GB 223.43-1985Iron, steel and alloy -- Determination of tungsten content -- Gravimetric method and spectrophotometric method (English PDF)
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Issued by
Standardization Administration of China
Level / Type
National · Mandatory
Issue date
May 13, 2008
Implementation date
November 1, 2008
Scope
GB 223.43-1985 (Iron, steel and alloy -- Determination of tungsten content -- Gravimetric method and spectrophotometric method) is available as an English-translated PDF.
GB 223.43-1985 — This section GB/T 223 requirements using cinchonine gravimetric and tetrakis phenylarsonic - thiocyanate - chloroform extraction photometric measurements Set tungsten content.
This section cinchonine gravimetric method is suitable for steel, high temperature alloys and precision alloys mass fraction of 1.00% - 22.00% of the amount of tungsten Determination.
This section tetrakis phenylarsonic - thiocyanate - chloroform extraction spectrophotometric method for carbon steel, alloy steel and high temperature alloys mass fraction to determine the number of 0.050% to 1.50% tungsten content.
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Document preview — GB 223.43-1985
National Standard of the People's Republic of China
- ICS
- 77.080.01
- Classification
- H 11
- Replacing
- GB/T 223.43-1994
Issued by: Standardization Administration of China
Contents
- Foreword
- 1 Scope
- 2 Normative references
- 3.1 Principle
- 3.2 Reagents
Foreword
GB/T in this part 223 instead of the GB/T 223.43-1994 "steel and alloy chemical analysis method for determining the amount of tungsten." this portion of the GB/T 223.43-1994 compared primarily with the following modifications.
--- Name to "Determination of tungsten steel and alloy content gravimetric method and spectrophotometry";
--- Increased water analysis reagents and instructions to modify the content and concentration of representation;
--- Modified Weigh Sample volume represented;
--- Modify the results of the formula in the amount of representation;
--- Change the specification for precision functional description.
Appendix A of this section is informative appendix.
This part is proposed by the China Iron and Steel Association.
This part of the National Steel Standardization Technical Committee.
This section drafted by. Institute of Metal Research, Daye steel mills.
1 Scope
This section GB/T 223 requirements using cinchonine gravimetric and tetrakis phenylarsonic - thiocyanate - chloroform extraction photometric measurements Set tungsten content.
This section cinchonine gravimetric method is suitable for steel, high temperature alloys and precision alloys mass fraction of 1.00% - 22.00% of the amount of tungsten Determination.
This section tetrakis phenylarsonic - thiocyanate - chloroform extraction spectrophotometric method for carbon steel, alloy steel and high temperature alloys mass fraction to determine the number of 0.050% to 1.50% tungsten content.
2 Normative references
The following documents contain provisions which, through reference GB/T 223 of this text, constitute provisions of this section. For dated reference documents Member, all subsequent amendments (not including errata content) or revisions do not apply to this section, however, encouraged to reach under this section Parties to research agreement to use the latest versions of these documents. For undated reference documents, the latest versions apply to this section.
GB/T 223.12 Methods for chemical analysis of iron, steel and alloys of sodium carbonate separation - diphenyl hydrazine spectrophotometric determination of chromium content GB/T 223.14 Methods for chemical analysis of iron, steel and alloys, tantalum reagent extraction and spectrophotometric determination of vanadium content Spectrophotometric determination of molybdenum content GB/T 223.26 Methods for chemical analysis of iron, steel and alloy The thiocyanate direct GB/T 6379.1 measurement methods and results of Accuracy (trueness and precision) - Part 1. General principles and definitions GB/T 6379.2 measurement methods and results of Accuracy (trueness and precision) - Part 2. Determine the weight of a standard measurement method the basic method of refolding and reproducibility GB/T 20066 Steel and iron - Sampling and determination of the chemical composition of the sample with a sample preparation method 3 a method cinchonine gravimetric method
3.1 Principle
Free samples of niobium. In the hydrochloric acid solution, the nitric oxide, tungsten formed precipitate tungstate, tungsten caprylate Ning complete precipitation, filtration, burning After the addition of silicon with hydrofluoric acid vaporized, burning to constant, that is impure tungsten trioxide quality.
Containing niobium samples. the niobium pentoxide and tungsten trioxide precipitated with sodium carbonate melt, after separating agent magnesium niobate by precipitation, and then beta- naphthol quinoline Rhodamine B or precipitation of tungsten, burning to constant as an impure quality tungsten trioxide.
Tungsten trioxide impure molten sodium carbonate, and filtered. Filtrate molybdenum, chromium, vanadium, respectively spectrophotometric determination of correction. Shen filter paper Lake iron, titanium and other impurities, burning into oxides after weighing. These oxides by subtracting the mass of impure tungsten trioxide mass, that was pure ozone Tungsten quality.
3.2 Reagents
Unless otherwise indicated, the analysis uses only recognized as analytical grade reagents and distilled or deionized water or equivalent purity.
3.2.1 anhydrous sodium carbonate.
3.2.2 nitrate, rho about 1.42g/mL.
......
This preview omits tables, figures, formulas and parts of the technical clauses. The complete document — 8 pages — is available in the English PDF.
Referenced standards
Normative references
- GB/T 223.14Methods for chemical analysis of iron, steel and alloy. The N-benzoyl-N-phenylhydroxylamine extraction photometric method for the determination of vanadium content
- GB/T 223.26Iron, steel and alloy - Determination of molybdenum content - The thiocyanate spectrophotometric method
- GB/T 20066Steel and iron -- Sampling and preparation of samples for the determination of chemical composition
GB/T 223 · GB/T 223.12 · GB/T 6379.1 · GB/T 6379.2
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