min; MAINTAIN this

temperature for 30 min; STOP heating;

b) OBSERVE it for 1 h.

6.2.10.4 Over discharge test

After the cell is fully charged through mechanical switching method as

specified in 6.1.3, CONDUCT the over discharge test in accordance with the

following steps.

a) MAKE the cell discharge at 2I3 (A) current, until the cell voltage reaches

to 0 V; CONTINUE forcedly discharge at 2I3 (A) current for 30 min;

b) OBSERVE it for 1 h.

6.2.10.5 Salt mist test
6.3.5 Discharge performance test

At 25°C ± 2°C conditions.

a) MAKE the fully charged module which is composed of n cells in series

connection discharge at I5, AND the final voltage is n × 0.8 V; MEASURE

the discharge time; CALCULATE t...

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This preview omits tables, figures, formulas and parts of the technical clauses. The complete document — 18 pages — is available in the English PDF.

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