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GB 19521.11-2005Safety code for inspection of hazardous properties for dangerous goods of lithium batteries (English PDF)

锂电池组危险货物危险特性检验安全规范

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Issued by

General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China; Standardization Administration of China

Level / Type

National · Mandatory

Issue date

October 19, 2005

Implementation date

May 1, 2006

Scope

GB 19521.11-2005 is the English-translated version of 锂电池组危险货物危险特性检验安全规范.

GB 19521.11-2005 — This standard specifies the requirements, tests and inspection rules for dangerous goods of lithium-ion cells or batteries. This standard is applicable to the inspection of hazardous properties for dangerous goods of lithium-ion cells or batteries.

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Document preview — GB 19521.11-2005

National Standard of the People's Republic of China

ICS
发布日期
Classification
A80

Issued by: General Administration of Quality Supervision, Inspection and Quarantine of the People's Republic of China; Standardization Administration of China

Contents

  • Foreword...3
  • 1 Scope...4
  • 2 Normative References...4
  • 3 Terms and Definitions...4
  • 4 Requirements...7
  • 5 Tests...8
  • 6 Inspection Rules...14

Foreword

Chapter 4 and Chapter 5 in this standard are mandatory and the rest are voluntary.

This standard is not equivalent to the "UN Recommendations on the Transport of Dangerous

Goods--Model Regulation" (Thirteenth revised edition) and the "UN Recommendations on

the Transport of Dangerous Goods--Manual of Tests and Criteria" (Fourth revised edition); its

relevant technical contents are consistent with the abovementioned regulations and some

editorial changes are made in the format of the standard text according to GB/T 1.1-2000.

This standard was proposed by and is under the jurisdiction of the National Technical

Committee on Dangerous Chemicals Management of Standardization Administration of

China (SAC/TC 251).

Chief drafting organization of this standard. Hazardous Products Central Laboratory of the

General Administration of Quality Supervision, Inspection and Quarantine of the People's

Republic of China.

Participating drafting organizations of this standard. Tianjin Entry-Exit Inspection and

Quarantine Bureau, Asia-Pacific Region Hazardous Products Association and Jiangnan

University.

Chief drafting staffs of this standard. Wang Libing, Gao Weiping, Li Ningtao, Liu Jun, Li

Dequan, Zhao Haolibao.

This standard was formulated for the first time.

Safety Code for Inspection of Hazardous Properties for

Dangerous Goods of Lithium Batteries

1 Scope

This standard specifies the requirements, tests and inspection rules for dangerous goods of

lithium-ion cells or batteries.

This standard is applicable to the inspection of hazardous properties for dangerous goods of

lithium-ion cells or batteries.

2 Normative References

The following documents contain provisions which, through reference in this text, constitute

provisions of this standard. For dated reference, subsequent amendments to (excluding

correction to), or revisions of, any of these publications do not apply. However, the parties to

agreements based on this standard are encouraged to investigate the possibility of applying

the most recent editions of the standards indicated below. For undated references, the latest

edition of the normative document referred to applies.

GB 19458 "Safety Code for Inspection of Hazardous Properties for Dangerous

Goods-General Specifications"

IEC 60050 (482) "International Electrotechnical Vocabulary - Part 482.Primary and

Secondary Cells and Batteries"

"UN Recommendations on the Transport of Dangerous Goods--Model Regulation"

(Thirteenth revised edition)

"UN Recommendations on the Transport of Dangerous Goods--Manual of Tests and

Criteria" (Fourth revised edition)

3 Terms and Definitions

The terms and definitions established in the "UN Recommendations on the Transport of

Dangerous Goods--Manual of Tests and Criteria" (Fourth revised edition) and in IEC 60050

(482) as well as the following ones are applicable to this standard.

3.1

Aggregate lithium content

It refers to the sum (g) of the content of lithium of all the cells that constitute the battery.

3.5

First cycle

It refers to the initial charge and discharge cycle after completing all the manufacturing

procedures.

3.6

Fully charged

It refers to that the rechargeable cell or battery is charged to its designed initial conditions.

3.7

Fully discharged

It refers to one of the following two conditions.

3.8

Large cell

It refers to the cell for which the content of lithium at its anode is larger than 12g at the fully

charged state.

3.9

Large battery

It refers to the battery for which the aggregate lithium content at all the anodes is larger than

500g at the fully charged state.

4 Requirements

4.1 General Requirements

4.1.1 The marks, signs and dangerous goods colored labels incused, printed or pasted on the

package of dangerous goods of lithium batteries shall be accurate and clear, and shall meet the

requirements of the relevant provisions specified in GB 19458.

4.2 Test Requirements

The test requirements for lithium cell and battery are detailed in Table 1.

5 Tests

5.1 Altitude Simulation, Extreme Temperature and Short Circuit Test

5.1.1 Test equipments

This test needs the following equipments. balance, vacuum chamber, electric furnace,

refrigerator box, conductors with total resistance no larger than 0.05ohm, thermocouple and

self-recording millivoltmeter.

5.1.3 Test methods
5.1.3.1 Altitude simulation

The cell and battery shall be stored for at least 6h at the absolute pressure of 11.6kPa and

temperature of 20°C.

5.2 Vibration, Impact and Short-circuit Test

5.2.1 Test equipments

This test needs the following equipments. vibration machine, impact testing apparatus,

conductors with total resistance no larger than 0.05ohm, thermocouple and self-recording

millivoltmeter. The impact testing apparatus shall meet the requirements stated in 38.3.4.2.2.1

of the "UN Recommendations on the Transport of Dangerous Goods--Manual of Tests and

Criteria" (Fourth revised edition).

5.2.2 Specimen preparation

The test specimens shall be prepared according to the requirements stated in 38.3.4.2.2 of the

"UN Recommendations on the Transport of Dangerous Goods--Manual of Tests and Criteria"

(Fourth revised edition).

5.2.3 Test methods
5.2.3.1 Vibration

The cell and battery shall be clipped onto the platform of vibration machine fixedly and

tightly without any surface deformed.

5.2.3.2 Impact

The cell and battery shall be tightened onto the impact testing apparatus with hard bracket,

and the bracket shall support all the installation surfaces. Each cell or battery shall bear

impacts of the equal size for three times, and these impacts shall be applied along three

mutually perpendicular directions that are orthometric to the cell or battery surface. During

the impact of every time, the acceleration mode of cell or battery shall be.

5.2.3.3 Short circuit

The same as 5.1.3.3.

5.3 Vibration, Impact and Charge Test

5.3.1 Test equipments

This test needs the following equipments. vibration machine, impact testing apparatus,

resistor and voltmeter. The impact testing apparatus shall meet the requirements stated in

38.3.4.2.2.1 of the "UN Recommendations on the Transport of Dangerous Goods--Manual of

Tests and Criteria" (Fourth revised edition).

5.3.3.2 Impact

The same as 5.2.3.2.

5.3.3.3 Charge test

One test cell or battery shall be connected with one non-discharged primary cell or battery of

the same type or one fully charged rechargeable cell or battery in the series connected cell

string, and the electrodes of the test cell or battery shall be inversely connected.

5.4 Internal Short Circuit Test

5.4.1 Test equipments

This test needs the following equipments. the clamping device (jaw vice and hydraulic ram,

etc.) with cleat insulator, the rod with the diameter of its rigid insulation surface being at least

50% of the overall size of minimum cell or being at least 6mm (taking the larger one therein),

and voltmeter.

5.5 Vibration, Impact and Low-capacity Cell Test

5.5.1 Test equipments

This test needs the following equipments. vibration machine, impact testing apparatus,

resistor and voltmeter. The impact testing apparatus shall meet the requirements stated in

38.3.4.2.2.1 of the "UN Recommendations on the Transport of Dangerous Goods--Manual of

Tests and Criteria" (Fourth revised edition).

5.5.2 Specimen preparation

The test specimens shall be prepared according to the requirements stated in 38.3.4.5.2 of the

"UN Recommendations on the Transport of Dangerous Goods--Manual of Tests and Criteria"

(Fourth revised edition).

5.5.3 Test methods
5.5.3.1 Vibration

The same as 5.2.3.1.

5.5.3.2 Impact

The same as 5.2.3.2.

5.7 Classification

The lithium cell and battery shall be respectively carried out with the series tests required in

5.1~5.6, and the tests of every series shall be carried out in order. If the lithium cell or the

battery meets all the test requirements listed in Table 1, then this lithium cell or battery shall

be judged as the Class 9 dangerous goods. The lithium cells and batteries related to

transportation as stated in the Special Regulations 188 in Chapter 3 of "UN

Recommendations on the Transport of Dangerous Goods--Model Regulation" (Thirteenth

revised edition) are not applicable to this standard.

6 Inspection Rules

6.1 The inspection shall be carried out item by item according to the requirements in

Chapter 4 and Chapter 5 of this standard.

6.2 Inspection conditions of hazardous properties.

The inspection of hazardous properties shall be carried out in case any one of the following

conditions is met.

6.3 Judgment rules.

The tests shall be carried out according to 5.1~5.6 of this standard, and the judgment shall be

carried out according to the test results and the hazardous properties for dangerous goods of

lithium batteries stated in 5.7 of this standard.

......

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This preview omits tables, figures, formulas and parts of the technical clauses. The complete document — all pages — is available in the English PDF.

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